• Journal of the Korea Concrete Institute
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• v.12 no.6
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• pp.51-56
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• 2000

Fly ash used as a cement replacement material increases the long term strength and also improves the durability of concrete and mortar. However, the use of fly ash is a little in spite of great benefit. In order to increase the consumption of fly ash, it has to be used as a cement replacement materials in the production of mortar and concrete, and the reduction of early strength development due to the use of fly ash also has to be diminished. In this study, many chemical compounds which accelerate the early strength was investigated. The $Na_2$$SO_4$, $K_2$$SO_4$, Triethanolamine were selected and applied to the production of mortar. It was found that they enhance the early strength development of mortar(1, 3day) and decrease the amount of $Ca(OH)_2$, and also increase the production of ettringite. According to the results of mercury instruction test, the pores ranged from 0.01 $\mu\textrm{m}$ to 5$\mu\textrm{m}$ were decreased and it was also found in the analysis of X ray and SEM that fly ash increases the amount of ettringite at early ages.

• Journal of the Korea Institute of Building Construction
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• v.21 no.4
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• pp.269-279
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• 2021

Palm Oil Fuel Ash(POFA) has been widely used to replace Portland cement to enhance the mechanical properties and durability of concrete. However, it reduces the workability of concrete due to the high content of unburnt carbon and its angular shape requiring the usage of superplasticizer to ensure a proper flowability. In this study, effects of different types and dosage of superplasticizer on the early mechanical and hydration properties of cement paste containing micro-POFA were evaluated using mini-slump test, early compressive strength, TGA, XRD, and SEM. The results indicated that the flowability of cement paste containing micro-POFA reduced as the replacement ratio of micro-POFA increased. As the dosage of superplasticizer increased, the flowability was also increased. In addition, the usage of superplasticizer reduced the early compressive strength, and the strength decreased with an increase in the dosage of superplasticizer. It was confirmed that superplasticizer hindered the formation of C-S-H leading to a relative increase in the formation of Ca(OH)₂.

• Journal of the Korean Ceramic Society
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• v.37 no.5
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• pp.438-443
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• 2000

This dissertation is focused on the study over the improvement for the early strength of belite-rich cement(BRC). For this purpose, the initial hydration behaviors according to addition of different calcium sulfate types were evaluated. From the observations by XRD, DSC and SEM, the BRC II and III with the addition of natural anhydrate and flue gas desulphurization(FGD) gypsum, respectively, formed much ettringite after 7 days more than the BRC I with the addition of chemical gypsum. The compressive strength of the BRC II and III developed outstandingly due to the formation of calcium aluminate hydrate within pores of hardened BRC paste. Especially, in the case of BRC III adding FGD with low impurities, the early as well as long term compressive strengths were shown very high, compared with other specimens.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.385-390
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• 2002

Autogenous shrinkage of concrete has been defined as decrease in volume due to hydration cement, not due to other causes such as evaporation, temperature change and external load and so on. For ordinary concretes, autogenous shrinkage is so little compared to the other deformations that it has been dignored. It has recently been proved, however, that autogenous shrinkage considerably increase with decrease in water to cement ratio. And it has been reported that cracking can be caused by autogenous shrinkage, when high- strength concretes were used. In this study, we propose an analytical system to represent autogenous shrinkage in cement paste in order to control crack due to autogenous shrinkage. The system is composed with the hydration model and pore structure model. Contrary to the usual assumption of uniform properties in the hydration progress, the hydration model to refine Tomosawa's represents the situation that inner and outer products are made in cement paste. The pore structure model is based upon the physical phenomenon of ion diffusion in cement paste and chemical phenomenon of hydration in cement particle. The proposed model can predict the pore volume ratio and the pore structure in cement paste under variable environmental conditions satisfactorily The autogenous shrinkage prdiction system with regard to pore structure development and hydration at early ages for different mix-proportions shows a reasonable agreement with the experimental data.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.789-792
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• 2005

Development of high-strength concrete and improved durability has brought new opportunities to the construction industry. However, some attention was given to characteristics of such concrete, in particular with respect to their cracking sensitivity. It has been argued and demonstrated experimentally that a low water/cement ratio concrete undergoes shrinkage due to self-desiccation. This so-called autogenous shrinkage cracking is a major concern for concrete durability. One possible method to reduce cracking due to autogenous shrinkage is the addition of expansive additive. Tests conducted by many researches have shown the beneficial effects of addition of expansive for reducing the risk of shrinkage-introduced cracking. This paper aimed at forecasting deformation of high strength cement paste with expansive additive for early age.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.5
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• pp.141-147
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• 2017

Recently, lots of researches on concrete with high volume mineral admixtures such as ground granulated blast-furnace slag(GGBS) have been carried out to reduce greenhouse gas. The high volume GGBS concrete has advantages such as low heat, high durability, but it has a limitation in practical field application, especially low strength development in early ages. This study investigated the compressive strength and hydration characteristics of high performanc and volume GGBS cement pastes with low water to binder ratio. The effects of fineness($4,330cm^2/g$, $5,320cm^2/g$, $6,450cm^2/g$, $7650cm^2/g$) and replacement(35%, 50%, 65%, 80%) of GGBS on the compressive strength, setting and heat of hydration were analyzed. Experimental results show that the combination of high volume slag cement paste with low water to binder ratio and high fineness GGBS powder can improve the compressive strength at early ages.

• Journal of the Korean Ceramic Society
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• v.44 no.1 s.296
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• pp.23-31
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• 2007

To examine the effects of chemical admixture on the fluidity and strength development of high chloride cement, experiments were conducted in which lignosulfonate (LS), naphthalenesulfonate (NS), and polycorboxylate (PC) were each added in standard and excessive amounts, and the results were as follows. 1. Because adding KCl to NS causes a decrease in flow, adding PC is better in maintaining high cement fluidity. 2. When cement contained much chloride comes in contact with water, hydration begins 4 h after contact and securing workability becomes difficult, but by adding PC, workability can be secured to 10 h. 3. The bound water ratio and compressive strength in aging 3 days occupy $70\sim80%$ of those in aging 28 days, and the early compressive strength increases not only by adding KCl, but also by chemical admixture. 4. Although compressive strength development is excellent in NS, PC, if NS is added excessively, hydration becomes slow and while the pore structures become slightly minute, the strength development decreases due to severe setting retardation.

• Journal of the Korean Ceramic Society
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• v.55 no.3
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• pp.224-229
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• 2018

OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

• Journal of the Korea Concrete Institute
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• v.22 no.5
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• pp.633-640
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• 2010

This study was performed to get basic information about properties of high blaine cement for shotcrete use. Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of high blaine cement. Setting time of high blaine cement was shorter and compressive strength was higher than those of ordinary portland cement (OPC). Results of analysis showed early hydration products of high blaine cement is smaller and spread widely due to increased specific surface. From the SEM observation and analysis of DSC and XRD results, it was seen that the aluminates accelerators promoted calcium aluminium hydrates while the alkali free accelerators increased ettringite and monosulfates formation. Strength and setting time measurement of cement paste with aluminate accelerator is more effective than the alkali free accelerator in reducing the setting time and increasing early strength while alkali free accelerator is more effective in increasing the strength after 7 days.

• Magazine of the Korea Concrete Institute
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• v.10 no.4
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• pp.195-204
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• 1998

Generally, in order to maintain high strength in concrete, it needs high cement content and low water-cement ratio.makes internal temperature rising after concrete placing inevitably, and happens temperature stress that makes initial cracks of concrete structure. Therefore, to control the thermal stress of high-strength concrete, we made 3 types of the fineness of ground granulated blast-furnace slag and 4 steps replacement. and then measured an amount of temperature rising and elapsed time of maximum temperature and strength of concrete. Also we considered the test results of heat evolution amount and heat evolution of cement paste made with 5 steps replacement by GGBF slag.As result of this study, in case of the 50% of replacement and the 6,000$\textrm{cm}^2$/g of fineness, we obtained satisfactory results that not only the controlled effect of temperature rising but strength at early ages.