• 제목/요약/키워드: High Xe

검색결과 141건 처리시간 0.029초

Synthesis and Photoisomerization Properties of Polynorbornenes with Azobenzene Chromophores

  • Kang, Suk-Hoon;Shin, Hee-Deuk;Oh, Cha-Hwan;Choi, Dong-Hoon;Park, Ki-Hong
    • Bulletin of the Korean Chemical Society
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    • 제23권7호
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    • pp.957-963
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    • 2002
  • We successfully synthesized the addition-type polynorbonenes (PNB) exhibiting photochromic properties and excellent thermal stability. Three norbornene-based monomers with different azobenzene moiety (R=NO2, H,OCH3) were synthesized by transesterification method. The corresponding PNB copolymers were synthesized by transition metal-catalyzed addition polymerization method, and characterized by GPC, UV-Vis spectroscopy, NMR, and thermal analysis. For comparison of the photochromic properties depending on the rigidity of polymer backbone, we prepared the polymethylmethacrylate (PMMA) copolymer with the corresponding azobenzene moiety. We investigated the photoisomerization behavior by means of optical muitichannel analyzer with Xe lamp as well as real-time UV-Vis spectroscopy with high-pressure mercury lamp. Among three PNB copolymers, a polymer with azobenzene (R=H) was the most adaptable for observation of photoisomerization behavior. It was found that the rate of photoisomerization and relaxation depended on the structure of azobenzene chromophore, rather than that of polymer backbone.

몬테 카를로 시뮬레이션을 이용한 2차원 X-선 검출기에 대한 연구 (A Study of 2-dimensional X-ray Detector using Monte Carlo Simulation)

  • 신형섭;이학재;이기성;강정원
    • 반도체디스플레이기술학회지
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    • 제9권4호
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    • pp.67-70
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    • 2010
  • X-ray absorption rate and multiplication factor of X-ray detector were calculated with Garfield code. High Z (= atomic number) was important factor to increase the absorption rate but low Z is also important to increase the multiplication. Five different gas composition were examined under the condition of 1400 V bias and 400 um gap. Xe 100% gas showed the highest absorption rate and He 96% + isobutene 4% showed the highest multiplication.

Measurement of excited species in discharges using Laser Absorption spectroscopy

  • Sakai, Yosuke
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.5-8
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    • 2000
  • The population density of excited species in dc, rf and laser ablation plume plasmas has been measured using laser absorption spectroscopy. It was shown that, when the plasma was modulated by on and off with, the sensitivity and signal to noise (S/N) ratio became high. For example, the atomic O(3$^{5}$ S$^{o}$ $_2$) Population density, No* in $O_2$/He mixtures was obtained by the highest S/N ratio at a frequency of 2.7kHz. In a 20Torr room air, the lowest No* level to be detectable was shown to be an order of 10$^{7}$ cm$^{-3}$ . The population densities of resonance Ar(1S$_2$) and Xe(1S$_4$) levels were also measured in barrier discharges and laser ablation plasmas.

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LCD 후면광원용 면방전형 FFL의 Dielectric Layer에 따른 방전 특성 (Discharge Characteristic of Surface Type FFL as LCD Backlighting according to Dielectric Layer)

  • 임민수;정득영;윤성현;임기조;권순석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.177-180
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    • 1999
  • In this paper, we studied Surface Discharge Type Flat Fluorescent Lamp(FFL) with High Luminance for LCD Backlighting. This lamp is Surface Discharge Type structure with a pair of Sodalime glass, insulator layer, phosphor layer, and Xe gas gap. There are two influences of Electric field on different dielectric thickness. The Electric field difference at the dielectric layer itself enhances minimum value of firing voltage and luminance uniformity. So, we measured the Electric filed at 0.5mm, 1mm gap length and discharge voltage for difference dielectric layer thickness. In experiment result, the thicker dielectric layer has higher firing voltage and lower current.

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LCD 백라이트용 면방전형 FFL의 방전 특성 (Discharge Characteristics of Surface Discharge Type FFL for LCD Backlighting)

  • 임민수;윤성현;신유섭;정득영;권순석;임기조
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1786-1788
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    • 1999
  • In this paper, we studied Surface Discharge Type Flat Fluorescent Lamp with High Luminance for LCD Backlighting, Liquid Crystal display(LCDs) demand the use of fluorescent lamp as the backlighting source. This lamp is Surface Discharge Type structure with a pair of Sodalime glass, insulator layer, phosphor layer, and Xe gas gap. In spite of its simple structure, the lamp has uniform and stable discharge over entire volume. Till now, we measured the current-voltage(V-I), Firing Voltage, Sustain Voltage for 0.5mm, 1mm electrode gap. In experiment result, long gap cell structure cause high firing voltage. The rising in firing voltage in long gap structure could not be explained by paschen's law because of non-uniform electric field.

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새로운 Fence 전극 구조에 의한 ac-PDP 효율 개선에 관한 연구 (A Study on the Improvement of the luminous Efficiency in ac-PDP with New Fence Structure)

  • 권비수;옥정우;김현종;이돈규;김동현;이호준;박정후
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.201-203
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    • 2005
  • To improvement the performance of PDPs, we developed an ac-PDP with new fence structure. By measuring minimum sustaining voltage(Vs), discharge current(Ion), discharge(Ioff), and brightness of the light from a 4-inch at-PDP, performances of the conventional structure and proposed structure are compared. The experimental results show that the test panel with the proposed new fence structure shows high luminance by 10%, and high luminous efficiency by 30% compared with the conventional structure at the Ne-Xe(8%) gas mixture of 400 torr.

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Dual-zone reactor와 CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산 (Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle Using Dual-zone Reactor and CeO2/ZrO2 Foam Device)

  • 조지현;서태범
    • 한국태양에너지학회 논문집
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    • 제37권5호
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    • pp.27-37
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    • 2017
  • In this study, an artificial solar simulator composed of a 2.5 kW Xe-Arc lamp and mirror reflector was used to carry out the solar thermal two step thermochemical water decomposition cycle which can produce high efficiency continuous hydrogen production. Through various operating conditions, the change of hydrogen production due to the possibility of a dual-zone reactor and heat recovery were experimentally analyzed. Based on the reaction temperature of Thermal-Reduction step and Water-Decomposition step at $1,400^{\circ}C$ and $1,000^{\circ}C$ respectively, the hydrogen production decreased by 23.2% under the power off condition, and as a result of experiments using heat recovery technology, the hydrogen production increased by 33.8%. Therefore, when a thermochemical two-step water decomposition cycle is conducted using a dual-zone reactor with heat recovery, it is expected that the cycle can be operated twice over a certain period of time and the hydrogen production amount is increased by at least 53.5% compared to a single reactor.

Theoretical gravity studies on roles of convection in crystal growth of $Hg_2Cl_2$-Xe by physical vapor transport under normal and high gravity environments

  • Kim, Geug-Tae;Kwon, Moo-Hyun
    • 한국결정성장학회지
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    • 제19권3호
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    • pp.107-115
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    • 2009
  • Particular interest in the role of convection in vapor crystal growth has arisen since some single crystals under high gravity acceleration of $10g_0$ appear considerably larger than those under normal gravity acceleration ($1g_0$). For both ${\Delta}T=60\;K$ and 90 K, the mass flux increases by a factor of 3 with increasing the gravity acceleration from $1g_0$ up to $10g_0$. On the other hand, for ${\Delta}T=30\;K$, the flux is increased by a factor of 1.36 for the range of $1g_0{\leq}g{\leq}10g_0$. The maximum growth rates for $1g_0$, $4g_0$, $10g_0$ appear approximately in the neighborhood of y = 0.5, and the growth rates shows asymmetrical patterns, which indicate the occurrence of either one single or more than one convective cell. The maximum growth rate for $10g_0$ is nearly greater than that for $1g_0$ by a factor of 2.0 at $P_B=20\;Torr$. For three different gravity levels of $1g_0$, $4g_0$ and $10g_0$, the maximum growth rates are greater than the minimum rates by a factor of nearly 3.0, based on $P_B=20\;Torr$. The mass flux increases with increasing the gravity acceleration, for $1g_0{\leq}g_y{\leq}10g_0$, and decreases with increasing the partial pressure of component B, xenon (Xe), $P_B$. The $|U|_{max}$ is directly proportional to the gravity acceleration for $20\;Torr{\leq}P_B{\leq}300\;Torr$. As the partial pressure of $P_B$ (Torr) decreases from 300 Torr to 20 Torr, the slopes of the $|U|_{max}s$ versus the gravity accelerations increase from 0.1 sec to 0.17 sec. The mass flux of $Hg_2Cl_2$ is exponentially decayed with increasing the partial pressure of component B, $P_B$ (Torr) from 20 Torr up to 300 Torr.

Mesh-type PECVD 방법으로 제조된 비정질 Si박막의 특성 및 레이저 결정화 (Characteristics of Amorphous Si Films Fabricated by Mesh-type PECVD and Their Crystallization Behavior Using Excimer Laser)

  • 한상용;최재식;김용수;박성계;노재상;김형준
    • 전기화학회지
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    • 제3권1호
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    • pp.19-24
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    • 2000
  • poly-Si TR는 LCD의 고해상도화, 고집적화에 따라 그 요구가 점점 필요해지고 있다. 그러나 poly-Si의 제조를 위해 주로 사용하는 레이저 결정화 방법은 박막 내에 함유된 수소 때문에 별도의 탈수소 공정을 행하는 실정이다. 막내의 수소는 결정화 시 eruption과 void등의 생성으로 poly Si의 막 특성뿐 아니라 소자 특성에도 나쁜 영향을 미치게 된다. 본 연구에서는 전술한 문제점을 제어하기 위해 mesh-type PECVD를 제안하고 저수소화 박막 증착에 관한 연구를 수행하였다. 증착된 비정질 Si 박막은 $300^{\circ}C$ 이하의 온도에서도 $1 at\%$ 이하의 낮은 수소 함유량을 가진 것으로 조사되었다. mesh에 의한 이런 결과는 막내에 함유되는 수소를 효과적으로 제어하고 별도의 탈수소 공정을 배제하여 공정 감소의 효과를 갖는 장점이 있다. 또한 제조된 비정질 Si을 이용하여 XeCl 레이저 결정화하여 그 거동을 조사하였는데 일반적인 거동과 달리 매우 넓은 공정 영역을 갖고 있는 것을 확인할 수 있었다 또한, 수소에 의한 표면 거칠기 문제는 발견되지 않았으며 비교적 조대하고 균일한 결정립 분포를 하는 것으로 조사되었다 본 결과는 레이저 결정화 공정의 안정성에 기여하고 소자 특성 향상에도 기여할 것으로 기대된다

TRIGA Mark-III 원자로의 노심특성계산 (Calculation of Nuclear Characteristics of the TRIGA Mark-III Reactor)

  • Chong Chul Yook;Gee Yang Han;Byung Jin Jun;Ji Bok Lee;Chang Kun Lee
    • Nuclear Engineering and Technology
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    • 제13권4호
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    • pp.264-276
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    • 1981
  • TRIGA Mark-III 원자로의 핵특성을 실제운전상태와 유사하게 모사할 수 있는 해석절차를 개발하였다. 계산에 사용한 전산코드는 다군중성자확산 연소계산코드인 CITATION이고 채택한 중성자에너지군의 수는 TRIGA형 원자로에서 일반적으로 사용하는 7군(고속영역 3, 열영역 4)이다. 직접적인 3차원 계산이 현실적으로 불가능하므로 평면 2차원계산과 원통형 2차원 계산으로 3차원 효과를 기하였다. 연구로와 같이 노심이 작은 원자로에 대하여는 중성자평형에서 buckling에 의한 효과가 매우 크기 때문에 이를 정확하게 나타내는 방법의 개발에 중점을 두었다. 본 연구에서는 에너지군 또는 영역에 무관한 buckling을 중성자 수송이론으로 산출하는 전형적인 방법을 사용하지 않고 중성자 확산이론으로서 에너지군별, 영역별 buckling을 산출하였으며, 이를 이용하여 수행한 노심계산의 결과는 만족스러웠다. 계산시 노심은 원자로수조의 중앙부에 있는 것으로 하고 제어봉은 완전히 인출되었으며 동위원생산용 조사시료는 없는 것으로 가정하였다. 계산결과로서 연소에 따른 초과반응도가의 변화, 운전이력에 따른 Xe-135 독작용의 변화, 회전조사시료대의 반응도가를 산출하고 이를 실제 운전자료와 비교하였다. 또한 중성자속 및 출력분포, 노심 각 조사시설에서의 중성자 스펙트럼등에 대한 계산결과도 제시하였다.

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