• 제목/요약/키워드: High Polymer

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모세관 리소그라피를 이용한 고종횡비 나노구조 형성법 (Capillary-driven Rigiflex Lithography for Fabricating High Aspect-Ratio Polymer Nanostructures)

  • 정훈의;이성훈;김필남;서갑양
    • 한국가시화정보학회지
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    • 제5권1호
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    • pp.3-8
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    • 2007
  • We present simple methods for fabricating high aspect-ratio polymer nanostructures on a solid substrate by rigiflex lithography with tailored capillarity and adhesive force. In the first method, a thin, thermoplastic polymer film was prepared by spin coating on a substrate and the temperature was raised above the polymer's glass transition temperature ($T_g$) while in conformal contact with a poly(urethane acrylate) (PUA) mold having nano-cavities. Consequently, capillarity forces the polymer film to rise into the void space of the mold, resulting in nanostructures with an aspect ratio of ${\sim}4$. In the second method, very high aspect-ratio (>20) nanohairs were fabricated by elongating the pre-formed nanostructures upon removal of the mold with the aid of tailored capillarity and adhesive force at the mold/polymer interface. Finally, these two methods were further used to fabricate micro/nano hierarchical structures by sequential application of the molding process for mimicking nature's functional surfaces such as a lotus leaf and gecko foot hairs.

강섬유 혼입 폴리머 시멘트 고강도 콘크리트 보의 전단거동 (Shear Behavior of Polymer Cement High Strength Concrete Beams Mixed with Steel Fiber)

  • 곽계환;박종건;곽경헌
    • 한국농공학회지
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    • 제44권1호
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    • pp.93-102
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    • 2002
  • Steel fiber and polymer are used widely for reinforcement material of RC structures because of its excellences of the durability, serviceability as well as mechanical properties. The purpose of this study is to investigate the shear behavior of polymer cement high strength concrete beams mixed with steel fiber. The compressive strength of concrete was based on the 100$\times$200 mm cylinder specimens. The compressive strength of concrete are 320$kgf/cm^2$, 436 $kgf/cm^2$ and 520 $kgf/cm^2$ in the 28 days. The static test was carried out to measure the ultimate load, the initial load of flexural and diagonal cracking, crack patterns and fracture modes. Also, load-strain and load-deflection examined. During the test cracks were sketched against the load values according to the growth of crack. result are as follows; (1) The failure modes of the specimens are increased in rigidity and durability with mixing steel fiber and polymer. (2) The load of initial crack was similar a theory of shear-crack strength. (3) The deflection and strain at failure load of Polymer-steel fiber high strength concrete beams were increased, improving the brittleness of the high strength concrete.

계면활성제를 이용한 합성고분자 수용액의 마찰저항감소 및 퇴화 특성 향상 연구 (The Study on Drag Reduction Rates and Degradation Effects in Synthetic Polymer Solution with Surfactant Additives)

  • 이동민;김남진;윤석만;김종보
    • 설비공학논문집
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    • 제13권3호
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    • pp.194-199
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    • 2001
  • The turbulent flow resistance of water solution with polymer is reduced as compared with that of pure water. This effects is named th drag reduction and offers the significant reduction of the pumping power and the energy consumption. But the intense shear forces and the high temperature experienced by the polymer solution when passing through the pipes cause the degradation a loss of drag reduction effectiveness. Especially, the degradation behavior is found to be strongly dependent on temperature. This mechanical and thermal degradation can be avoided by adding materials such as surfactant to the polymer solution, which enhance the bonding force between molecules. In the present study, Copolymer and SDS were utilized and they were mixed in 10 different mixture ratios, while total concentration was fixed as 100wppm. Degradation of Copolymer-SDS mixture solutions was investigated experimentally in closed loop at the temperature of $10^{\circ}C\; and\; 80^{\circ}C$ with various flow average velocities of 1.5 m/sec, 3.0m/sec, and 4.5m/sec. Degradation characteristics of polymer solution without surfactant show a radical loss of drag reduction effectiveness at high temperature. Degradation alleviation ability of surfactant is especially effective at high temperature. Consequently, this results show that the addition of surfactant to the polymer solution can control unfavorable degradation phenomena for high temperature systems.

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일체형 재생연료전지 적용을 위한 sGO 함량 변화에 따른 sGO/sPEEK 복합막의 특성 평가 (The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell)

  • 정호영;김민우;임지훈;최진혁;노성희
    • KEPCO Journal on Electric Power and Energy
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    • 제2권1호
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    • pp.127-131
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    • 2016
  • Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPont's Nafion which is a commercial polymer electrolyte membrane has high permeability, high cost, and decreasing proton conductivity and dimensional stability over $80^{\circ}C$. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer electrolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane's water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.

HF-CT센서를 이용한 고분자애자의 오손특성 (Contamination Characteristics of Polymer Insulator using High Frequency Current Transformer)

  • 박재준
    • 정보학연구
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    • 제8권4호
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    • pp.1-7
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    • 2005
  • Investigations of high frequency current transformer(HF-CT) waveform characteristics of the surface leakage on kaolin polluted EPDM polymer insulators have been performed. This work is part of a program aimed at examining the potential for HF-CT waveform characteristics analysis to provide information about the environment contaminants and environment condition of polymer insulators. The investigation reported examined the HF-CT waveform characteristics at high frequencies. The use of high frequency measurements for on-line applications reduces electrical inference. This work was peformed utilizing HF-CT to monitor of surface polluted discharge. It was found that HF-CT waveform frequency spectrum, magnitude depend on importantly the duration of the surface discharge activity.

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EVA, EVCL 분말수지와 플라이애시를 혼입한 시멘트 모르타르의 고온특성 (High Temperature Properties of Cement Mortar Using EVA, EVCL Redispersible Polymer Powder and Fly Ash)

  • 송훈;신현욱
    • 한국건설순환자원학회논문집
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    • 제6권4호
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    • pp.365-372
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    • 2018
  • 건축물에서의 3D 프린팅은 구조재 및 비구조재로의 적용으로 구분되며, 비구조재는 내 외장 패널이나 조형물로의 적용 등이 주를 이룬다. 연속적으로 적층하여 제조하는 3D 프린팅 방식은 시멘트 모르타르의 경화속도나 특성을 개질하며 이를 위한 재료의 혼입과 경화속도나 시공성, 접착성의 개선을 위한 시멘트 혼화용 폴리머의 사용이 필수적이다. 본 연구는 적층방식 3D 프린팅 적용을 위해 시멘트, 플라이애시, EVA 및 EVCL 분말수지의 혼입률을 달리하여 고온에서의 특성을 검토하였고 혼입에 따른 유효성 여부를 확인하였다. 실험결과, EVA 및 EVCL 분말수지에 혼입에 따라 시멘트 모르타르는 연행된 공기에 의해 특성이 개질되었고 EVA보다는 EVCL을 혼입한 시험체가 고온에서 유리하였다.

고유동 폴리머시멘트모르타르의 건조수축 및 강도 특성 (Drying Shrinkage and Strength Properties of High-Fluidity Polymer-Modified Mortar)

  • 주명기;이윤수;정인수
    • 콘크리트학회논문집
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    • 제16권5호
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    • pp.651-657
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    • 2004
  • 본 연구에서는 재유화형 분말수지 혼입 고유동 폴리머 시멘트 모르타르의 공기량, 응결시간, 건조수축 및 강도특성에 미치는 분말소포제 첨가율 및 수축저감제 첨가량의 영향에 대하여 검토하였다. 그 결과, 재유화형 분말수지 혼입 고유동 폴리머시멘트 모르타르의 공기량은 분말소포제 첨가율 및 폴리머-시멘트비의 증가에 따라 감소하는 경향을 보였다. 재유화형 분말수지 혼입 고유동 폴리머 시멘트 모르타르의 응결시간은 분말소포제 첨가율에 관계없이 폴리머-시멘트비의 증가에 따라 늦어지는 경향을 보였다. 재유화형 분말수지 혼입 고유동 폴리머 시멘트 모르타르의 건조수축은 분말소포제 첨가율에 관계없이 폴리머-시멘트비 및 분말 수축저감제 첨가율의 증가에 따라 감소하는 경향을 보였다. 또한 분말소포제 첨가율 및 수축저감제 첨가율에 관계없이 재유화형 분말수지 혼입 고유동 폴리머 시멘트 모르타르의 휭 및 인장강도는 폴리머-시멘트비의 증가에 따라 증가하는 경향을 보였으나, 압축강도는 감소하는 경향을 보였다.

Linear and network structures of polymer electrolyte based on phosphate and polyether copolymers

  • Kim, Jun-Young;Kim, Seong-Hun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 가을 학술발표회논문집
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    • pp.232-235
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    • 1998
  • ion conducting polymers have been extensively investigated because of their potential application as an electrolyte in solid state batteries [1]. Among the polymer electrolytes, solid polymer electrolytes (SPEs) composed of ion conducting polymer and alkali metal salt have many advantages such as high ionic conductivity, high energy density and light weight. This made them suitable replacement for liquid electrolytes. (omitted)

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송배전용 고분자 애자의 설계와 열화시험 (The Design and Aging Test of Polymer Insulator for Power Transmission and Distribution)

  • 이운용;조한구;임기조
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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    • pp.553-555
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    • 2000
  • Recently polymer insulators are being used for outdoor high voltage applications. Polymer insulators for transmission line have significant advantages over porcelain and glass insulators, especially for ultra-high voltage(UHV) transmission lines. In this paper, the design trend and method polymer insulator are investigated and Aging test method is analysed to know life time of insulator.

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배전용 폴리머 현수애자의 설계해석 (The Design Analysis of Distribution Polymer Suspension Insulator)

  • 이운용;조한구;한동희;임기조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.66-68
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    • 2001
  • Recently polymer insulators are being used for outdoor high voltage applications. Polymer insulators for transmission and distribution line have significant advantages over porcelain and glass insulators, especially for ultra-high voltage(UHV) transmission lines. Their advantages are light weight, vandalism resistance and hydrophobicity. In this paper, distribution polymer suspension insulator has been designed and investigated electric field distribution by FEM.

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