• Journal of the Korean Society for Heat Treatment
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• v.27 no.3
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• pp.121-126
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• 2014

High-nitrogen Fe-18Mn-18Cr-N austenitic steels with higher yield strength have been recently developed and used for generator retaining rings because they have non-magnetic, high strength, high ductility, and good corrosion resistance. In the present study, a high-nitrogen Fe-18Mn-18Cr-0.61N austenitic steel was fabricated and then tensile and Charpy impact tests were conducted on them in order to investigate the effect of cold working on the mechanical properties. Although the yield and tensile strengths usually increased with cold working, the ductility and impact toughness significantly decreased after cold working. On the other hand, the high-nitrogen austenitic steel exhibited a ductile-brittle transition due to unusual brittle fracture at low temperatures despite having a face-centered cubic structure. The ductile-brittle transition temperature obtained from Charpy impact tests could be remarkably increased by $60^{\circ}C$ after 20% cold working because of the enhanced cleavage-like brittle fracture.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.2
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• pp.196-205
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• 2004

The cutting characteristics and the deformed layer of nitrogen(N)-added type 316LN stainless steel were comparatively investigated to type 316L stainless steel. The cutting force, the surface roughness(Ra) and the tool wear in face milling works were measured with cutting conditions, and the deformed layers were obtained from micro-hardness testing method. The cutting resistance of type 316LN was similar to type 316L in spite of its high strength. The surface roughness of type 316LN was superior to type 316L for all the cutting conditions. In particular, in the high cutting speed above 345m/min, the surface roughness of the two stainless steels was closely same. The deformed layer thickness of the two stainless steels was generated in the 150$\mu\textrm{m}$-300$\mu\textrm{m}$ ranges, and its value of type 316LN was lower than that of type 316L. This is due to the high strength properties by nitrogen effect. It was found that type 316LN was higher in the tool wear than that type 316L, and flank wear was dominant to crater wear. In face milling works of type 316LN steel, tool wear is regarded as a important problem.

• Journal of the Korean institute of surface engineering
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• v.51 no.4
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• pp.249-255
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• 2018

High temperature and low temperature gaseous nitriding was performed in order to study of the surface hardening and wear properties of the nitrided AISI 410 Martensitic stainless steels. High temperature gaseous nitiridng (HTGN) was carried out using partial pressure $N_2$ gas at $1,100^{\circ}C$ for 10 hour, and Low temperature gaseous nitiridng (LTGN) was conducted in a gas mixture of NH3 and N2 at $470^{\circ}C$ for 10 hour. The nitrided samples were characterized by microhardness measurements, optical microscopy and scanning electron microscopy. The phases were identified by X-ray diffraction and nitrogen concentration was analyzed by GD-OES. The HTGN specimen had a surface hardness of about $700HV_{0.1}$, $350{\mu}m$ of case depth. A ${\sim}50{\mu}m$ thick, $1,250HV_{0.1}$ hard nitrided case formed at the surface of the AISI 410 steel by LTGN, composed nitrogen supersaturated expanded martensite and ${\varepsilon}-Fe_{24}N_{10}$ iron nitrides. Additionally, the results of the wear tests, carried out LTGN specimen was low friction coefficient and high worn mass loss of ball. The increase in wear resistance can be mainly attributed to the increase in hardness and to the lattice distortion caused by higher nitrogen concentration.

• Advances in materials Research
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• v.13 no.3
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• pp.183-194
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• 2024

D3 tools steel and 440C stainless steel (SS) are normally being employed for application such as knife blade and cutting tools. These steels are iron alloys which have high carbon and high chromium content. In this study, lab work focused on the microstructural and corrosion behavior of D3 tools steel and 440C SS after went through heat treatment processes. Heat treatments for both steels were started with normalizing at 1020 ℃, continue with hardening at 1000 ℃followed by oil quenching. Cryogenic treatment was carried out in liquid nitrogen for 24 hours. The addition of cryogenic heat treatment is believed to increase the hardness and corrosion resistance for steels. Both samples were then tempered at two different tempering temperatures, 160 ℃ and 426 ℃. For corrosion test, the samples were immersed in NaCl solution for 30 days to study the corrosion behavior of D3 tool steel and 440C SS after heat treatment. The mechanical properties of these steels have been investigated using Rockwell hardness machine before heat treatment, after heat treatment (before corrosion) and after corrosion test. Microstructure observation of samples was carried out by scanning electron microscopy. The corrosion rate of these steels was calculated after the corrosion test completed. From the results, the highest hardness is observed for D3 tool steel which tempered at 160 ℃(54.1 HRC). In terms of microstructural analysis, primary carbide and pearlite in the as-received samples transform to tempered martensite and cementite after heat treatment process. From this research, for corrosion test, heat treated 440C SS sample tempered with 426 ℃possessed the excellent corrosion resistance with corrosion rate 0.2808 mm/year.

• Journal of the Korean Society for Heat Treatment
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• v.20 no.6
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• pp.311-317
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• 2007

This study examined the phase changes, nitride precipitation and variation in mechanical properties of STS 304, STS 321 and STS 316L austenitic stainless steels after high temperature gas nitriding (HTGN) at temperature ranges from $1050^{\circ}C\;to\;1150^{\circ}C$. Fine round type of $Cr_2N$ nitrides were observed in the surface layers of 304 and 316L steels, even more in STS 321. Additionally, square type of TiN was found in STS 321 austenitic matrix too. As a result of many precipitates in the surface layer of the STS 321, it was seen $370{\sim}470Hv$ hardness variation depending on the HTGN treatment conditions, and interior region of austenite represented 150Hv. The surface hardness value of STS 304 and STS 316L showed $255{\sim}320Hv$, respectively. The nitrogen content was shown 0.27, 1.7 and 0.4% respectively at the surface layers of the STS 304, STS 321 and STS 316L. After the HTGN it was shown the improvement of corrosion resistance of the STS 321 and STS 316L compared with solution annealed steels in the solution of 1N $H_2SO_4$ whereas the STS 304 was not.

• Transactions of Materials Processing
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• v.22 no.3
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• pp.165-170
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• 2013

High temperature deformation behavior of a heat-resistant duplex stainless steel, used as a retort in the Pidgeon process for Mg production, was investigated in this study. 25Cr-8Ni based duplex stainless steels were cast into rectangular ingots, with dimensions of $350mm{\times}350mm{\times}100mm$. Nitrogen and yttrium were added at 0.3wt.% each to enhance the heat-resistance of the steel. Phase equilibrium was calculated using the thermodynamic software FactSage$^{(R)}$ and the database of FSStel. For comparison, cast 310S steel, a widely used heat-resistant austenitic stainless steel, was also examined in this study. Dilatometry was conducted on the as-cast ingots for the temperature range from RT to $1200^{\circ}C$ and the thermal expansion coefficients were evaluated. The nitrogen addition was found to have an effect on the thermal expansion behavior for temperatures between 800 and $1000^{\circ}C$. High temperature tensile and compression tests were conducted on the ingots for temperatures ranging from 900 to $1230^{\circ}C$, which is the operation temperature employed in Mg production by the Silico-thermic reduction process. The steel containing both N and Y showed much higher strength as compared to 310S.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.2
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• pp.147-152
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• 2002

Carbon nitride thin films were deposited by reactive sputtering for the hard coating materials on Si wafer and tool steels. When the nitrogen content of carbon nitride film on tool steel is 33.4%, the mean hardness and elastic modulus are 49.34 GPa and 307.2 GPa respectively. The nitrided or carburised surface acts as the diffusion barrier which shows better adhesion of carbon nitride thin film on the steel surface. To prevent nitrogen diffusion from the film, steel substrate can be saturated by nitrogen forming a Fe$_3$N layer. The desirable structure at the surface after carburising is martensite, but sometimes, due to high carbon content an proeutectoid Fe$_3$C structure may form at the grain boundaries, leaving the overall surface brittle and may cause defects.

• Corrosion Science and Technology
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• v.5 no.5
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• pp.181-188
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• 2006

In this study, the characteristics of the experimentally produced high N-high Cr bearing stainless steels are discussed as a part of applications of materials for FGD (Fuel Gas Desulfurization) system of thermal power plants or for power plants using seawater as coolant. Corrosion resistance of developed alloys is especially investigated in detail. Corrosion characteristics of vacuum melted cast are shown to be superior to that of air melted one. From the viewpoint of CPT, It is estimated that the differences of corrosion resistance are $21.8^{\circ}C{\sim}24.6^{\circ}C$ at PRE 40 and $8^{\circ}C{\sim}12.4^{\circ}C$ at PRE 50, and the gaps becomes bigger as the PRE values are lower. In the evaluation of corrosion resistance in alloy A2501, Z3101, and A3301 according to Cr concentration, alloy A3301 shows a deviation from the general tendency in chloride solutions. It has relatively high PRE value as 48.6, but it has relatively poor pitting resistance. It is, however, difficult to observe a specific phase except ferrite in microstructure analysis and neither detects special phase such as sigma phase.

• Journal of Welding and Joining
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• v.19 no.3
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• pp.317-324
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• 2001

This study deals with high power Nd:YAG laser welding of thin steels for small pressure vessels. Full penetration welding at the overlap joint was performed so as to assure sufficient weld strength. Results showed that mid-depth weld size reduced drastically with increasing the travel speed. Position of focus had little effect on the bead formation even though short focal system was used. However, the shape factor and the bead width had closely related with the position of focus. Based on the microstructural inspection, acceptable weld was obtained when the overlap clearance was controlled up to 20% of the base metal thickness. In the case that the joint contained more clearance than the critical value, both the tensile shear strength and the tear strength were reduced. Results also demonstrated that shielding gases were proved to play a key role as far as the bead formation characteristics was taken into consideration. Blowing dry air through 5mm in diameter nozzle produced narrower bead cross-section than that of argon or nitrogen shielding.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.574-575
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• 2006

Due to the increasing use that the stainless steel is getting recently in the nuclear industry, this document proposes the study of the stainless steel 316L with boron addition. With the final product, the properties of the stainless steel 316L (good mechanical properties and high corrosion resistance) with the boron neutron absorption properties are claimed to unify. The P/M technologies allow adding higher boron quantities than with the solidification conventional technologies, where segregation is produced.