• Bulletin of the Korean Chemical Society
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• 제35권12호
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• pp.3465-3474
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• 2014

Porous silica particles are the most prevailing raw material for stationary phases of liquid chromatography. During a long period of time, various methodologies for production of porous silica particles have been proposed, such as crashing and sieving of xerogel, traditional dry or wet process preparation of conventional spherical particles, preparation of hierarchical mesoporous particles by template-mediated pore formation, repeated formation of a thin layer of porous silica upon nonporous silica core (core-shell particles), and formation of specific silica monolith followed by grinding and calcination. Recent developments and applications of useful porous silica particles will be covered in this review. Discussion on sub-$3{\mu}m$ silica particles including nonporous silica particles, carbon or metal oxide clad silica particles, and molecularly imprinted silica particles, will also be included. Next, the individual preparation methods and their feasibilities will be collectively and critically compared and evaluated, being followed by conclusive remarks and future perspectives.

• 정보처리학회논문지A
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• 제16A권5호
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• pp.307-318
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• 2009

컴퓨터 그래픽스에서 구름과 같은 대기 현상을 모델링하고 렌더링하는 것은 그 복잡성과 규모, 편재성 등으로 인해 상당히 까다로운 연구과제들 중의 하나이다. 본 논문은 컴퓨터 게임이나 항공 시뮬레이션 분야에서 요구되는, 실시간에 처리될 수 있는 구름 모델링과 렌더링 방법을 제안한다. 제안하는 방법은 사용자가 직관적이고 대화형 편집 과정을 거쳐 권운, 층운, 적운 등의 다양한 형태를 생성할 수 있다. 또한, 메타볼과 계층적 구형 파티클을 사용하여, 세부 묘사를 자동으로 추가할 수 있다. 생성된 파티클들은 다중 순방향 산란과 이방성 산란을 고려하여 빌보드 방식으로 출력함으로써 실시간 처리가 가능하다.

• 한국재료학회지
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• 제23권1호
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• pp.53-58
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• 2013

Superhydrophobic $SiO_2$ layers with a micro-nano hierarchical surface structure were prepared. $SiO_2$ layers deposited via an electrospray method combined with a sol-gel chemical route were rough on the microscale. Au particles were decorated on the surface of the microscale-rough $SiO_2$ layers by use of the photo-reduction process with different intensities ($0.11-1.9mW/cm^2$) and illumination times (60-240 sec) of ultraviolet light. With the aid of nanoscale Au nanoparticles, this consequently resulted in a micro-nano hierarchical surface structure. Subsequent fluorination treatment with a solution containing trichloro(1H,2H,2H,2H-perfluorooctyl)silane fluorinated the hierarchical $SiO_2$ layers. The change in surface roughness factor was in good agreement with that observed for the water contact angle, where the surface roughness factor developed as a measure needed to evaluate the degree of surface roughness. The resulting $SiO_2$ layers revealed excellent repellency toward various liquid droplets with different surface tensions ranging from 46 to 72.3 mN/m. Especially, the micro-nano hierarchical surface created at an illumination intensity of $0.11mW/cm^2$ and illumination time of 60 sec showed the largest water contact angle of $170^{\circ}$. Based on the Cassie-Baxter and Young-Dupre equations, the surface fraction and work of adhesion for the micronano hierarchical $SiO_2$ layers were evaluated. The work of adhesion was estimated to be less than $3{\times}10^{-3}N/m$ for all the liquid droplets. This exceptionally small work of adhesion is likely to be responsible for the strong repellency of the liquids to the micro-nano hierarchical $SiO_2$ layers.

• 한국표면공학회지
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• 제57권1호
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• pp.49-56
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• 2024

Superhydrophobic surfaces have been expected to be able to provide considerable performance improvements and introduce innovative functions across diverse industries. However, representative methods for fabricating superhydrophobic surfaces include etching the substrate or attaching nanosized particles, but they have been limited by problems such as applicability to only a few materials or low adhesion between particles and substrates, resulting in a short lifetime of superhydrophobic properties. In this work, we report a novel coating technique that can achieve superhydrophobicity by electrophoretic deposition of aluminum nitride (AlN) nanopowders and their self-bonding to form a surface structure without the use of binder resins through a hydrolysis reaction. Furthermore, by using a water-soluble adhesive as a temporary shield for the electrophoretic deposited AlN powders, hierarchical aluminum hydroxide structures can be strongly adhered to a variety of electrically conductive substrates. This binder-free technique for creating hierarchical structures that exhibit strong adhesion to a variety of substrates significantly expands the practical applicability of superhydrophobic surfaces.

• 한국대기환경학회지
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• 제13권5호
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• pp.345-353
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• 1997

The purpose of the study was to stastically classify individual PM-10 measured by SEM/EDX (scanning electron microscopy/energy dispersive x-ray analyzer). The SEM/EDX provided various physical parameters like optical diameter, as well as major 18 chemical information (Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb) for a particle-by-particle basis. The total of 1,419 particles were analyzed for the study. Thus density and mass of each particle can be estimated based on its chemical composition. Further the study developed 4 semisource profiles including highway, oil boiler, incinerator, and soil emissions, where each sample was collected near the source in the ambient air The profiles developed were consisted of mass fractions and their uncertainties based on a particle class concept. To obtain mass fraction of each particle class, an agglomerative hierarchical cluster analysis was initially applied to create particle classes for each sample. Then uncertainties were calculated for each class based on the jacknife method. The 1,258 particles out of 1,419 (88.7%) were assorted in newly generated particle classes. The study provides opportunities to identify particle's source quantitatively and to develope various receptor models.

• 한국전산구조공학회논문집
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• 제31권3호
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• pp.133-140
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• 2018

본 논문은 $Ni-A{\ell}_2O_3$로 구성된 금속-세라믹 이종 입자복합재의 2차원 미세구조(microstructure) 생성과 미세구조 스케일(scale)에 따라 정의되는 계층적 모델들의 역학적 특성 분석에 관한 내용이다. 이종 입자복합재의 미세구조는 수학적인 MDF(random morphology description functions) 모델링기법을 복합재의 2차원 RVE(representative volume element) 영역에 적용하여 생성하였다. 그리고 미세구조 생성에 필요한 가우스 함수들의 개수에 따라 미세구조의 계층적 모델을 정의하였다. 한편 임의 미세구조 내 금속과 세라믹 입자가 차지하는 체적분율(volume fraction)은 RMDF 함수의 레벨을 조정함으로서 설정하였다. RMDF기법에 의한 미세구조들은 가우스 함수들의 개수가 일정할지라도 랜덤하게 생성된다. 이렇게 랜덤하게 생성되는 미세구조들을 2차원 보(beam) 모델에 적용하여 미세구조의 스케일에 따른 수직응력과 전단응력의 계층적 변동을 수치 해석적으로 고찰하였다. 또한, 균열해석을 통해 RMDF의 랜덤성과 가우스 함수들의 개수가 균열선단에서의 응력값에 미치는 영향을 고찰하였다.

• 한국항공우주학회지
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• 제50권6호
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• pp.385-391
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• 2022

본 논문에서는 경사 하강법 기반의 경로 생성(GBPP)과 입자 군집 최적화(PSO)를 결합하여 3차원 공간에서 금지구역, 지형정보, 고정익 특성 등을 고려한 경로 생성 알고리즘을 제안한다. 기존의 GBPP 방법의 경우 빠르게 경로 생성이 가능하지만 초기 경로에 따라 지역적 최적 값에 빠져 안전하지 않은 경로가 생성될 수 있다. 유전 알고리즘(GA)과 PSO 등 생물학에서 영감을 받은 군집 지능 알고리즘들의 경우 다양한 경로들을 샘플링하여 지역적 최적 값 문제를 해결할 수 있다. 다만 무인기와 경로점 개수가 증가하여 최적 변수가 증가할 경우 군집 개수를 늘려야 하고 계산 시간이 크게 증가한다. 두 알고리즘 단점을 보완하고자 본 연구에서는 GBPP 입력 값인 초기경로를 수평, 수직 방향에 대한 변위 두 가지 변수로 정의하고 이를 PSO 변수로 정의하여 계층적 경로 최적화 알고리즘 HPSO를 제안한다. 제안한 알고리즘은 통용되는 비행 제어 컴퓨터(FCC)의 software-in-the-loop simulation(SILS)을 사용하여 고정익 무인기에 대한 사용 가능성을 검증하였다.

• 천문학회보
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• 제37권1호
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• pp.44.2-44.2
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• 2012

Cosmological shock waves result from supersonic flow motions induced by hierarchical clustering during the large-scale structure formation in the Universe. Suprathermal particles are known to be produced via plasma interactions at collisionless shocks in tenuous plasmas and they can be further accelerated to become cosmic rays (CRs) via diffusive shock acceleration (DSA). The presence of CR electrons has been inferred from observations of diffuse radio halos and relics in some merging galaxy clusters. We have calculated the emissions from CR electrons accelerated at weak planar shocks, using time-dependent DSA simulations that include energy losses via synchrotron emission and Inverse Compton scattering. The simulated nonthermal emission are used to model the synchrotron emission from several observed radio relics.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 2006년 제4회 한국유체공학학술대회 논문집
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• pp.383-386
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• 2006

In this study, we propose a new fast algorithm for calculating short range forces in molecular dynamics, This algorithm uses a new hierarchical tree data structure which has a high adaptiveness to the particle distribution. It can divide a parent cell into k daughter cells and the tree structure is independent of the coordinate system and particle distribution. We investigated the characteristics and the performance of the tree structure according to k. For parallel computation, we used orthogonal recursive bisection method for domain decomposition to distribute particles to each processor, and the numerical experiments were performed on a 32-node Linux cluster. We compared the performance of the oct-tree and developed new algorithm according to the particle distributions, problem sizes and the number of processors. The comparison was performed sing tree-independent method and the results are independent of computing platform, parallelization, or programming language. It was found that the new algorithm can reduce computing cost for a large problem which has a short search range compared to the computational domain. But there are only small differences in wall-clock time because the proposed algorithm requires much time to construct tree structure than the oct-tree and he performance gain is small compared to the time for single time step calculation.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.200-200
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• 2011

Hierarchical mesoporous ZSM-5 with enhanced mesoporosity was synthesized by microwave through the rapid assembly via ionic interaction between sulfonic acid functionalized ZSM-5 nano particles and cationic surfactant. The catalytic performance of enhanced accessibility due to mesoporosity and acidity were investigated in the alkylation of mesitylene with benzyl alcohol as alkylating agent. The effect of mole ratio of aromatic with benzyl alcohol, reaction time and alkylation agent were also studied. The enhanced mesoporosity and acidity of sulfonic acid functionalized mesoporous ZSM-5 induced activity enhancement compared with non-functionalized mesoporous ZSM-5, sulfonic functionalized mesoporous ZSM-5 synthesized by hydrothermal method and conventional microporous ZSM-5. The sulfonic acid functionalized mesoporous ZSM-5 showed much higher chemoselectivity of benzylated mesitylene than others, whereas the others mainly show dibenzyl ether as product. This significant difference in catalytic selectivity was resulted from the existence of mesopores, which definitely allowed the benzylation in mesopores.