• Title/Summary/Keyword: Hi-carbon

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Nam, Woo-Seok;Jung, Jae-Uk;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.388-391
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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Improved Field Emission by Liquid Elastomer Modification of Screen-Printed CNT Film Morphology

  • Lee, Hyeon-Jae;Lee, Yang-Doo;Cho, Woo-Sung;Kim, Jai-Kyeong;Lee, Yun-Hi;Hwang, Sung-Woo;Ju, Byeong-Kwon
    • Journal of Information Display
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    • v.7 no.2
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    • pp.16-21
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    • 2006
  • The effect of improvement on the surface morphology of screen-printed carbon nanotube (CND) films was studied by using the optically clear poly-dimethylsiloxane (PDMS) elastomer for surface treatment. After the PDMS activation treatment was applied to the diode-type CNT cathode, the entangled carbon nanotube (CNT) bundles were broken up into individual free standing nanotubes to remarkably improve the field-emission characteristics over the as-deposited CNT film. Also, the cathode film morphology of a top gated triode-type structure can be treated by using the proposed surface treatment technique, which is a low-cost process, simple process. The relative uniform emission image showed high brightness with a high anode current. This result shows the possibility of using this technique for surface treatment of large-size field emission displays (FEDs) in the future.

Field Emission Properties of Screen Printed Carbon Nanotubes (스크린 프린팅된 탄소나노튜브의 전계방출 특성)

  • Lee, Yang-Doo;Lee, Jung-Ah;Moon, Seung-Il;Park, Jeung-Hoon;Han, Jong-Hun;Yoo, Jae-Eun;Lee, Yun-Hi;Nahm, Sahn;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.541-544
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    • 2004
  • Multi- wall carbon nanotubes(MWNTs) were synthesized by thermal chemical vapor deposition. The paste for screen printing was composed of MWNTs, organic vehicle and glass frit. Carton nanotube paste was screen-printed on ITO(indium tin oxide) deposited soda lim을 glass, and then heat treatment was performed. Before the surface treatment, turn on field of derive was 2.6 V/$\mu\textrm{m}$. After the surface treatment, the value was changed into 1.8 V/$\mu\textrm{m}$. The anode current of the derive with 2.83 V/$\mu\textrm{m}$(turn on field) was changed 4 $\mu\textrm{A}$ into 390 $\mu\textrm{A}$ at 1,700 V. Adsorption effect of MWNTs onto phosphor of anode plate was observed by the field emission measurement and resulted in bad effects on properties of devices lifetime and emission lighting.

Isolation of Yeasts utilizing Phthalic Compounds as a Sole Carbon Source (프탈산 화합물을 탄소원으로 이용하는 효모의 분리 및 동정)

  • Lee, Young-Nam;Yu, Jeong-Hi;Lee, Sang-Sun
    • The Korean Journal of Mycology
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    • v.19 no.1
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    • pp.41-46
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    • 1991
  • Three isolates of yeast utilizing phthalic compounds as a sole carbon source were obtained from the surface waters exposed to the industrial effluents near Cheong Ju city. On the basis of microscopic observations on morphology and various biochemical characterizations, the three isolates were identifed as a species of Rhodotorula. Candida or Torulopsis. A number of aroma­tic chemicals including phthalic compounds would support the growth of these yeasts as a sole carbon source, Thus, the yeast isolates would have potentials in reduction of environmental burden due to industrial wastes of aromatic hydrocarbons.

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Characterization of ptsHI Operon from Leuconostoc mesenteroides SY1, a Strain Isolated from Kimchi

  • Park Jae-Yong;Jeong Seon-Ju;Chun Ji-Yeon;Lee Jong-Hoon;Chung Dae-Kyun;Kim Jeong-Hwan
    • Journal of Microbiology and Biotechnology
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    • v.16 no.6
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    • pp.988-992
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    • 2006
  • The ptsHI operon from Leuconostoc mesenteroides ssp. mesenteroides SY1 (L. mesenteroides SY1), a strain isolated from kimchi, was cloned and characterized. The ptsH open reading frame (ORF) was 273 bp in size, which can encode a protein of 90 amino acid residues with a molecular weight of 9,212 Da. The pfsI ORF was 1,719 bp in size, which was capable of encoding a protein of 572 amino acids with a molecular mass of 62,549 Da. ptsH and pfsI genes were transcribed as a single transcript of 2.0 kb in size regardless of carbon sources, supporting the operon structure. Although the deduced amino acid sequences of the HPr and EI were highly homologous with those of other Gram-positive bacteria, an additional amino acid (glutamine at the $3^{rd}$ amino acid) was present in HPr from L. mesenteroides SY1. Phosphorylation sites of HPr included the histidine residue ($16^{th}$) and serine residue ($47^{th}$). Mutant HPrs, in which each phosphorylation site was mutated into alanine, were obtained, and phosphorylation with HPr and mutated HPrs showed that HPr was phosphorylated at the serine residue ($47^{th}$) by HPr kinaseiphosphorylase (HPr K/P).

Climatic Changes During the Past 400,000 Years

  • Yi, HI-Il;Shin, Im-Chul
    • The Korean Journal of Quaternary Research
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    • v.18 no.2 s.23
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    • pp.23-31
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    • 2004
  • Temperature variations, and carbon dioxide and methane concentrations are summarized during the past 400,000 years. Atmospheric temperature varied approximately within $10^{\circ}C$ during the past 400,000 years. Most of the time during the past 400,000 years, temperature was lower than today except 410000, 320000, 250000, and 125000 years ago. Temperature was slightly higher or at least similar to today during the time period of 410000. 320000, 250000, and 125000 years ago. The carbon dioxide concentration varied between 180 and 300 ppm, and the methane concentration varied between 40 and 700ppb. The present atmospheric concentration of carbon dioxide is 375 ppm and methane is 1750 ppb. Temperature was 5-$7^{\circ}C$ lower than today during the Last Glacial Maximum(18,000 years ago) and the Younger Dryas(10,000 years ago). Temprature was varied within $1^{\circ}C$ during the past 10,000 years. Especially Middle Holocene Climatic Optimum(6,000 years ago), Medieval Warm Period (500-1,000 years ago), and Little Ice Age(100-500 year ago) were global climatic events. In general, mechanism for the Middle Holocene Climatic Optimum, Medical Warm Period, and Little Ice Age can be explained by the solar insulation, however their exact mechnism is not well known. Carbon dioxide concentration during the past 400,000 years never reached the current value of 375 ppm. Furthermore, the current methane concentration never reached during the past 20Ma. However, current temperature value has happened several times during the past 400,000 years. The implication of this is unsolved question so far. This should be challenged in the near future.

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Vacuum Carburizing System for Powdered Metal Parts & Components

  • Kowakewski, Janusz;Kucharski, Karol
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1018-1021
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    • 2006
  • Powdered metal parts and components may be carburized successfully in a vacuum furnace by combining carburizing technology $VacCarb^{TM}$ with a hi-tech control system. This approach is different from traditional carburizing methods, because vacuum carburizing is a non-equilibrium process. It is not possible to set the carbon potential as in a traditional carburizing atmosphere and control its composition in order to obtain a desired carburized case. This paper presents test results that demonstrate that vacuum carburizing system $VacCarb^{TM}$ carburized P.M. materials faster than traditional steel with acceptable results. In the experiments conducted, PM samples with the lowest density and open porosity showed a dramatic increase in the surface carbon content up to 2.5%C and a 3 times deeper case. Currently the boost-diffusion technique is applied to control the surface carbon content and distribution in the case. In the first boost step, the flow of the carburizing gas has to be sufficient to saturate the austenite, while avoiding soot deposition and formation of massive carbides. To accomplish this goal, the proper gas flow rate has to be calculated. In the case of P.M. parts, more carbon can be absorbed by the part's surface because of the additional internal surface area created by pores present in the carburized case. This amount will depend on the density of the part, the densification grade of the surface layer and the stage of the surface. "as machined" or "as sintered". It is believed that enhanced gas diffusion after initial evacuation of the P.M. parts leads to faster carburization from within the pores, especially when pores are open . surface "as sintered" and interconnected . low density. A serious problem with vacuum carburizing is delivery of the carbon in a uniform manner to the work pieces. This led to the development of the different methods of carburizing gas circulation such as the pulse/pump method or the pulse/pause technique applied in SECO/WARWICK's $VacCarb^{TM}$ Technology. In both cases, each pressure change may deliver fresh carburizing atmosphere into the pores and leads to faster carburization from within the pores. Since today's control of vacuum carburizing is based largely on empirical results, presented experiments may lead to better understanding and improved control of the process.

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Photoalteration in Biodegradability and Chemical Compositions of Algae- derived Dissolved Organic Matter (자외선에 의한 조류기원 용존유기물의 생분해도 및 화학조성변환.)

  • Imai, Akio;Matsushige, Kazuo;Nagai, Takashi;Kim, Yong-Hwan;Kim, Bom-Chul;Choi, Kwang-Soon
    • Korean Journal of Ecology and Environment
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    • v.36 no.3 s.104
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    • pp.235-241
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    • 2003
  • The effect of ultraviolet (UV) radiation on the characteristics of algae-derived dissolved organic matter (DOM) was examined by comparing the biodegradability and DOM fraction distribution of algal DOM before and after UV exposure. Algal DOM from two axenic cultures of Microcystis aeruginosa and Oscillatoria agardhii were irradiated for 24 h at a UV intensity of 42 W/$m^2$. A complete degradation of algal DOM during the UV exposure did not occur, remaining at constant concentrations of dissolved organic carbon(DOC). After UV exposure, however, microbial degradations were reduced by 17% in M. aeruginosa and 53% in O. agardhii, respectively, and decomposition rates also were two times lower in UV exposed algal DOM. In addition, the chemical compositions of algal DOM altered substantially after UV radiation exposure. The proportions of hydrophilic bases (HiB; protein-like DOM) decreased considerably in both algal DOM sources after UV exposure (16.8% and 20.0% of DOM, respectively), whereas those of hydrophilic acids (HiA; carboxylic acids-like DOM) increased as much as the decrease of the HiB fraction. Capillary ion electrophoresis (CE) analysis showed that several carboxylic acids increased significantly after UV exposure, further confirming an increase in HiA fractions. The results of this study clearly indicate that algal DOM can be changed in its chemical composition as well as biodegradability without complete degradation by UV radiation.

Study on technique development for the solidified body of rock waste and evaluation of fracture toughness (암석폐재의 고화체 합성기술의 개발과 파괴인성평가에 관한 연구)

  • Na, Eui-Gyun;Yu, Hyosun;Kim, Jin-Yong;Lee, Jeong-Gee;Chung, Se-Hi
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.9
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    • pp.1452-1461
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    • 1997
  • The hot press apparatus to obtain the solidified rocks with 60mm of diameter against rock waste was developed, and the optimum conditions for solidification were founded out, of which were 300.deg. C of temperature and 1hr of holding time. The solidified rocks reinforced with the fibers (carbon, steel) were made by means of a hydrothermal hot press method. Fracture toughness of those was obtained using the round compact tension(RCT) specimens. Load and displacement behaviours of the solidified rocks reinforced with the fibers were dependent upon the fiber volume fraction and kind of the fibers. Strength and fracture energy of the solidified rocks with steel were much larger than those of the solidified ones with carbon because of the Bridge's effect, multiple cracking and crack branching phenomena.

Fabrication of Mo-tip Field Emitter Array and Diamond-like Carbon Coating Effects (몰리브덴 팁 전계 방출 소자의 제조 및 다이아몬드 상 카본의 코팅효과)

  • Ju, Byeong-Kwon;Jung, Jae-Hoon;Kim, Hoon;Lee, San-Jo;Lee, Yun-Hi;Tchah, Kyun-Hyon;Oh, Myung-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.7
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    • pp.508-516
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    • 1998
  • Mo-tip field emitter arrays(FEAs) were fabricated by conventional Spindt process and their life time characteristics and failure mode were evaluated. The fabricated Mo-tip FEA could generate at least $0.35\{mu} A/tip$ emission current for about 320 persistently under a constant gate bias of 140 V and was finally destroyed through self-healing mode. Thin diamond-like carbon films were coated on the M-tip by plasma-enhanced CVD and the dependence of emission properties upon the DLC thickness was investigated. By DLC coating, the turn-on voltage and emission current were appeared to be improved whereas the current fluctuation was increased in the DLC thickness range of $0~1,000\{AA}$.

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