• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.128-128
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• 2013

Fabrication of heterogeneous catalysts using Atomic Layer Deposition (ALD) has recently been attracting attention of surface chemists and physicists. In this talk, I will present recent results about structures and chemical activities of various catalysts prepared by ALD, particularly focusing on Ni-based catalysts. Ni has been considered as potential catalysts for $CO_2$ reforming of methane (CRM); however, Ni often undergoes rapid decrease in catalytic activity with time, and therefore, application of Ni as catalysts for CRM has been regarded as difficult so far. Deactivation of Ni catalysts during CRM reaction is from either coke formation on Ni surface or sintering of Ni particles during reaction. Two different strategies have been used for enhancing stability of Ni-based catalysts; $TiO_2$ nanoparticles were deposited on micrometer-size Ni particles by ALD, which turned out to reduce coke formation on Ni surfaces. Ni nanoparticles deposited by ALD on mesoporous silica showed high activity and long-term stability from CRM without coke deposition and sintering during CRM reaction. Ni-based catalysts have been also used for oxidation of toluene, which is one of the most notorious gases responsible for sick-building syndrome. It was shown that onset-temperature of Ni catalysts for toluene oxidation is as low as $120^{\circ}C$. At $250\circ}C$, total oxidation of toluene to $CO_2$ with a 100% conversion was found.

• The Korean Journal of Ceramics
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• 제3권1호
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• pp.5-12
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• 1997

Charged carbon clusters which are formed by the gas activation are suggested to be responsible for the formation of the metastable diamond film. The number of carbon atoms in the cluster that can reverse the stability between diamond and graphite by the capillary effect increases sensitively with increasing the surface energy ratio of graphite to diamond. The gas activation process produces charges such as electrons and ions, which are energetically the strong heterogeneous nucleation sites for the supersaturated carbon vapor, leading to the formation of the charged clusters. Once the carbon clusters are charged, the surface energy of diamond can be reduced by the electrical double layer while that of graphite cannot because diamond is dielectric and graphite is conducting. The unusual phenomena observed in the chemical vapor deposition diamond process can be successfully approached by the charged cluster model. These phenomena include the diamond deposition with the simultaneous graphite etching, which is known as the thermodynamic paradox and the preferential formation of diamond on the convex edge, which is against the well-established concept of the heterogeneous nucleation.

• Bulletin of the Korean Chemical Society
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• 제34권5호
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• pp.1445-1453
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• 2013

$Zn_{(1-x)}Ni_xAl_2O_4$ (x = 0.0-1.0) spinels were prepared at $800^{\circ}C$ by co-precipitation method and characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. The specific surface area was determined by BET. SEM image showed nano sized spherical particles. XPS confirmed the valence states of the metals, showing moderate Lewis character for the surface of materials. The powders were successfully used as new heterogeneous catalysts of Biginelli's reaction, a one-pot three-component reaction, leading to some dihydropyrimidinones (DHPMs). These new catalysts that produced good yields of DHPMs, were easily recovered by simple filtration and subsequently reused with persistent activity, and they are non-toxic and environmentally friendly. The optimum amount of catalyst is 20% by weight of benzaldehyde derivatives, while the doping amount has been found optimal for x = 0.1.

• 한국표면공학회지
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• 제34권5호
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• pp.499-502
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• 2001

Functionally gradient NiCrAlY/$ZrO_2$-$Y_2$$O_3$ and NiCrAlY/$ZrO_2$- $CeO_2$-$Y_2$$O_3$ coatings were prepared by APS. The as-sprayed microstructure consisted of metal-rich and ceramic-rich regions, between which $Al_2$$O_3$-rich layers existed owing to the oxidation during APS. During oxidation between 900 and $1100^{\circ}C$ in air, the pre-existing $Al_2$$O_3$-rich scales grew, due mainly to the preferential reaction of Al with inwardly transporting oxygen along the heterogeneous phase boundaries. As the amount of ceramics in the coating increased, the oxidation resistance increased.

• 한국해양공학회지
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• 제29권3호
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• pp.249-254
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• 2015

Buoys are widely used in marine areas because they can mark positions and simultaneously acquire and exchange underwater, surface, and airborne information. Recently, the need for controlling and optimizing a buoy's position and attitude has been raised to achieve successful communication in a heterogeneous collaborative network composed of an underwater robot, a surface robot, and an airborne robot. A buoy in the form of a marine robot would be ideal to address this issue, as it can serve as a moving node of the communication network. Therefore, a buoy-based autonomous surface robot-kit with the abilities of sonar-based avoidance, dynamic position control, and static attitude control was developed and is discussed in this paper. The test and evaluation results of this kit show the possibility of real-world applications and the need for additional studies.

• Nuclear Engineering and Technology
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• 제28권1호
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• pp.44-55
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• 1996

원자력 발전소에서 방사성 요오드를 제거하기 위해 사용되는 원료활성탄과 2%, 5%TEDA(Triethylene-Diamine) 첨착활성탄을 이용하여 원소요오드와 유기요오드인 메틸요오드에 대한 흡착특성을 분석하였다. 여러 흡착 등온식을 선정하여 실험치와 비교함으로서 선정된 흡착 등온식의 적합성 여부를 검증하였다. 흡착평형 실험결과 Dubinin-Astakhov(DA) 등온식이 여러 가지 흡착등온식 가운데 가장 적합한 것으로 나타났다. 흡착표면의 흡착에너지 분포가 불균일(Heterogeneous)하기 때문에 포텐셜 (Potential) 에너지를 근거로 하는 DA등온식이 흡착평형 관계를 보다 정확하게 나타내는 것으로 생각된다. 흡착표면의 불균일성을 확인하기 위해 흡착에너지 분포도를 원료활성탄과 첨착활성탄에 대해 상호 비교하였다 활성탄-요오드 흡착시스템에서 불균일성은 활성탄의 기공구조 분만 아니라 흡착질과 활성탄과의 상호관계에 의해서도 영향을 받게된다 따라서 흡착표면의 불균일성은 활성탄을 첨착함에 따라서 증가하게 되고 원소요오드보다 유기요오드의 경우 불균일성이 더 커지는 것으로 보여진다.

• Nuclear Engineering and Technology
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• 제21권3호
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• pp.193-204
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• 1989

본 논문에서는 정보 이론의 maximum entropy Principle을 이용하여 중성자속 분포를 재생하는 새로운 방법을 시도하였다. 어떤 대상에 대한 부분적인 정보가 있을 때, 이 정보의 한도 내에서 entropy를 최대화시키는 확률 분포는 가장 객관적인 것이 된다. Nodal method계산결과인 평균 중성자속과 current의 값을 prior information으로 삼고, 핵 연료 집합체의 경계에서의 중성자속 분포를 확률의 형태로 변환해서 확률로써 다룬다. Prior information의 한도 내에서 entropy를 최대화시키는 경계에서의 확률 분포를 구하면 핵연료 집합체의 경계에서의 중성자속 분포가 구해지는데, 이것을 경계조건으로 heterogeneous assembly calculation을 행하여 세부적인 중성자속 분포를 구한다. 이 새로운 방법을 몇 개의 benchmark problem assembly에 응용해 본 결과, 노심의 안쪽 부분에서는 이 방법이 form function method에 의한 것과 비슷한 정확도를 보였고 바깥 부분에서는 다소 큰 오차를 보였다. 본 논문에서는 surface-averaged neutron current를 prior in-formation에 포함시키지 못했는데, 이것을 포함시키면 결과가 훨씬 개선 될 것으로 보인다.

• 한국정보통신학회:학술대회논문집
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• 한국정보통신학회 2021년도 춘계학술대회
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• pp.186-188
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• 2021

본 아키텍처(IDPS)는 현 해군 수상함 전투체계의 함정별 소프트웨어 진단 도구를 통합하여 진단 방식의 일관성과 효율성, 진단 소요 시간의 감소를 달성하기 위한 웹기반의 플랫폼을 구축하는 구조적 방법이다. 함형 별 구분된 독립적인 진단 방식으로 인하여 수명주기지원(LTS) 시 인력 운용 측면의 비효율성과 진단자의 숙련도 등에 따른 진단 품질의 차이가 발생하기 때문에, 함정 SW 상태를 진단하는 방식을 함형에 구분없이 일원화하고 진단자에 따른 진단 결과의 편향과 오차가 발생하지 않도록 진단데이터를 플랫폼에 내재된 상태결정알고리즘(SDA)에 의해 판정하도록 지능화하였다. 장기적으로 수상함 전투체계 소프트웨어의 진단에 있어 진단 품질의 하락없는 사람 개입이 최소화된 지능화된 시스템 구축을 추구하며, 이를 통해 진단 소요 시간을 단축하고 진단 결과의 활용에 더 많은 자원을 투입할 수 있을 것으로 기대된다.

• Bulletin of the Korean Chemical Society
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• 제26권11호
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• pp.1819-1822
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• 2005

In the search for a simple preparation method of heterogeneous catalyst, the iron porphyrins were coordinated bonded to the surface of a polymeric core-shell nanosphere. The heterogeneous catalyst was characterized by FT-IR, scanning electron microscope, and UV-vis spectrophotometer. The iron porphyrin bound core-shell nanospheres was about 470 nm in diameter and their catalytic activity for cyclohexene oxidation was similar to a homogeneous iron porphyrin in a solvent composition range of 25-75% acetonitrile/water (v/v). In addition, they could be recovered by simple centrifugation and their catalytic activity was maintained more than the third cycle.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2748-2752
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• 2012

Cr(III) and Co(III) complexes with acetylacetonate were anchored onto a mesoporous MCM-41 through Schiff condensation. The materials were characterized by XRD, FT-IR, BET, CHN and ICP techniques. Elemental analysis of samples revealed that one C=N bond was formed through Schiff condensation on MCM-41 surface. The catalysts were tested for the alcohol oxidations using t-butyl hydroperoxide (TBHP) and $H_2O_2$ as oxidant. The catalytic experiments were carried out at both room temperature and reflux condition. Various solvents such as dichloromethane, acetonitrile and water were examined in the oxidation of alcohols. Among the different solvents, catalytic activity is found more in acetonitrile. Further, the catalysts were recycled three times in the oxidation of alcohols and no major change in the conversion and selectivity is observed, which shows that the immobilized metal-acetylacetonate complexes are stable under the present reaction conditions.