• 분석과학
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• 제37권1호
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• pp.63-78
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• 2024

The continuous increasing of the global demand of copper and nickel metals raises the interest in developing alternative technologies to produce them from copper sulfide ore. Also, in line with Egypt's vision 2030 for achieving the sustainable socioeconomic development which aims at developing alternative and eco-friendly technologies for processing the Egyptian ores to produce these strategic products instead of its importing. These metals enhance the advanced electrical and electronic industries. The current work aims at investigating the recovery of copper and nickel from Abu Swayeil copper ore using pug leaching technique by sulfuric acid. The factors affecting the pug leaching process including the sulfuric acid concentration, leaching time and temperature have been investigated. The copper ore sample was characterized chemically using X-ray fluorescence (XRF) and scanning electron microscope (SEM-EDX). A response surface methodology develops a quadratic model that expects the nickel and copper leaching effectiveness as a function of three controlling factors involved in the procedure of leaching was also investigated. The obtained results showed that the maximum dissolution efficiency of Ni and Cu are 99.06 % and 95.30%, respectively which was obtained at the following conditions: 15 % H₂SO₄ acid concentration for 6 hr. at 250 ℃. The dissolution kinetics of nickel and copper that were examined according to heterogeneous model, indicated that the dissolution rates were controlled by surface chemical process during the pug leaching. The activation energy of copper and nickel dissolution were 26.79 kJ.mol^-1 and 38.078 kJ.mol^-1 respectively; and the surface chemical was proposed as the leaching rate-controlling step.

• 마이크로전자및패키징학회지
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• 제11권3호
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• pp.77-82
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• 2004

본 연구에서는 고유전율(K100) 및 저유전율(K7.8) LTCC(Low Temperature Co-fired Ceramics) 그린 시트를 이종 LTCC 기판으로 동시 소성하는 경우, 고유전율 LTCC 내의 유리 분말 함유량에 따라 발생하는 수축 거동 변화가 이종 LTCC기판의 휨 특성에 미치는 영향에 대하여 평가하였다. 유리 분말 함유량의 증가에 따른 고유전율 LTCC 그린시트의 수축률 및 유전 특성을 측정하였으며, 고유전율/저유전율 비대칭형 적층체의 소결 거동을 고온 현미경을 이용하여 실시간으로 측정하였다. $50\%$ 유리가 첨가된 K100 조성의 경우 수축 개시 온도 및 수축 구간의 범위 , 최종 수축률이 K7.8 조성과 유사하였으며, 동시 소성 시 가장 우수한 휨 특성을 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1720-1726
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• 2014

(S)-Alanine Racemase Chiral Analogue ((S)-ARCA) was used as an efficient adsorbent for the selective separation of D-amino acids (D-AAs), which are industrially important as chiral building blocks for the synthesis of pharmaceutical intermediates. The organic phase, containing (S)-ARCA adsorbent and phase transfer reagents, such as ionic liquid type molecules (Tetraphenylphosphonium chloride (TPPC), Octyltriphenylphosponium bromide (OTPPBr)), were coated on the surfaces of mesoporous carbon supports. For the immobilization of chiral adsorbents, meso/macroporous monolithic carbon (MMC), having bimodal pore structures with high surface areas and pore volumes, were fabricated. The separation of chiral AAs by adsorption onto the heterogeneous (S)-ARCA was performed using a continuous flow type packed bed reactor system. The effects of loading amount of ARCA on the support, the molar ratio of AA to ARCA, flow rates, and the type of phase transfer reagent (PTR) on the isolation yields and the optical purity of product D-AAs were investigated. D-AAs were selectively combined to (S)-ARCA through imine formation reaction in an aqueous basic solution of racemic D/L-AA. The (S)-ARCA coated MMC support showed a high selectivity, up to 95 ee%, for the separation of D-type phenylalanine, serine and tryptophan from racemic mixtures. The ionic liquids TPPC and OTPPBr exhibited superior properties to those of the ionic surfactant Cetyltrimethyl ammonium bromide (CTAB), as a PTR, showing constant optical purities of 95 ee%, with high isolation yields for five repeated reuses. The unique separation properties in this heterogeneous adsorption system should provide for an expansion of the applications of porous materials for commercial processes.

• 한국전산구조공학회논문집
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• 제26권4호
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• pp.213-221
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• 2013

이 논문에서는 반무한 고체영역의 표면에서 측정한 변위응답의 시간이력으로부터 유한요소망 연속기법을 이용해 탄성파 속도의 공간적 분포를 추정하는 역해석 문제를 소개한다. 반무한 영역에서의 역해석을 위해서는 해석 대상이 되는 유한영역의 경계에서 파동의 반사가 일어나지 않도록 하는 것이 중요하다. 이를 위해 유한영역의 경계면에 perfectly-matchedlayers(PMLs)라는 수치적 파동흡수층을 도입하였고, PML을 경계로 하는 유한영역에서 역해석 문제를 정의하였다. 이 문제를 탄성파동방정식을 구속조건으로 하는 최적화 문제로 표현하였으며, 라그랑주 승수법에 기초한 비구속 최적화 기법에 의해 탄성파속도의 최적 분포를 결정하였다. 해의 정확도와 수렴성을 높이기 위해 유한요소망 연속기법을 도입하여 점진적으로 밀도가 증가하는 유한요소망에 대해 연속적으로 역해석을 수행하였다. 1차원 예제들을 통해 유한요소망 연속기법을 이용한 역해석으로부터 탄성파속도의 분포를 정확히 추정할 수 있음을 확인하였으며, 측정 응답에 노이즈가 존재하는 경우에도 제안한 역해석 기법은 목표 탄성파속도 분포에 근사한 결과를 도출하였다.

• Journal of Radiation Protection and Research
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• 제27권1호
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• pp.67-75
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• 2002

지표 토양 환경내 오염물 거동 해석을 위하여 지하수 유동 및 오염물 이동 수치모델을 수립하였다. 수치모델의 검증 및 현장 적용성 검사를 위하여 해석해와 상호 비교하였다. 계산결과 지하수 유동 및 오염물 이동의 수치해는 해석해와 잘 일치하였다. 특히 지하수 유동의 1차원 및 2차원 비균질 매질에서 수치해가 검증됨 따라 실제 현장 적용시 존재하는 비균질 매질의 특성을 잘 재현할 것으로 판단된다. 또한 오염물 이동 수치모델의 계산결과 이류와 수력학적 분산에 의해 토양내의 오염물 이동이 잘 재현되었다. 수치모델의 운영 결과 모델의 중요한 입력항은 복잡한 경계조건의 선택으로 이들의 적절한 선택이 모델 결과에 중요한 영향을 주고 있음이 나타났다.

• 한국실내디자인학회논문집
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• 제6호
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• pp.45-52
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• 1995

The presentation of the method by which the furniture and the architecture can be unified in one category, and the study and the verification on the mutual relation in the shape and the function are having been consistently made till the late twenties. The change of the social structure such as increasing the unit dwelling space with the small scale comes to need the efficiency in using space and the open dwelling space by the systematic spa-cial formation. Therefore, the understanding of the mean-ing and the characteristics of system furnitures as the design method which can meet such needs will be made here in this study. The application of the systematic consideration as the method of interior design means the formation of the firm image on the spacial environment through the mix-ture and link of the heterogeneous factors, the organic connection of each surface, the establishment of the natu-ral relation by linking the heterogeneous materials mutu-ally. and the easiness of the entire plan in the end. This study aims at analyzing and studying the typical charac-teristics by understanding the historical background and methodical principle which enabled the appearance of this kind of thought, and the adapted cases of the wood and metal material system furniture. There may be difference between the structural sub-stance and formative consideration. Transformative furni-ture which consists of the factors is the concept for the encrease of the multi purpose value by mixing the unit cabinets. One system can be separated horizontally, verti-cally, and to the drawers, and it gives us the disengage-ment from the artificial environment, since all the heights and width can be transformed as per each situa-tion of the space. The factors which can not be found in the other existing furniture are as follows. 1. disengagement from the artificial environment. 2. establishing the new productiosn trend as freed from the customers' fashion trend. 3. presenting the producing condition which leads the exact technology. 4. flexibility of the furniture which enables the reduction and enlargement in each situation.

• Investigative Magnetic Resonance Imaging
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• 제24권3호
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• pp.95-122
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• 2020

In this article, we evaluated the performance of radiofrequency (RF) coils in terms of the signal-to-noise ratio (S/N) and homogeneity of magnetic resonance images when used for ultrahigh-frequency (UHF) 7T magnetic resonance imaging (MRI). High-quality MRI can be obtained when these two basic requirements are met. However, because of the dielectric effect, 7T magnetic resonance imaging still produces essentially a non-uniform magnetic flux (|B₁|) density distribution. In general, heterogeneous and homogeneous RF coils may be designed using electromagnetic (EM) modeling. Heterogeneous coils, which are surface coils, are used in consideration of scalability in the |B₁| region with a high S/N as multichannel loop coils rather than selecting a single loop. Loop coils are considered state of the art for their simplicity yet effective |B₁|-field distribution and intensity. In addition, combining multiple loop coils allows phase arrays (PA). PA coils have gained great interest for use in receiving signals because of parallel imaging (PI) techniques, such as sensitivity encoding (SENSE) and generalized autocalibrating partial parallel acquisition (GRAPPA), which drastically reduce the acquisition time. With the introduction of a parallel transmit coil (pTx) system, a form of transceiver loop arrays has also been proposed. In this article, we discussed the applications and proposed designs of loop coils. RF homogeneous coils for volume imaging include Alderman-Grant resonators, birdcage coils, saddle coils, traveling wave coils, transmission line arrays, composite right-/left-handed arrays, and fusion coils. In this article, we also discussed the basic operation, design, and applications of these coils.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.68-69
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• 2011

The process of charge transfer at the interface between two semiconductors or between a metal and a semiconductor plays an important role in many areas of technology. The optimization of such devices requires a good theoretical description of the interfaces involved. This, in turn, has motivated detailed mechanistic studies of interfacial charge-transfer reactions at metal/organic, organic/organic, and organic/inorganic semiconductor heterojunctions. Charge recombination of photo-induced electron with redox species such as oxidized dyes or triiodide or cationic HTM (hole transporting materials) at the heterogeneous interface of $TiO_2$ is one of main loss factors in liquid junction DSSCs or solid-state DSSCs, respectively. Among the attempts to prevent recombination reactions such as insulating thin layer and lithium ions-doped hole transport materials and introduction of co-adsorbents, although co-adsorbents retard the recombination reactions as hydrophobic energy barriers, little attention has been focused on the anchoring processes. Molecular engineering of heterogeneous interfaces by employing several co-adsorbents with different properties altered the surface properties of $TiO_2$ electrodes, resulting to the improved power conversion efficiency and long-term stability of the DSSCs. In this talk, advantages of the coadsorbent-assisted sensitization of N719 in preparation of DSSCs will be discussed.

• 멤브레인
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• 제25권3호
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• pp.276-286
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• 2015

30 LMH의 정유량 플럭스로 운전하는 MBR에서, 휴지 및 역세정에 따른 한외여과 분리막의 오염을 조사하였다. 또한, 연속적인 공기세정과 비교하여 분리막 여과저항을 최소화하기 위한 간헐적인 공기세정을 평가하였다. 여과 조건은 14.5분 여과와 0.5분의 휴지를 유지하였으며, 역세정 시간은 휴지 시간과 동일하게 운전하였다. 공기세정이 정지하는 동안에 분리막 표면의 겔층 위에 케?이 빠르게 축척되었으며, 역세정으로 겔층과 케?층의 복합층은 쉽게 제거되었다. 역세정 후에 공기세정이 정지하는 동안 분리막 표면에 케?이 형성되어 공경 내부의 오염현상을 억제하였다. Pearson 상관성을 조사한 결과, 간헐적인 공기세정에서 공기 세정이 정지하는 시간과 분리막의 오염은 매우 연관성이 높다는 것을 알았다. 즉, 간헐적인 세정에서 공기세정이 정지하는 시간이 갈수록 오염억제에 효과적이었다.

• Nuclear Engineering and Technology
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• 제42권5호
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• pp.474-499
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• 2010

This paper presents the mostortant developments implemented in the APOLLO2 spectral code since its last general presentation at the 1999 M&C conference in Madrid. APOLLO2 has been provided with new capabilities in the domain of cross section self-shielding, including mixture effects and transfer matrix self-shielding, new or improved flux solvers (CPM for RZ geometry, heterogeneous cells for short MOC and the linear-surface scheme for long MOC), improved acceleration techniques ($DP_1$), that are also applied to thermal and external iterations, and a number of sophisticated modules and tools to help user calculations. The method of characteristics, which took over the collision probability method as the main flux solver of the code, allows for whole core two-dimensional heterogeneous calculations. A flux reconstruction technique leads to fast albeit accurate solutions used for industrial applications. The APOLLO2 code has been integrated (APOLLO2-A) within the $ARCADIA^{(R)}$ reactor code system of AREVA as cross section generator for PWR and BWR fuel assemblies. APOLLO2 is also extensively used by Electricite de France within its reactor calculation chain. A number of numerical examples are presented to illustrate APOLLO2 accuracy by comparison to Monte Carlo reference calculations. Results of the validation program are compared to the measured values on power plants and critical experiments.