• 제목/요약/키워드: Heterogeneous materials

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Determination of representative volume element in concrete under tensile deformation

  • Skarzyski, L.;Tejchman, J.
    • Computers and Concrete
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    • v.9 no.1
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    • pp.35-50
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    • 2012
  • The 2D representative volume element (RVE) for softening quasi-brittle materials like concrete is determined. Two alternative methods are presented to determine a size of RVE in concrete subjected to uniaxial tension by taking into account strain localization. Concrete is described as a heterogeneous three-phase material composed of aggregate, cement matrix and bond. The plane strain FE calculations of strain localization at meso-scale are carried out with an isotropic damage model with non-local softening.

Melting Point of Amorphous Copper Phase on Crystalline Silicon Solar Cells During Cold Spray using Molecular Dynamics Calculations (분자 동역학 계산을 통한 결정질 실리콘 태양전지 기판에 콜드 스프레이 전극 형성 시 발생되는 비정질 구리상에 대한 용융 온도 변화 연구)

  • Kim, Soo Min;Kang, Byungjun;Jeong, Sujeong;Kang, Yoonmook;Lee, Hae-seok;Kim, Donghwan
    • Current Photovoltaic Research
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    • v.3 no.2
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    • pp.61-64
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    • 2015
  • In solar industry, numerous researchers reported about cold spray method among various electrode formation technic, but there are no known a bonding mechanism of metal powder. In this study, a cross-section of copper electrode formed by cold spray method was observed and heterogeneous phase between silicon substrate and copper electrode was analyzed using morphology observation technic. SEM and TEM analysis were performed to analyze a crystallinity and distribution shape of heterogeneous copper phase. Molecular dynamics simulation was performed to calculate glass transition temperature of copper metal. In the result, amorphous copper phase was observed near interface between silicon substrate and metal electrode. The results of the molecular dynamics simulation show that an amorphous copper phase could be formed at a temperature below the melting point of copper because cold spraying resulted in a lower glass transition temperature.

Synthesis of Palladium Nanoparticles Encapsulated in Phosphine Ligand-Grafted Mesoporous Silicas and Their Application to Suzuki Cross-Coupling Reaction (팔라듐 나노입자가 담지된 메조포러스 실리카의 제조와 이를 이용한 Suzuki Cross-Coupling 반응의 적용연구)

  • Kim, Sang-Wook;Joo, Jin
    • Clean Technology
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    • v.17 no.1
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    • pp.13-18
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    • 2011
  • Phosphine ligand-grafted mesoporous silica materials with large pores were prepared for the ligand-modified heterogeneous Pd nanocatalysts. New heterogeneous catalytic system was developed using palladium nanoparticles encapsulated in phosphine ligand-grafted mesoporous silica. The catalyst showed good catalytic activities for Suzuki cross-coupling using bromobenzene derivatives due to excellent phosphine ligand effects. Catalytic results showed nanoparticie catalysts can be recycled twice with decreased yields.

A transport model for high-frequency vibrational power flows in coupled heterogeneous structures

  • Savin, Eric
    • Interaction and multiscale mechanics
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    • v.1 no.1
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    • pp.53-81
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    • 2008
  • The theory of microlocal analysis of hyperbolic partial differential equations shows that the energy density associated to their high-frequency solutions satisfies transport equations, or radiative transfer equations for randomly heterogeneous materials with correlation lengths comparable to the (small) wavelength. The main limitation to the existing developments is the consideration of boundary or interface conditions for the energy and power flow densities. This paper deals with the high-frequency transport regime in coupled heterogeneous structures. An analytical model for the derivation of high-frequency power flow reflection/transmission coefficients at a beam or a plate junction is proposed. These results may be used in subsequent computations to solve numerically the transport equations for coupled systems, including interface conditions. Applications of this research concern the prediction of the transient response of slender structures impacted by acoustic or mechanical shocks.

Strain Hardening Behaviour of PM Alloys with Heterogeneous Microstructure

  • Straffelini, Giovanni
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.928-929
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    • 2006
  • Tensile stress-strain and dynamic acoustic resonance tests were performed on Fe-C-Ni-Cu-Mo high-strength steels, characterized by a heterogeneous matrix microstructure and the prevalence of open porosity. All materials display the first yielding phenomenon and, successively, a continuous yielding behavior. This flow behavior can be described by the Ludwigson equation and developes through three stages: the onset of localized plastic deformation at the pore edges; the evolution of plastic deformation at the pore necks (where the austenitic Ni-rich phase is predominant); the spreading of plastic deformation in the interior of the matrix. The analytical modeling of the strain hardening behavior made it possible to obtain the boundaries between the different deformation stages.

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Ultimate Heterogeneous Integration Technology for Super-Chip (슈퍼 칩 구현을 위한 헤테로집적화 기술)

  • Lee, Kang-Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.4
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    • pp.1-9
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    • 2010
  • Three-dimensional (3-D) integration is an emerging technology, which vertically stacks and interconnects multiple materials, technologies, and functional components such as processor, memory, sensors, logic, analog, and power ICs into one stacked chip to form highly integrated micro-nano systems. Since CMOS device scaling has stalled, 3D integration technology allows extending Moore's law to ever high density, higher functionality, higher performance, and more diversed materials and devices to be integrated with lower cost. The potential benefits of 3D integration can vary depending on approach; increased multifunctionality, increased performance, increased data bandwidth, reduced power, small form factor, reduced packaging volume, increased yield and reliability, flexible heterogeneous integration, and reduced overall costs. It is expected that the semiconductor industry's paradiam will be shift to a new industry-fusing technology era that will offer tremendous global opportunities for expanded use of 3D based technologies in highly integrated systems. Anticipated applications start with memory, handheld devices, and high-performance computers and extend to high-density multifunctional heterogeneous integration of IT-NT-BT systems. This paper attempts to introduce new 3D integration technologies of the chip self-assembling stacking and 3D heterogeneous opto-electronics integration for realizng the super-chip.

The Preparation and its Properties of Heterogeneous Anion Exchange Membrane from Polyethylene Matrix with 4-Vinylpyridine-divinylbenzene (폴리에틸렌을 지지체로한 4-Vinylpyridine-divinylbenzene 불균질계 음이온교환막의 제조 및 그의 특성에 관한 연구)

  • Hwang, Taek-Sung;Choi, Jang-Rak
    • Korean Journal of Materials Research
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    • v.8 no.11
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    • pp.1061-1066
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    • 1998
  • The synthesises of anion exchange resin from 4vinylpyridine-divinyIbenzene(4-VP-DVB) were intented to separate boron ion. The heterogeneous anion exchange membranes were prepared with polyethylene(PE) matrix bythe hot press method. The prepared exchange membranes were characterized by FT-IR, conductormeter and pH meter to confirm structural, mechanical and electrochemical properties. Their capacities were measured by changing floe rate and voltage. The best seperation capacity was appeared in the heterogeneous membrane which contains 50 wt % 4-VP-DVB resin within PE matrix. The heterogeneous membranes treated with acid were better than that treated with water. Results from this experiment were indicated that the optimal flow rate, voltage. and time in the seperation of boron ion were lOml/min, 18volts, and 4 hours respectively.

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Preparation of a Composite of Sulfated Zirconia/Metal Organic Framework and its Application in Esterification Reaction

  • Park, Eun Young;Hasan, Zubair;Ahmed, Imteaz;Jhung, Sung Hwa
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1659-1664
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    • 2014
  • A porous metal-organic framework (MOF), MIL-101, was synthesized in the presence of sulfated zirconia (SZ) to produce acidic SZ/MIL-101 composites for the first time. The composites were characterized with XRD, nitrogen adsorption, FT-IR, scanning electron microscope, chemical analysis and so on. The composites (SZ/MIL-101s) were successfully applied in a liquid-phase esterification for a high yield of ester. This catalytic result of SZ/MIL-101, compared with that of pure SZ or MIL-101 (showing a negligible yield of ester), suggests that the SZ in the composite is highly active in the acid catalysis probably because of the well-dispersed active species of SZ. Moreover, the esterification is catalyzed in heterogeneous mode as confirmed by negligible esterification after filtration of the catalyst. Finally, microwaves can be efficiently applied both in the synthesis of the composites and the esterification reaction to accelerate the two processes of synthesis and esterification by about 5 times.