• Korean Chemical Engineering Research
• /
• 제52권5호
• /
• pp.647-651
• /
• 2014

대량의 유류 취급과 사격, 폭파훈련으로 인한 피탄지에 중금속 물질의 발생, 많은 인원이 사용 후 발생되는 폐기물, 노후화된 시설물(구조물 포함) 등으로 인해 군부대는 환경오염사고를 야기할 수 있는 가능성을 지니고 있다. 경기도 의정부시에 위치한 5개의 반환미군기지를 대상으로 오염도를 분석하였으며, 그 결과 TPH (Total Petroleum Hydrocarbons), BTEX (Benzene, Toluene, Ethylbenzene, Xylene), 중금속에 의한 토양오염과 지하수 오염을 확인할 수 있었다. 군기지 오염토양의 정화를 위하여 토양증기추출법, 슬러핑공법, 토양경작법 및 토양세척법이 적용되었으며, 적용된 5개의 부지 모두 법적 기준에 적합하도록 정화되었다.

• Ocean and Polar Research
• /
• 제25권1호
• /
• pp.21-30
• /
• 2003

Seasonal fluctuations of physico-chemical and biological aspects of the environment were studied in Vladivostok harbour (Golden Horn Bay, the East Sea/Sea of Japan). The benthic community structure was described with a focus on size-spectra (bacteria, meio- and macrofauna) related with the chemical environment and chemical fluxes in sediment and to reveal their possible ecological role in the process of bioremediation of the environment. Samples from two sites with different concentrations of heavy metals (Fe, Zn, Cu, Pb, Mn, Cr, Ni Cd, Co) and petroleum hydrocarbon were assessed by a number of methods. These included plate counts of culturable bacteria, observation through a scanning electron (SEM) and transmission electron microscope (TEM). These approaches were complemented with microscopic assessments of the diversity of the benthic community. The specific communities had a limited number of species, tolerant to abnormally high levels of toxic compounds. The dominant species were presented by several sho.1-lived small polychaetes (Capitella capitata) and nematodes (Oncholaimium ramosum). The highest population density was recorded in microbenthos, in various diatoms, various physiological groups of bacteria which participate in biomineralization: marine heterotrophic bacteria, which oxidized oil, black oil in addition to groups resistant to heavy metals. They have the entire set of mechanisms for neutralizing the negative effect of those compounds, forming the detrital food web and biogeochemical circulation of material in sediments, which results in the biological self-recycling of sea basins. Macro- and meiobenthic organisms were more sensitive to a greater extent of $H_2S$ and petroleum hydrocarbons than to metal content, but the within-site rankings were the same as those achieved for microbiological analyses.

• 대한조선학회논문집
• /
• 제42권3호
• /
• pp.259-267
• /
• 2005

The effects of hull flexibility on shaft alignment are growing as ship sizes are increased mainly for container carrier and LNG carrier. In order to consider hull flexibility on a propulsion shafting system, standardization of ship service conditions is necessary because hull deformation is continuously variable according to ship service conditions. How to summarize ship service conditions is suggested based on practically applicable four viewpoints : hull, engine, loading and sea status. Effects of the external forces acting on a ship propulsion shafting system are generally commented. Several design criteria regulated by classification societies are pointed at issue which seems to have Insufficient technical background. A qualitative verification is carried out to point out the invalidity of the assumption of effective supporting position. In this work, an elastic nonlinear multi-supporting bearing system is introduced as a key concept of the elastic shaft alignment. Hertz contact theory is proved to be more proper one than projected area method in calculation of the nonlinear elastic stiffness of the bearing, The squeezing and oil film pressure calculations in the long journal bearing like an after stern tube bearing are recognized as a necessary process for elastic shaft alignment design.

• Advances in concrete construction
• /
• 제4권2호
• /
• pp.123-143
• /
• 2016

Use of heavy fuel fly ash (HFFA) (diesel and cracked fuel) for power generation in Saudi Arabia has generated and accumulated large quantities of HFFA as a byproduct. In this research, HFFA is studied with the emphasis on the utilization of this waste material in concrete blocks and asphalt concrete mixes. Two types of mixes, one with low and other with high cement content, were studied for concrete blocks. Different mixes having varying percentages of HFFA (0% to 25%), as cement/sand replacement or as an additive, were studied. The performance of concrete blocks is evaluated in terms of compressive strength, water absorption, durability and environmental concerns. The results showed that blocks cannot be cast if more than 15% HFFA is used; also there is a marginal reduction in the strength of all the mixes before and after being exposed to the sulfate solution for a period of ten months. HFFA is studied in asphalt concrete mixes in two ways, as an asphalt modifier (3&5%) and as a filler (50%) replacement, the results showed an improvement in stiffness and fatigue life of mixes. However, the stability and indirect tensile strength loss were found to be high as compared to the control mix due to moisture damage, indicating a need of using antistripping agents. On environmental concerns, it was found that most of the concerned elements are within acceptable limits also it is observed that lower concentration of barium is leached out with the higher HFFA concentrations, which indicates that HFFA may work as an adsorbent for this leaching element.

• 한국안전학회지
• /
• 제30권4호
• /
• pp.79-85
• /
• 2015

Onboard fire extinguishing system is important to protect cargo and human lives and every oil tanker has foam type fire extinguishing system. Because of environmental problem, agent which contains materials such as Perfluorinated compounds are regulated and the development of the environmental friendly agent is required. The protein foam has less environmental pollution problem and has an excellent fire extinguish performance to oil fire. In the research, bivalency metal salts were added as stabilizer to increase fire resistance and stability of the foam. Ferrous sulfate, Iron chloride and Nickel chloride were used and to adjust to vessel, sea water was applied. As a stabilizer increased, the expansion ratio was raised. However 25% drainage time was decreased over 2.0 wt.% which is knowable that the foam brokes easily. The amount of generated foam was measured to check fluidity of foam and it appeared that when $FeSO_4$ 1.2 wt.% was added, the amount of generated foam reached large and also the 25% drainage time was high. To evaluate the fire extinguishing performance for oil fire, the small scale oil fire test was executed. When $FeSO_4$ 1.2 wt.% was added, fire extinguishing time was in its shortest which informs fluidity of foam and stability are important factors on fire extinguishing efficiency.

• Molecular & Cellular Toxicology
• /
• 제1권3호
• /
• pp.189-195
• /
• 2005

Industrial development has increase consumption of crude oil and environmental pollution. A large number of microbial lipolytic enzymes have been identified and characterized to date. To development for a new lipase with catalytic activity in degradation of crude oil as a microbial enzyme, Acinetobactor sp. B2 was isolated from soil samples that were contaminated with oil in Daejon area. Acinetobactor sp. B2 showed high resistance up to 10 mg/mL unit to heavy metals such as Ba, Li, Al, Cr, Pb and Mn. Optimal growth condition of Acinetobactor sp. B2 was confirmed $30^{\circ}C$. Lipase was purified from the supernatant by Acinetobactor sp. B2. Its molecular mass was determined to the 60 kDa and the optimal activity was shown at $40^{\circ}C$ and pH 10. The activation energies for the hydrolysis of p-nitrophenyl palmitate were determined to be 2.7 kcal/mol in the temperature range 4 to $37^{\circ}C$. The enzyme was unstable at temperatures higher than $60^{\circ}C$. The Michaelis constant $(K_{m})\;and\;V_{max}$ for p-nitrophenyl palmitate were $21.8{\mu}M\;and\;270.3{\mu}M\;min^{-1}mg\;of\;protein^{-1}$, respectively. The enzyme was strongly inhibited by $Cd{2+},\;Co^{2+},\;Fe^{2+},\;Hg^{2+},\;EDTA$, 2-Mercaptoethalol. From these results, we suggested that lipase purified from Acinetobactor sp. B2 should be able to be used as a new enzyme for degradation of crude oil, one of the environmental contaminants.

• 신재생에너지
• /
• 제2권2호
• /
• pp.118-125
• /
• 2006

The target of this work was the process development of demonstration plant to produce the high quality alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70 t/y and the pilot plant of 360 t/y had been developed. Main research contents in this step were the process performance test of pilot plant of 360 ton/year and the development of demonstration plant of 3,000 t/y, which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/y showed about 80% yield of liquid product, which was obtained by both light gas oil(LGO) and heavy gas oil(HGO), The boiling point range distribution of LO product that was mainly consisting of olefin components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

• 한국마린엔지니어링학회:학술대회논문집
• /
• 한국마린엔지니어링학회 2005년도 전기학술대회논문집
• /
• pp.160-165
• /
• 2005

The proceeding bearings of marine diesel engine are affected by dynamic loads from the cylinder gas pressure and the inertia force from the crank mechanism. Oil film must support the load of the shaft and it also must protect the proceeding and the bearings from damage. This study uses Goenka's new curve fit to carry out the theoretical analysis of oil film in proceeding bearings for MAN B&W 12K90MC-C and Hyundai Heavy Industry Co., Ltd HiMSEN H21/32 Engine. The applied engine's analysis results show the behavior of the proceedings in main and crank pin bearings. The results of this study will be the proper criteria for the proceeding bearings design and be available for development of the new technology in the proceeding bearing and for the high strength lining coating.

• KSTLE International Journal
• /
• 제8권2호
• /
• pp.29-34
• /
• 2007

Recently, requirements relating to performance, environment and noise in the oil hydraulic system of the heavy construction equipment have been reinforced continuously. In order to solve these technical trends, studies on the system compactness, operation under high pressure and great rotating speed, electronic control, substitute oil, and noise reduction have been progressed briskly. Among these recent studies, the system operation under high pressure is quite difficult to carry into effect due to mechanical limitations; that is, for realizing the system operation in the hydraulic pump under high pressure, the improvements or innovations on the design techniques, the manufacturing techniques, and the lubrication performance of the working oil are required. Accordingly, in this study, the stress distribution and optimum design factors under the maximum pressure were discussed by using stress analysis on the cylinder block of the hydraulic axial piston pump, which is one of the most important relative sliding regions.

• 한국식품영양학회지
• /
• 제7권4호
• /
• pp.297-306
• /
• 1994

This experiment was carried out to investigate the healing loss and the heavy metal residues such as copper, zinc, manganese, cadmium and lead In porcine visceras by inductively coupled argon plasma spectrometer(ICP), and to probe changes when porcine visceras were boiling In water treatment(BWT), heating in autoclave treatment (HAT) and heating In oil treatment (HOT) . The range of heating loss on porcine viscera were BWT(23.11∼34.53%) , HAT(18.48∼28.00%) and HOT(14.20∼25.22%)and the heart tissue were higher and liver were lower than those of the other tissues. The total value of heavy metal residues in large intestine, small intestine, heart, kidney, liver and stomach tissue were 11.298${\pm}$5.302 ppm, 27.825${\pm}$8. 177 ppm, 16.756${\pm}$6.334 ppm 21.107${\pm}$6.057 ppm, 25.369 ${\pm}$ 10.164 ppm and 12.611 ${\pm}$5.513 ppm, respectively. Heavy metal residues in porcine visceras tended to decrease according to heating methods and the variety viscera, and the change of total heavy metal residues on BWT, HAT and HOT were 4.16∼32.57%, 12.01∼28.09% and 9.60∼25.76%, respectively. The decrease of lead element of mean value were 21.76% and copper, zinc, manganese and cadmium element were 18.00∼ 18.16%. The change of heavy metal residues were not significant in the porcine visceras(P>0.05), and the these were significantly correlated among the three heating method(P < 0.05).