• Economic and Environmental Geology
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• v.28 no.2
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• pp.147-154
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• 1995

Coal fly ashes collected from the Samcheonpo and the Seocheon Power Plants were analyzed for major and minor components and heavy metals such as As, Cd, Co, Cr, Cu, Ga, Hg, Mo, Ni, Pb, Sb, V and Zn in order to suggest basic data to apply coal fly ash as fertilizer or soil ameliorator. The specific gravity of the samples was less than 2.0, and amounts of organic matter range from 5.0% to 12.3%. The identified minerals by XRD were mainly quartz, mullite and pyrite in anthracite coal, and mainly quartz and mullite in bituminous coal. Generally, the contents of heavy metal elements analyzed were lower less than those of soil, though higher in some samples. Element couples of some elements( e.g., As-Mo, Zn ; Mo-As, Sb, V, Zn ; Sb-Zn ) show positive correlations with each other, but the high correlations of toxic elements such as As, Pb, Cd and Hg indicate to give attention to apply coal fly ash as fertilizer or soil ameliorator.

• Asian Journal of Atmospheric Environment
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• v.4 no.1
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• pp.9-19
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• 2010

The size distribution of airborne particulate matter (PM) and the concentrations of associated metallic elements were investigated in a busy urban region of a typical Korean industrial city. The PM concentrations measured during the spring, except for those in the size range of 1.1 to 2.1 ${\mu}m$, were slightly higher than the PM concentrations in the summer. Coarse particles contributed greatly to the variation in PM concentrations in the spring, while fine and submicron particles contributed largely to the variation in PM concentrations in the summer. The difference in size modes of the PM concentrations between spring and summer may be explained by the Asian dust effect and its accompanying wind direction and speed. Extremely high enrichment factors (EFs) values (6,971 to 60,966) for all of the size distributions in PM were identified for cadmium (Cd). High EFs values (12 to 907) were also identified for other heavy metals including Cr, Cu, Ni, Pb, Zn and Mn. Low EF values (0.29 to 8.61) were identified for Ca, K, Mg and Na. These results support the common hypothesis that most heavy metals in ambient PM have anthropogenic sources and most light metals have crustal sources. The results of principal components analyses and cluster analyses for heavy metals indicate that the principal sources of PM and metals were emissions from non-ferrous metal smelters, oil combustion, incinerators, vehicular traffic and road dust.

• Journal of Korea Foundry Society
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• v.18 no.3
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• pp.246-253
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• 1998

Precision metal mold casting process is a casting method manufacturing mechanical elements with high precision, having heavy/light alloys as casting materials and using permanent mold. To improve dimensional accuracy and the final mechanical properties of the castings, the solidification speed and the cooling rate of the casting should be controlled with the optimum mold cooling system, and moreover, to obtain more accurate control of the whole process interfacial heat transfer characteristic at the mold/casting interface must be studied in advance. In the present study, aluminum alloy casting system with metal mold equipped with electrical heating elements and water cooling system was designed and the temperature histories at points inside the metal mold were measured during the casting process. The heat transfer phenomena at the mold/casting interface was characterized by the heat flux between solidifying casting metal and metal mold, and the heat flux history was obtained using inverse heat conduction method. The effect of mold cooling condition upon the heat flux profile was examined, and the analysis shows that the heat flux value has its maximum at the beginning of the process.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2010.04a
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• pp.649-650
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• 2010

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.3
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• pp.198-207
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• 1999

Five core sediments acquired from the Lake Shihwa are analyzed for variations of sedimentary environment and heavy metal pollution after the Shihwa seawall construction. The depositional environment of the study area is divided into anoxic, oxic and mixed suboxic conditions based on the C/N ratio and C/S ratios of organic matters. Controlling factors for redox condition are the water depth and the difference in industrial effluents supply. Correlations among geochemical elements (Mn, U, Mo) show a distinctive difference and thus can be used as an indicator of redox condition. The content of Al, Ti are dependent on the sediment characteristics, and the contents of heavy metals (Cr, Ni, Cu, Zn, and Pb) indicate heavy metal pollution. The concentrations of heavy metals are higher near Shiswa-Banwol industrial complexies than the central part of Lake Shihwa. Especially, the accumulation of the heavy metal at the surface sediments near Shihwa-Banwol industrial complex are two to eight times higher than in the center of Lake Shihwa.

• Journal of the Korean GEO-environmental Society
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• v.9 no.4
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• pp.47-52
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• 2008

In this study, it was analyzed the soil components and elution characteristics of heavy metal ions in sediment samples to examine the effect of sediments embedded in Andong and Imha reservoirs on water quality. Major elements of sediments were shown to be Al, Si, K, and Fe by EDS analysis and major soil components of the collected 6 different sediments were illite (I), kaolinite (Ka), quartz (Q) and feldspar (F). And especially quartz took up a considerable part of sediments by XRD analysis. The total concentrations of Zn, As, Cr, Cu and Pb in sediments of Andong reservoir were relatively higher than those of Imha reservoir. The elution property of heavy metal from sediments had various aspects according to pH. Among the heavy metals in Andong reservoir sediments, As and Zn were significantly eluted at pH 6 compared with the other heavy metals. In the case of the adsorption tests using the sediments, the adsorptive capacities of Zn, Cd and Cu were very weak, on the while those of Pb and Cr were high.

• Journal of Soil and Groundwater Environment
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• v.27 no.6
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• pp.1-10
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• 2022

This study assessed the feasibility of iron oxide nanoparticles impregnated with biochar (INPBC), derived from woody biomass, as a stabilizing agent for the stabilization of farmland soil in the vicinity of an abandoned mine through pot experiments with 28 days of lettuce growth. The lettuce grown in the INPBC amended soils increased by more than 100% and the concentrations of inorganic elements (Cu, Ni, Zn) decreased by more than 40%. As, Cd and Pb were not transferred properly from the soils to the lettuce biomass. The bioavailability of arsenic and heavy metals in the INPBC amended soils were decreased by 26%~50%. It seems that the major mechanisms of stabilization were arsenic adsorption on iron oxides, heavy metal precipitation by soil pH increasing and heavy metal adsorption on organic matter. These results revealed that the lower bioavailability of the inorganic pollutants in the soils stabilized using INPBC induced lower transfer to the lettuce. Thus, INPBC could be used as an amendment material for the stabilization of farmland soils contaminated by arsenic and heavy metals. However, a pre-review of the chemical properties of the amended soil must be performed prior to applying INPBC in farmland soil because the concentration of the nutrients in the soil such as available phosphates and exchangeable cations (Ca, Mg, K) could be decreased due to adsorption on the surface of the iron oxides and organic matter.

• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.536-539
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• 2003

The Dongjung Au-Ag-Cu mine area was seriously contaminated with As and heavy metals-Cd, Cu, Hg, Mn, Pb and Zn etc. Those elements were highly accumulated in plants grown at farmland as well as farmland soil. Stream waters and groundwater which has been used as drinking water around the mine site contain high levels of heavy metals, especially As. As a result of human health risk assessment using EHS(Extraction of Heavy metals in Stomach and Small intestine) test for bioaccessible contents of heavy metals, there is a potential of cancer and adverse effects on human health for the residents of the mine area.

• Economic and Environmental Geology
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• v.29 no.1
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• pp.45-55
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• 1996

Although the Dongjin Au-Ag-Cu mine had been abandoned since about forty years ago, the results of this study on the dispersion patterns and contamination level of heavy metals in the hydrologic system flowing via the waste rump show that the environmental impacts from the mine wastes are still significant. The stream water in the vicinity of the waste rump is severely acidified (pH 3.8 to 4.4) and highly enriched in various dissolved heavy metals. The heavy metal contents of the stream water and stream sediments are systematically attenuated with increasing distance from the mine area. However, it is worth to note that continuous attenuation of heavy metal contents in both media were reenriched in downstream area more than 800 m apart from the mine because it can be acted as a secondary source of heavy metal pollution. The heavy metals, especially Cd, Cu and Zn of polluted downstream sediments mainly occur in Fe-Mn oxides and organic materials, which indicates that these elements are the main pollutants from the waste rump of the Dongjin mine. The heavy metal contents of crops, such as sesame, perilla, red Pepper and brown rice, collected from the polluted farm land in the downstream area are lower than those of land plants from stream sides, but significantly higher in Cd, Cr, Cu and Zn than those from the unpolluted farm land. Especially, almost all of the crops in polluted farm land have been severly contaminated by Cd (>0.4 ppm). On the other hand, the heavy metal contents of the crops collected from refreshed farm land by means of a soil addition method shows significantly lowered level comparing with those of polluted area, which indicates that a soil addition method was effective for the refreshment of polluted farm land by toxic metallic pollutants. Wormwoods from this area showed very high contents in a11 the heavy metals even in unpolluted area (Cd > 1 ppm, Cr > 1 ppm, Cu > 11 ppm, Pb> 4 ppm, Zn > 55 ppm), indicating that a special caution must be payed when one takes ingest them.

• Korean Journal of Environmental Agriculture
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• v.21 no.3
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• pp.223-228
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• 2002

In addition to supplying the essential elements, Ca and S, phosphogypsum can have profound effect on both the physical and chemical properties of certain soils. However, no widespread use of by-product phosphogypsum will be made unless such uses pose no threat to the public health and soil contamination. In this study, the extractability of As, Cd, Cu, and Pb with water and DTPA solution from phosphogypsum samples of pH 3, 5, and 7 were investigated to estimate the availability of those metals. Contents of water extractable metals in ohosphogypsum were less than 5 mg/kg for all the heavy metals investigated. The extractability of metals in DTPA solution was not quite different but a little higher in comparison to the water extraction. And the extractability was decreased as the pH of phosphogypsum increased. In the phosphogypsum of pH 7, amounts of water extractable metals were nearly zero. There was no significant difference in the amount of extractable metals during the extraction period of 5 weeks. The length of extraction time did not affect heavy metal extractability. Therefore there may be small fractions of easily soluble or extractable forms of metals in the phosphogypsum and most of the metals would be present in very insoluble forms. These results suggest that the application of phosphogypsum at appropriate rates on agricultural lands appears of no concern in terms of hazardous element contamination in soil.