• Title/Summary/Keyword: Heavy metal analysis

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A Study on SPI(soil pollution index) in City Land

  • Kim, Young-Sik;Kim, Gi-Sun;Song, Mi-Ra
    • Journal of Environmental Health Sciences
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    • v.33 no.6
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    • pp.502-505
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    • 2007
  • To estimate the soil quality of Miryang area, soil analysis were conducted according to the city and out of city of soil expenses at according to analysis components and heavy metal pollution of irradiation sampling sites. The through soil components the principal element about the 71% $SiO_2\;and\;Al_2O_3$, the pH of field area near the city center was lower than that of the other field area, which indicated that this acidification was probably attributed to the acid rain caused by the traffic exhaust gas such as $SO_x\;and\;NO_x$. Acidification was more severe in the field area than in the farming land. The concentration of five heavy metals such as Cu, Cd, Pb, As and Cr were found to be lower than the standard of soil pollution. An assessment using the SPI(Soil Pollution Index), which was developed to estimate an overall soil quality, was performed. Each SPS(Soil Pollution Score) were evaluated with the results of the data from this study. The soil quality of most area of Miryang land was determined to Class 1, which indicated that the soil was healthy.

Effect of Pre-treatments on the Content of Heavy Metals in Packaging Paper

  • Jo, Byoung-Muk;Jeong, Myung-Joon
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.465-469
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    • 2006
  • Pre-treatment methods to determine various heavy metal contents in packaging papers were investigated by ICP-ES (Inductively Coupled Plasma Emission Spectrometry) analysis. Pre-treatment methods utilized in this study include dry ashing and decomposition methods ($HNO_{3-}HClO_{4-}HF,\;HNO_{3},\;and\;H_{2}SO_{4-}HNO_{3}$). They were compared with the conventional extraction (water) and migration (3% acetic acid) methods. The five representative heavy metals (Cd, As, Pb, Cr and Hg) were analyzed. For Cd, Hg, and As, the results were below detection limit of the instrument. In case of Cr and Pb, the migration test is considered to be a better method compared to the extraction test, but all pretreated methods showed much higher detection efficiency than the extraction or migration test. However, the detection ratio between the migration test and decomposition methods was different. Among all decomposition methods, the nitric acid - perchloric acid - hydrofluoric acid treatment brought a slightly higher detection value than others, but there was no significant difference among them except sulfuric acid - nitric acid method. Concerning Pb, the sulfuric acid - nitric acid method showed a low detection efficiency compared to other decomposition methods. The sulfuric acid - nitric acid method is, thus, not considered to be a suitable analysis method for Pb in packaging papers.

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The Biological Treatment of Soil Washing Water Contaminated with Heavy Metal (중금속오염 토양 세척수의 생물학적 처리)

  • Jeong, Jeong-Hwa;Seo, Pil-Soo;Kong, Sung-Ho;Seo, Seung-Won;Kim, Min-Kyoung;Lee, Jong-Yeol;Lee, Sang-Seob
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1222-1227
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    • 2006
  • In this study, nine strains were isolated from heavy metal-contaminated soil in a mine. The high efficiency bacteria, JH1, to be able removal cadmium and copper, was selected by the screen test. JH1 was identified as Ralstonia eutropha by 16S rDNA analysis, fatty acid analysis, and its morphological and biochemical characteristics. After the cadmium-contaminated soil was washed with citric acid solution(pH 6, 10 mM), Ralstonia eutropha JH1 was inoculated in the soil washing water. In order to determine the optimal cell concentration for inoculation, cell concentrations were considered in 0.5, 1.0, 2.0, 4.0 g/L, respectively. The removal efficiencies for cadmium in each cell concentration of Ralstonia eutropha JH1 were 49.9, 84.4, 89.7% and 89.9% of 110 mg/L(Cd), after 5 days culture in soil washing water. When Ralstonia eutropha JH1 was inoculated in soil washing water containing each cadmium(110 mg/L) and copper(100 mg/L), each of them was removed completely during 6 days culture. The completely removing time for cadmium and copper in each low concentration, 10, 30 and 60 mg/L were 12, 18 and 48 hrs, respectively.

Analysis of Thermal Cycles and Microstructure of Heat Affected Zone for a Low Alloy Carbon Steel Pipe under Multipass Weld (저합금 탄소강 배관재의 다층용접 열영향부의 미세조직 및 열이력 해석)

  • Kim, Tae-Wan;Ha, Jun-Uk;Kim, Dong-Jin;Kim, Jeong-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.3
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    • pp.497-504
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    • 2002
  • The purpose of this study is to analyze thermal cycles and to investigate microstructures of heat affected zones for a low alloy carbon steel pipe under a multipass weld. The commercial finite element code SYSWELD is used to compute thermal cycles during multipass weld. The numerical results such as thermal cycles and size of heat affected zone are compared with those of the experiment and the two results show a good agreement. In addition, the microstructure and hardness are investigated from the weldment in detail. The weakest location is founded at intercritical region near the base metal.

Evaluation of Shelf-life of Bojungikgi-tang by Long-term Storage Test (장기보존시험에 따른 보중익기탕 전탕팩의 유통기한 평가)

  • Seo, Chang-Seob;Kim, Jung-Hoon;Kim, Seong-Sil;Lim, Soon-Hee;Shin, Hyeun-Kyoo
    • Korean Journal of Pharmacognosy
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    • v.44 no.2
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    • pp.200-208
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    • 2013
  • The aim of this study was to evaluate the shelf-life of Bojungikgi-tang (Buzhongyiqi-tang in Chinese) by long-term storage test. Experiments were performed to evaluate the stability such as the selected physicochemical, pH, identification, heavy metal, microbiological experiment, and amount of marker compounds under a long-term storage test of Bojungikgi-tang decoction. The significant change was not showed in pH, heavy metal, microbiological, and identification test based on long-term storage test. Furthermore, the HPLC analysis was performed for the determinations of liquiritin, glycyrrhizin, nodakenin, and hesperidin in Bojungikgi-tang by long-term storage test. We were calculated shelf-life of Bojungikgi-tang decoction based on the amount change of four constituents. Consequently, Shelf-life by four compounds at room temperature was predicted 23 month. The suggested shelf-life would be helpful on the storage and distribution of herbal medicine.

Analysis of Microbial Community Structure in Mine Tailings of Abandoned Mines Over the Depth Using Quinone Profiles (Quinone Profile법을 이용한 폐광산 광미내에 존재하는 깊이별 미생물 군집구조해석)

  • Lim, Byung-Ran;Kim, Myoung-Jin;Ahn, Kyu-Hong;Hwang, Hyun-Jung;Lee, Ki-Say
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.670-674
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    • 2005
  • The respiratory quinone profile was used as a tool for the study on microbial community structure in the mine tailings of abandoned mines over the depth. For the study, the area of Jingok mine located in Bongwha, Korea has been selected. The distributions of Cd, Cu, Pb, Al, Fe and Mn showed the following common patterns; the highest values in the upper part of mine failings (0-20 cm), rapid decrease with increasing depth. The dominant quinone species of the mine tailings were UQ-9 followed by UQ-10, suggesting that microbes had contributed to heavy metal degradation. The quinone contents in mine tailings ranged from 5.0 to 24.9 nmol/kg. The microbial diversity in the upper part of mine tailings (0-40 cm) was higher than that of lower part of mine tailings (100-120 cm).

Depositional Environment and Distribution of Heavy Metal off the Shihwa Dam

  • Oh, Jae-Kyung
    • Journal of the korean society of oceanography
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    • v.32 no.3
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    • pp.120-127
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    • 1997
  • Depositional environment off the Shihwa Dam has been studied to investigate the change of sedimentation process and the pollution. In order to understand how the sediments are distributed, polluted and modified, depositional factors have been analyzed and compared with the previous data. Study area, located off the Shihwa Dam, was surveyed to collect 25 bottom samples and 2 cores in 1996 and echo-sounding in 1997. These sediments were analyzed for the study of the global characteristics of sediment such as grain size and organic matter. Among these samples, the selected twenty surface sediments were analyzed for the comparison with their contents of metallic elements (Al, Mn, Fe, V, Cr, Co, Ni, Cu, Zn, Cd, Pb, As). According to field and lab analysis of sediments, three sedimentological zones have been generally identified around study area; near the dam (sandy Silt), near the dike (Sand) and offshore (silty Sand) zones. Textural parameters show that the content of silt and clay is dominant near the dam excepting the dike zone of LNG Storage Base and offshore (Palmido). The total concentration of Mn, Ni, Fe, Zn and Cd in bulk sediments was increased after the construction of the dam, while the content of Mn and Cr were higher near tidal channel than in the offshore area. Meanwhile, the annual increasing pattern of some heavy metal has appeared in this area. Based on this primary study, modification of the depositional environment may be caused by the construction of the dam and LNG Storage Base. Additionally, environmental evaluation on organic/inorganic factors has been suggested for interpreting environmental changes caused by coastal development in the nearshore such as the Shihwa coastal area.

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Heavy Metal as Risk Factor of Cardiovascular Disease - An Analysis of Blood Lead and Urinary Mercury (심혈관계 질환 위험요인으로서의 중금속 - 납과 수은에 대한 분석 -)

  • Kim, Dae-Seon;Yu, Seung-Do;Cha, Jung-Hoon;Ahn, Seung-Chul;Lee, Eun-Hee
    • Journal of Preventive Medicine and Public Health
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    • v.38 no.4
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    • pp.401-407
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    • 2005
  • Objectives : We wanted to investigate the relationship between heavy metal, especially lead and mercury, to the blood pressure and cholesterol level in children. Methods : This study was undertaken in three primary schools and the study subjects were a total of 274 children. The lead in the blood and the urine mercury were analyzed by performing atomic absorption spectroscopy. Results : All of participants' blood lead levels and urine mercury concentrations were below the suggested level of concern according to the criteria of the CDC and ATSDR. We found no significant correlation between lead, mercury and the blood pressure. The blood lead level did not show any relationship with the blood pressure and cholesterol. However, the urine mercury levels were associated with the serum cholesterol. Conclusion : Our study suggests that mercury can induce an increase of cholesterol as a risk factor of myocardial infraction and coronary/cardiovascular disease.

Establishment of Shelf-life of Ssanghwa-tang by Long-term Storage Test (장기보존시험에 따른 쌍화탕의 유통기한 설정)

  • Seo, Chang-Seob;Kim, Jung-Hoon;Lim, Soon-Hee;Shin, Hyeun-Kyoo
    • Korean Journal of Pharmacognosy
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    • v.43 no.3
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    • pp.257-264
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    • 2012
  • The purpose of this study was to estimate the shelf-life of Ssanghwa-tang by long-term storage test. Experiments were conducted to evaluate the stability such as the selected physicochemical, pH, identification, heavy metal, microbiological experiment under a long-term storage test of Ssanghwa-tang. The significant change was not showed in pH, heavy metal, microbiological, identification test and quantitative analysis based on long-term storage test. The contents of albiflorin, paeoniflorin, cinnamic acid, liquiritin, and glycyrrhizin in long-term storage test were 66.8-93.1 ${\mu}g/mL$, 429.0-495.0 ${\mu}g/mL$, 3.8-4.4 ${\mu}g/mL$, 32.0-38.1 ${\mu}g/mL$, and 66.8-71.7 ${\mu}g/mL$, respectively. Shelf-lifes by 5 compounds about 3 lots at room temperature were predicted 21-37, 14-21, and 16-72 months, respectively. The suggested shelf-life would be helpful on the storage and distribution of herbal medicine.

The SWSV signal analysis for decision of heavy metal ion concentration using digital signal processing method (디지털신호처리기법을 이용한 중금속이온농도 결정의 SWSV 신호분석)

  • Lee, Jae choon
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.5 no.4
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    • pp.11-17
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    • 2009
  • Polarography is a subclass of voltammetry where the working electrode is a dropping mercury electrode. More, I developed the experiment for raising up mercury electrode. In Voltammetry, information about an analyte is obtained by measuring the current as the potential is varied at oxidation-reduction reaction. A plot of current vs. potential in a polarography experiment shows the current oscillations correspoding to the drops of Hg falling from the capillary. The drops growth causes capacitive and faradic current. These changing current effects combined with experiments where the potential is continuously changed can result in noisy traces. The raising up type improved upon the method of dropping in hardware. In reduction of the noise, moving average smoothing method have been used. But the other procedure is introduced based on Fourier transformation. So FFT and IFFT engine was implemented and installed in my experiment. However, after experimentation, peak height as the measuring parameter gave a good linear relationship to concentration. The resolution of potential peaks of various kinds, using Zn and Cu as the example, was improved using the smoothing method.