• Title/Summary/Keyword: Heavy metal analysis

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Comparison of the Characteristics of Reservoir and Stream Sediments in Kum River basin (금강권역의 호소 및 하천 퇴적물 특성 비교)

  • Hwang, Jong-Yeon;Han, Eui-Jung;Kim, Tae-Keun;Yu, Soon-Ju;Yoon, Young-Sam;Chung, Yong-Soon
    • Journal of Environmental Impact Assessment
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    • v.7 no.2
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    • pp.135-143
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    • 1998
  • In order to study the general characteristics of reservoir and stream sediments, various analysis tests were conducted. Water contents and ignition loss were measured to know the primary sediment characteristics. The COD, total phosphorus and nitrogen were contained for the determination of organic substance content. For the purpose of establishing the contamination degree of heavy metals, some heavy metal contents were investigated. In heavy metal contents, reservoir sediments showed somewhat higer value than stream sediments. As a result, the reservoir sediment content of all analysis items were higher than stream sediment.

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Heavy and Trace Metal Analysis of River Otter (Lutra lutra) Spraints from the Geoje Island (우리나라 거제지역에 서식하는 수달의 식이물 중금속 및 미량원소 분석에 대한 연구)

  • Cho Heesun;Lee Sang-Don
    • Korean Journal of Environmental Biology
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    • v.23 no.3 s.59
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    • pp.315-321
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    • 2005
  • The population of river otter (Lutra lutra) has been declined most of the world due to hunting, habitat destruction and indirect or direct influences of eutrophication, acidification and toxic chemicals. This study is conducted to identify the population decline of river otter in Korea with relation to environmental pollution caused by accumulation of heavy and flared metals. The field survey was conducted during Jan~Dec, 2004 at a monthly basis by collecting spraints. A total of 228 spraints were collected and analysis was done by ICP-AES. The concentrations of fourteen metals (Cr, Zn, Cd, Pb, Ni, Fe, Co, Mn, Mg, Cu, Al, Ba Hg, As) have been determined. Annual concentrations of Cd $(1.38{\mu}g\;g^{-1}),\;Zn\;(599.06\;{\mu}g\;g^{-1}),\;Pb\;(5.54\;{\mu}g\;g^{-1})$ at Gucheon were higher than those of Yeonchocheon. Concentrations of $Cr\;(5.01{\mu}g\;g^{-1}),\;Ni\;(1.91{\mu}g\;g^{-1}),\;Co\;(0.25{\mu}g\;g^{-1})$ were higher at Yeonchocheon. Most metals in winter were significantly increased (P<0.05) as season progressed from spring to winter. $Pb\;(15.58{\mu}g\;g^{-1}),\;Cu\;(15.15{\mu}g\;g^{-1}),\;a;Guchoen\;and\;Cr\;(5.77{\mu}g\;g^{-1})$ at Yeonchocheon were high in the downstream of winter.

Application of Hot Spot Analysis for Interpreting Soil Heavy-Metal Concentration Data in Abandoned Mines (폐금속 광산의 토양 중금속 오염 조사 자료 해석을 위한 핫스팟 분석의 적용)

  • LEE, Chae-Young;KIM, Sung-Min;CHOI, Yo-Soon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.22 no.2
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    • pp.24-35
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    • 2019
  • In this study, a hotspot analysis was conducted to suggest a new method for interpreting soil heavy-metal contamination data of abandoned metal mines according to statistical significance level. The spatial autocorrelation of the data was analyzed using the Getis-Ord $Gi{\ast}$ statistic in order to check whether soil heavy metal contamination data showing abnormal values appeared concentrated or dispersed in a specific space. As a result, the statistically significant data showing abnormal values in the mine area could be classified as follows: (1) the contamination degree and the hotspot value (z-score) were both high, (2) the contamination degree was high but the z-score was low, (3) the contamination degree was low but the z-score was high and (4) the contamination degree and the z-score were both low. The proposed method can be used to interpret the soil heavy metal contamination data according to the statistical significance level and to support a rational decision for soil contamination management in abandoned mines.

Heavy Metal Accumulation of Small Mammals in Gumbo River Basin (금호강에 서식하는 소형포유류의 중금속축적에 관한 연구)

  • 이상돈
    • Korean Journal of Environmental Biology
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    • v.21 no.3
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    • pp.257-261
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    • 2003
  • Population of small mammals (Apodemus agrarius and Crocidura lasiura) was monitored to identify the bioaccumulation of heavy metals in Gumho river basin around Daegu city. The small mammals were captured during 28 of May~12 of June, 2002. The techniques of live-trapping and snap-trapping were applied to capture the animals. A total of 39 animals were captured among which 53.3% (16130) of population were reached to breeding. Heavy metals (Cu, Pb, Zn, Cd) were analyzed. According to the analysis of heavy metal elements, Zn was more accumulated in kidney (6.83 mg $kg^{-1}$) than in liver (3.66). However, the accumulation of Cu was higher in liver than in kidney. Even though this site was relatively away from major industrial zones, heavy metals were wide spread along the stream of Gumbo River. This is the first quantitative study of small mammal bioaccumulation of heavy metals in Korea so that further research should be followed in other industrial areas that heavy metals were widely dispersed.

Stabilization of Agricultural Soil Contaminated by Arsenic and Heavy Metals using Biochar derived from Buffalo Weed (단풍잎돼지풀 기반 바이오차를 이용한 비소 및 중금속 오염 농경지의 안정화)

  • Koh, Il-Ha;Kim, Jungeun;Kim, Gi Suk;Park, Mi Sun;Kang, Dae Moon;Ji, Won Hyun
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.87-100
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    • 2016
  • Biochar, which has high alkalinity, has widely studied for amendment of soil that contaminated with heavy metals. The aim of this study is assessment of amendment for arsenic and heavy metals contaminated acidic agricultural soil using biochar that derived from buffalo weed (A. trifida L. var. trifida). Pot experiments were carried out including analysis of soil solution, contaminants fractionation, soil chemical properties and plant (lettuce) uptake rate. Arsenic and heavy metals concentrations in soil solution showed relatively low in biochar added experiments when compared to the control. In the heavy metals fractionation in soil showed decrease of exchangeable fraction and increase of carbonates fraction; however, arsenic fractionations showed constant. Soil chemical properties indicated that biochar could induce recovery of soil quality for plant growth in terms of soil alkalinity. However, phosphate concentration in biochar added soil decreased due to Ca-P precipitation by exchangeable calcium from biochar. Arsenic and heavy metals uptake rate of plant in the amended experiment decreased to 50% when compared to the control. Therefore biochar derived from buffalo weed can be used as amendment material for agricultural soil contaminated with arsenic and heavy metals. Precipitation of As-Ca and metal-carbonates are major mechanisms for soil amendment using char.

A Study on the Heavy Metal Contents in Fish and Sediments of the Mankyung River (일부 河川流域의 淡水魚와 沈積土의 중금속 함량에 관한 연구)

  • 황인담;기노석;양기승;이재형;김남송
    • Journal of Environmental Health Sciences
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    • v.15 no.1
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    • pp.33-49
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    • 1989
  • Pollution in the rivers has received considerable attention in recent years, particullary with reference to the effect due to increasing concentration of heavy metals. The metals are toxic to the ecosystem as a whole and to man in particular, since he is at the end of a variety of food chains by virture of his varigated diet. In addition, numerous laboratory tests have established that certain metals, such as Cd, pose a threat to a wide variety of aquatic organisms at concentrations as low as a few $\mu$g/1. Before the biological effects of heavy metals in impacted ecosystems can be completely assessed, however it is necessary to provide data on the concentration of heavy metals in such systems. This study was performed to investigate the concentration level of heavy metals in water, fish and sediments from upstream ($S_1-S_4$) to downstream ($S_5-S_9$) of the Mankyung river. Samples of water, fish, and sediments were collected along the tributaries of the Mankyung from September to October in 1987 and analyzed for lead, cadmium, copper, and zinc by atomic absorption spectrophotometer. From the data presented in this study, we can infer that the concentrations of the heavy metals investigated both in water and sediments are similar to those found in literature for unpolluted regions. The results obtained from the analysis of the edible tissue of the C. auratus show low concentration levels of the four heavy metals investigated. We conclude that the area is still relatively unpolluted and recommended continuing the monitoring of heavy metal concentrations to improve our understanding of their cycle in the river environment.

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Adsorption Characteristics of Heavy Metals in Wastewater on Bone Charcoal (Bone Charcoal에 의한 폐수증의 중금속 흡착특성)

  • Chung, Paul-Gene;Kwak, Dong-Heui;Lee, Jae-Wook
    • Journal of Korean Society on Water Environment
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    • v.16 no.4
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    • pp.555-563
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    • 2000
  • The study was conducted to evaluate the adsorption equilibrium of heavy metals on bone charcoal made of livestock bone which was sintered at $550{\sim}600^{\circ}C$. Analysis of bone charcoal by XRD and FT-IR showed that crystal structure was similar to that of synthetic hydroxyapatite. Adsorption equilibrium capacity of single component (Pb, Cd, and Zn) on bone charcoal could be expressed as Langmuir, Freundlich, and Sips equations. Sips isotherm was best among the three isotherms. The values predicted by IAST(ideal adsorbed solution theory) showed good relationship to the experimental data in multicomponent adsorption equilibrium. Adsorption affinity was in order of Pb, Cd, and Zn. The order was same in case of activated carbon or synthetic hydroxyapatite. Through the study results. it would be expected that bone charcoal made of livestock could be used in field of wastewater treatment plants as adsorbent to remove heavy metal.

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A Study on the Distribution of Heavy Metals in Soils and Native Plants of Goggyochun (곡교천 주변의 토양과 자생식물의 중금속분포에 관한 연구)

  • Cho, Hae-Yong;Choi, Chang-Ha
    • Journal of Environmental Impact Assessment
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    • v.9 no.4
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    • pp.339-348
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    • 2000
  • This study was conducted to investigate the distribution pattern of plants on the streamside of Goggyochun, and to survey the distribution of heavy metal-contaminated soils and plants. A total of 11 survey sites were selected along the Goggyochun during the period of between June and September 1999. The wet land plants were composed of 44 species. The most frequently occurring species in the study sites were Rumex crispus, Persicaria hydropiper, Cyperus amuricus and Setaria viridis, and among them the Humulus japonicus, Erigeron canadensis and Phragnites communis species were dominants of the community. Analysis of soil properties showed that organic matter and clay contents were higher in the upstream region while sand content was higher in the downstream region. The pH and the organic matter contents of soils were at range of 6.70-9.94 and 2.39-15.16% respectively. The average contents of Pb and Cd in soils were 11.96mg/kg and 1.64mg/kg respectively, and these values were higher as compared with those of ordinary soil in Korea. The average contents of Zn and Pb in Persicaria hydropiper were 8.30mg/kg and 7.38mg/kg respectively, and these values were higher than other plants. The distribution of heavy metals in plants varied in accordance with the species regardless of the sites.

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The effects of heavy metals on microbial biomass and activity in contaminated urban park soils (도시 공원의 토양에서 중금속이 미생물의 생체량과 활성에 미치는 영향)

  • Kim, Ok-Kyung;Paul Birch
    • The Korean Journal of Ecology
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    • v.15 no.3
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    • pp.267-279
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    • 1992
  • The relationship between pb, zn, cd, and the microbial biomass and activity were investigated in three public park soils of central and outer london. Variability with distance from the roadside and profile were studied. The heavey metal concentrations were the highest in hampstead heath and hyde park with high trafic density and the lowest in hainault. The highest concentrations of heavy metals were found adjacent to the roadside in the upper parts of the soil profile. Dehydrogenase activity, adenosine tri-phosphate and ergosterol contents used as indices of micrbial biomass and activity, were generally higher in hainadult, and also higher in the upper pats of the soil profile. Simple regression analysis indicated that the microbial biomass and activity were affected significantly by moisture content, water holding capacity, total organic carbon, total nitrogen, and organic mater rather than heavy metal concentration. Highest inputs of nitrogen and carbon were associated with high inputs of heavey metals, all three being derived from vehicle emissions adjacent to the road. The hyde park and hampstead heath microbial populations were able to respond to the c and n input positively by increase in biomass and activity, whereas the hainault populations could not. This rsult suggrsts adaptation in he former to heavy matals, but not in the latter.

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Uptake of Heavy Metals by Radish (Raphanus sativus cv. sodamaltari) from the Soils after Long-Term Application of Organic Wastes (유기성 폐기물 장기시용 후 토양에서 무 (Raphanus sativus cv. sodamaltari)의 중금속 흡수)

  • Kwon, Soon-Ik;Jang, Yeon-Ah;Kim, Kye-Hoon;Jung, Goo-Bok;Kim, Min-Kyeong;Hwang, Hae;Chae, Mi-Jin;Kim, Kwon-Rae
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.1
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    • pp.65-72
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    • 2013
  • This study was carried out to understand the long-term effects of organic waste treatments on the fate of heavy metals in soils originated from the organic wastes and consequent uptake of heavy metals by plant, together with examination of changes in soil properties and plant growth performance. In this study, the soils treated with three different organic wastes (municipal sewage sludge, alcohol fermentation processing sludge, pig manure compost) at three different rates (12.5, 25.0, 50.0 ton $ha^{-1}yr^{-1}$) for 7 years (1994 - 2000) were used. To see the long-term effect, plant growth study and soil examination were conducted twice in 2000 and 2010, respectively. There was no additional treatments of organic wastes for 10 years after the organic waste treatment for 7 years. Compared to plant growth examination conducted in 2000 using radish (Raphanus sativus cv. sodamaltari), it appeared that height, root length and diameter, fresh weight of radish grown in 2010 decreased in the plots treated with municipal sewage sludge and alcohol fermentation processing sludge and that the extent of decrease was higher with increase of sludge application rates. On the other hand, pig compost treatment increased plant height, root length and diameter, fresh weight with increasing application rates. Cu and Pb concentrations in radish root and leaves increased in 2010 compared to those in 2000 while Ni concentrations in root and leaves decreased. Zn concentration was increased only in the soils treated with pig manure compost. Multiple regression analysis among heavy metal species fractions in soils, soil pH, and metal concentrations in radish root and leaves indicated that the metal uptake by radish was governed mainly by the soil pH and subsequent increase of available heavy metal fractions in soils with organic waste treatments.