• 한국환경과학회지
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• 제9권5호
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• pp.409-414
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• 2000

In order to examine the availability and effectiveness of crab shell for the removal of heavy metals in aqueous solution the crab shell was compared with cation exchange resin(CER), zeolite granular activated carbon (GAC) and powdered activated carbon(PAC) on aspects of heavy metal removal capacity rate and efficiency. In the removal of Pb, Cd and Cr, the heavy metal removal capacity of crab shell was higher than those of any other sorbents (CER, zeolite, GAC, PAC) and the order of heavy metal removal capacity was crab shell>CER>zeolite>PAC GAC. However in the removal of Cu, the result of crab shell was slightly lower than that of CER. The initial heavy metal removal rate was affected by the sorts of sorbents and metals. In all heavy metals the heavy metal removal rate of crab shell was higher than those of any other sorbents. Under the heavy metal concentration of 1.0 mmole/$\ell$ the heavy metal removal efficiency of crab shell was maintained as 93~100% which was much higher than those of any other sorbents.

• The Korean Journal of Ecology
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• 제22권5호
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• pp.295-298
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• 1999

산림지역의 강우분석에 의한 중금속 농도를 분석한 결과, Al의 수종별 농도는 공단지역의 해송림이 상수리나무림보다 1.3배 높았고, 도시지역은 해송림이 2.1배 높았다. 공단지역과 도시지역 수간류의 Al 농도는 수관통과우와 임외우 보다 각각 2.3배와 192.5배, 4.8배와 55배 높은 농도였고, 임외우는 두 지역에서 같은 농도로 낮았다. Mn의 농도는 수종별 농도는 도시지역의 해송림이 1,4배 높았다. Mn의 강우별 농도는 수간류가 수관통과우 보다 6.1배 높았고, 임외우 보다 121배 높은 농도였다. 강우의 계절별 농도를 분석한 결과에서 Al은 공단지역에서 12월의 강우가 가장 높았고, 다음으로 3월, 6월, 8월 순으로 분석되었지만, 도시지역은 계절별 뚜렷한 변화가 없었다. 지역별 중금속의 농도는 공단지역에서 Al>Mn>Ni의 순이었고, 도시지역은 Mn>Al>Ni의 순으로 조사되었다.

• 환경영향평가
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• 제5권2호
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• pp.21-31
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• 1996

To assess the impact resulted from the slag dumping, we studied that the changes in the concentration of heavy metal were researched through the statistic analysis at 4 stations in Yongil bay, Korea from 1988 to 1995. And in order to clarify resulting from the changes in heavy metal concentration due to be leaked out from dumped slag, it was fulfilled experiments of the slag extraction. In the extracting experiment, Pb and As were only leaked out from slag aged during 10 days but all of heavy metals were not from it aged during 90 or 180 days. It was found that the concentrations of heavy metals in sea water of vincinity of slag dumping area were still remained in similar, comparing with it of control site(site 4) when they were by analysed statistic method, anova test and Mann-Whitney test. The slag recycling ratio of our country is lower than foreign country. While we need to apply a new process for phosphate treatment, foreign country already apply a slag to phosphorous removal. We suggest that slag dumping cannot putatively affected the changes in the concentration of heavy metal. And we thought that impact of heavy metal induced by slag dumping was not severe. So, it is necessary to utilize this process in phosphorous removal, like a foreign country.

• 한국환경보건학회지
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• 제36권6호
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• pp.480-495
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• 2010

This study evaluated the distribution of the concentrations of nano-particles and heavy metals (08-Pb, Cr, Zn, As, Fe, 09-Pb, Cr, Zn, Cu, Ni, Mn) in Seoul, Chungnam A and Gwangyang from August to December, in 2008 5 times each in the Seoul area, 5 times in and Chungnam A area and from August to November, in 2009 14 times in the Chungnam A area, 8 times in the Gwangyang area. The examined results showed high concentration level from $PM_1$ through $PM_{0.1}$ in all three areas. These results were obtained the concentration of particles by diameter and statistically significant in Stage5 (1.0-0.56 ${\mu}m$) from the result of conducting Kruskal-Wallis H test (p < 0.05). In the case of the heavy metal concentration included in 0.10-0.056 ${\mu}m$, 0.056 ${\mu}m$, the lead concentration of Chungnam Asan area was 6.49 ng/$m^3$ and 9.93 ng/$m^3$, which was higher than 3.05 ng/$m^3$ and 4.22 ng/$m^3$ of Seoul, respectively. The concentration of iron in Seoul was 9.28 ng/$m^3$ and 13.24 ng/$m^3$, that appeared higher than 2.38 ng/$m^3$ and 3.23 ng/$m^3$ of Chungnam A area, respectively. The concentration level was similar to other metals except lead and iron in Chungnam A area and Seoul. From the concentration of heavy metal included in 0.10-0.056 ${\mu}m$, 0.056 ${\mu}m$, the lead concentration of Chungnam A area was 0.31 ng/$m^3$ and 0.12 ng/$m^3$ while Gwangyang was 0.28 ng/$m^3$, 0.06 ng/$m^3$. Thus Chungnam A area showed higher lead concentration than Gwangyang. The manganese concentration of Chungnam A area was 0.12 ng/$m^3$ and 0.03 ng/$m^3$ while Gwangyang was 0.21 ng/$m^3$ and 0.08 ng/$m^3$. Therefore, the concentration of Gwangyang appeared higher than that of Chunnam A area. These two metals showed statistically significant in 0.056 ${\mu}m$ (p < 0.05, p < 0.01). Among the concentration of heavy metal in all regions, the result demonstrated that the order of higher concentration is arsenic > iron > zinc > chrome > lead > nickel > copper > manganese.

• 한국환경과학회지
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• 제9권6호
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• pp.495-503
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• 2000

Dust samples were collected from 17 middle and high schools in the Jeonju-city. heavy metal concentrations were determined for the dry-deposited dusts from indoor and outdoor of classroom and playground of each sampling site. Concentrations of Cd, Cr, Cu, Ni, Pb and Zn in indoor\`s dusts were highly concentrated. Also heavy metal concentrations in outdoor\`s dusts were similar to that of indoor\`s dusts. Concentrations of Cd, Cu, and Zn in the dusts were much higher than the world average contents in soil and environmental orientation value. These levels are similar to those of the dust samples at middle schools located at Kangseo-gu and Yangchon-gu , Seoul. Playground dusts in 6 schools exhibited the enhanced heavy metal pollution with a pollution index (by Kloke) greater than 1.0. Most indoor and outdoor dusts exhibited the enhanced heavy metal pollution with a pollution index(by Cullbard et al.) greater than 1.0.

• 환경위생공학
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• 제22권1호
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• pp.29-35
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• 2007

This study was examined adsorption ability of heavy metal Hg(I), Pb(II), and U(Vl) ion use of fruit from schizandra chinensis, The fruits of schizandra chinensis sample used breaking into fragments $50{\sim}100$ mesh. The sample solution was mixed fruits of schizandra chinensis and heavy metal ion. Each heavy metal ion of into solution was quantum analysis with ICP-AES. As the result, each condition of maxium adsorption ability of heavy metal ion was high in the range of pH 5-7, adsorption time was about 15 minutes, and the optimum temperature was $100^{\circ}C$. The heavy metal ion was increased adsorption in order of increasing concentration and in ethanol solution better than in aqueous solution.

• 한국환경농학회지
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• 제16권2호
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• pp.115-118
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• 1997

When the light metals such as $Ca^{++}$ and $Mg^{++}$ were added to heavy metal solution, the adsorption of heavy metals was increased by 20 to 30% more, but there were no differences between species. $Pb^{++}$ was the most adsorbed metal(99.5%), and the adsorption ratio of $Cd^{++}$ was significantly improved. In addition, when the light metal concentration was increased to 100ppm, the adsoption ratios of all four heavy metals were reached to 92 to 99%, while coniferous barks showed only 85 to 92%. On the mixture of four heavy metals, the adsorbed amount of each metal was significantly reduced, compared with that of one heavy metal, while $Zn^{++}$ showed the adsorption improvement to 95%. On the column experiment, $Pb^{++}$ was almost completely adsorbed in the upper part of column, and the adsorbed amount of $Cu^{++}$ was gradually decreased depending on column depth. However, $Cd^{++}$ and $Zn^{++}$ were not influenced by column height, and constantly adsorbed on various column height. Based on the above results, each heavy metal had different adsorption mechanism.

• 한국지하수토양환경학회지:지하수토양환경
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• 제27권4호
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• pp.63-74
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• 2022

In analyzing heavy metals in soil samples, the standard protocol established by Korean Minstry of Environment (KSTM) requires two different pretreatments (A and B) based on soil particle size. Soil particles < 0.15 mm in diameter after sieving are directly processed into acid extraction (method A). However, if the quantity of soil particles < 0.15 mm are not enough, grinding of the particles within 0.15 mm ~ 2 mm is required (method B). Grinding is often needed for some field samples, especially for the soil samples retrieved from soil washing process that contain relatively large-sized soil grains. In this study, two soil samples with different particle size distribution were prepared and analyzed for heavy metals concentrations using two different pretreatment to investigate the effect of grinding. The results showed that heavy metal concentrations tend to increase with the increase of the fraction of small-sized particles. In comparison of the two pretreatments, pretreatment A yielded higher heavy metal concentration than pretreatment B, indicating significant influence of grinding on analytical results. This results suggest that the analytical values of heavy metals in soil samples obtained by KSTM should be taken with caution and carefully reviewed.

• 한국환경보건학회지
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• 제18권1호
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• pp.47-57
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• 1992

This study was performed to evaluate contamination degree of heavy metals in sediments of Han River, compared with other nation's evaluation method. The results were as follows 1. The contamination Ratio calculation method by heavy metal concentration in differnt fraction size has a limitation to apply to all of the areas of Han river because of its characteristics of sediment. As a result, this method applied to only 4 areas of Pal Dang, Wang Sook Chon, Uk Chon, and Bul Kwang Chon, and Contmination Ratio of heavy metals in those areas were relatively low of below 3. So it's considered that those areas have less contaminated from anthropogenic contaminants. 2. The Contamination Ratio calculation method by heavy metal concentration in different areasthat of upper area to be background level-has a limitation also to apply to Han river. But it is considered that this method was relatively suitable to apply, so it should be prepared evaluation standand method for them. Contamination ratio from background level as Pal Dang area were most high in An Yang Chon. So it must be prepared purification and control measure at An Yang Chon.

• 한국토양비료학회지
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• 제49권6호
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• pp.768-775
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• 2016

Heavy metal pollution in arable field is an critical problem due to crop safety. For this reason, national survey of heavy metal pollution in the arable field near at the industrial area has been conducted from 1999 in Korea. The main purpose of this research was to monitor heavy metal pollution in Chungnam/chungbuk province and to evaluate pollution index (PI) in soil. Total of 15 sampling locations were examined and average concentration of each heavy metals were following: As - $2.99{\pm}2.63$, Cd - $0.23{\pm}0.07$, Cu - $9.35{\pm}6.48$, Ni - $9.26{\pm}8.03$, Pb - $10.18{\pm}3.32$, Zn - $52.9{\pm}17.18$. No sampling site was exceeded threshold level of each heavy metals. Calculated PI in soil was ranged between 0.03 - 0.27 indicating that also no heavy metal pollution is occurred in examined sampling locations. Although, no heavy metal pollution was observed in the examined sites but monitoring of heavy metal pollution should be continued for possible accidental pollution in arable field near at the industrial area.