• Title/Summary/Keyword: Heating-hydration

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Study on Utilization of Converter Slag as Concrete Admixture

  • Satou, Masaki;Tsuyuki, Naomitsu;Umemura, Yasuhiro;Harada, Hiroshi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.514-519
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    • 2001
  • Converter has been slag produced 10 million tons per year in Japan. It is a steel making by product produced in the same way as the blast-furnace slag. Though blast-furnace slag is being used effectively as a concrete admixture, the converter stag has never been used effectively because of the expansion action of contained free lime and iron oxide. This is an important environmental problem in the steel industry. Beta-2CaOSiO$_2$(beta-C$_2$S) is contained 40 percent in converter slag, therefore it is very promising as a concrete admixture. We proposed an accelerated aging processes capable of stabilizing the converter slag in a short time. The converter slag is dipped into alkali aqueous solution after heating at low temperature. It was subsequently ground to a grain size of 75 ${\mu}{\textrm}{m}$ , inner 30 percent of OPC. The properties of mortar and concrete using the blended cement were determined. As a result, it has become apparent that the expansion was reduced and long term compressive strength was increased while that at early ages was not so remarkable. The hydration exotherm rate was lower than that of the OPC.

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Study on the Properties of Field Applied Non-Curing Concrete in Winter Season (동절기 무양생 콘크리트의 현장적용 성능 평가에 관한 연구)

  • Yoo, Jo-Hyeong;Kim, Woo-Jae;Hong, Seok-Beom;Kim, Hyeong-Cheol;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.5
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    • pp.413-419
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    • 2016
  • In the cold-weathering concrete construction, it is important to ensure stable strength development of concrete in a low temperature environment. In this study, Non-curing cement(NCC) using the classified high fineness cement and self-heating powder was investigated for stable strength development without curing in a low temperature environment (less than $0^{\circ}C$). The actual size Mock-Up tests by various cement type and curing condition are performed to evaluate the strength development and hydration heat of concrete.

Carbonation Properties of Recycled Cement Mortar made of Cementitious Powder from Concrete Waste (폐콘크리트 미분말을 이용한 재생시멘트 모르터의 중성화 특성)

  • Park, Cha-Won;Ahn, Jae-Cheol;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.6 no.4 s.22
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    • pp.61-68
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    • 2006
  • Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement's performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

Determination of Energy and Time Requirement for Cooking Pigeon Pea (Cajanus cajan)

  • Akinoso, Rahman;Oladeji, Ojeronke Dewum
    • Journal of Biosystems Engineering
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    • v.42 no.1
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    • pp.56-61
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    • 2017
  • Purpose: High energy requirement and long cooking time are limiting consumption of pigeon pea (Cajanus cajan), a nutritious food. This study was performed to estimate energy and time demand by different methods of cooking pigeon pea. Methods: Pigeon pea (150 g) was soaked in 2.0 L of water at ambient temperature ($29{\pm} 2^{\circ}C$) to determine hydration behavior. Cooking experiments were conducted using aluminum and pressure-cooking pots. Efficiency of cooking was evaluated using four types of cooking appliances (kerosene, liquefied petroleum gas (LPG), electric, and charcoal stoves). Normal (continuous heating until the food was satisfactorily cooked) and control (controlling the energy input to closely match the actual energy required) cooking were conducted. Energy requirement and duration of cooking were determined using standard procedures. Results: Soaking increased moisture content from 11.99 to 30.01% in 90 min, while water absorption rate decreased with soaking duration. In cooking 150 g of pigeon pea using kerosene stove, presoaked normal pressure-pot cooking method consumed the least energy (10 800 kJ) and time (205 min), while unsoaked normal cooking consumed the highest energy (18 450 kJ) and time (336 min). Using LPG stove, unsoaked normal cooking method required the highest energy (52 470 kJ), while presoaked control pressure-pot required the least energy (14 405 kJ). For electric stove, the lowest energy (15 560 kJ) and shortest duration (105 min) were recorded during control cooking of presoaked sample in the pressure-pot. Conclusions: Control cooking was not practicable using charcoal stove. Generally, kerosene stove consumed the least energy, while electric stove was found to have the shortest duration of cooking.

Effects of CNT Additions on Mechanical Properties and Microstructures of Cement (CNT 첨가량에 따른 시멘트의 역학성능 및 미세구조의 영향)

  • Oh, Sungwoo;Oh, Kyeong-seok;Jung, Sang-hwa;Chung, Wonseok;Yoo, Sung-won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.162-168
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    • 2017
  • Carbon nanotube(CNT) is one of the promising construction materials to produce concrete with high strength and durability by adding in the concrete mixtures from various researches. Also, its superior heat conductivity can be one of the options to develop self-heating concrete. In this research, the fundamental study was conducted to investigate mechanical properties and microstructures of cement pastes and mortars by strength tests and porosity measurement with several CNT additions, which were 0 wt%, 0.115 wt%, 0.23 wt% and 0.46 wt% of CNT-cement ratio. Compressive and flexural strength test were conducted at 3, 7 and 28 days, and pore characteristics were investigated by mercury intrusion porosimetry. SEM-EDS and Thermogravimetric analysis(TGA) were conducted to prove the hydration product types and CNT dispersion in the cement matrix. As a result, even though high amount of CNT additions were caused worse performance, mixtures with 0.115 wt% of CNTs developed the similar performance with plain mixture.

Field Application of the Mass Concrete Using Insulation Curing Method with Double Bubble Sheets Subject to Cold Weather (이중버블시트를 이용한 단열보온양생공법의 한중매스콘크리트 현장적용)

  • Lee, Dong-Gyu;Kim, Jong;Kim, Ki-Hoon;Hwang, Yin-Seong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.1-4
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    • 2007
  • This study investigated the applicability of insulation curing method with double layer bubble sheets to the man concrete subjected to cold weather. Temperature history of the mass concrete indicated that the highest temperature of center section was exhibited at $34^{\circ}C$ while the that of surface section was $25^{\circ}C$. Difference between center and surface was shown to be less $10^{\circ}C$ when the temperature of center section was peak section, and thereby associated temperature cracking index was calculated 1.5, and occurrence probability of temperature cracking was 5%, so there was no temperature cracking caused by internal restraint. No temperature crack was observed by naked eye. It was clear that early frost demage and temperature cracking could be restrained due to reducing temperature difference between inner part and outside in the case double bubble sheets applied to insulation curing method in cold weather. The maturity of mass concrete is higher than outside about $72\sim89^{\circ}$ DD, so it was demonstrated to prevent early frost demage and ensure strength excellently. Insulation curing method with double bubble sheets was more economic than heating curing method.

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Investigation of the Effects of CNT Dosages on the Hydration and Heating Properties of Cement Composites with Low Water-to-binder Ratio (낮은 물-바인더 비를 갖는 시멘트 복합체의 CNT 첨가량에 따른 수화특성 및 발열특성)

  • Oh, Sungwoo;Jung, Sang-hwa;Chung, Wonseok;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.182-188
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    • 2018
  • Recently, various researches on the utilization of carbon nanotube(CNT) with superior electrical conductivity and large surface areas into concrete have been actively conducted. Thus, mechanical and thermal properties of cement-flyash composites were evaluated concerning the CNT replacements. Based on the low binder-to-water ratio, the cement composites were produced with 0.2 % and 0.5 % of CNT solids. The compressive strengths with various ages, isothermal calorimetry measurement, SEM analysis, thermal conductivity of cement composites and thermal gravimetry analysis were implemented. As the amount of CNT addition was increased, the thermal conductivity of cement composites were also increased. Also, there was no significant mechanical property differences between mixtures with and without CNTs.

Effects of hydration pretreatment on small molecule amphiphiles(SMA) at two levels in reduced-calorie cake systems (수화 전처리에 따른 양쪽성 저분자 유화제(Small Molecule Amphiphile)의 첨가 수준이 저 열량 케익 체계에 미치는 영향)

  • 김혜영;셋서케롤
    • Korean journal of food and cookery science
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    • v.10 no.1
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    • pp.8-12
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    • 1994
  • The effects of small molecule amphiphiles(SMA) at 1.5 and 15% levels were compared with or without heating to 65$^{\circ}C$ and cooling pretreatment in modified reduced-calorie cake systems. The SMA used were monoglycerides(MG), sorbitan monosterate(SMS), VanallR polysorbate 60(PS60), surose ester(SE) F10, F70, and F160, Low batter specific gravities with high cake voumes were noted with the high levels of treated SMS, MG, and SE F10 and F70 or cakes with treated low levels of SEF160, F70 and PS 60. Cake volumes with the treated low levels of SEF160, F70, and PS 60 were comparable to cake volumes when using an untreated high level of Vanall$\^$R/.

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Multicomponent assessment and ginsenoside conversions of Panax quinquefolium L. roots before and after steaming by HPLC-MSn

  • Huang, Xin;Liu, Yan;Zhang, Yong;Li, Shuai-Ping;Yue, Hao;Chen, Chang-Bao;Liu, Shu-Ying
    • Journal of Ginseng Research
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    • v.43 no.1
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    • pp.27-37
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    • 2019
  • Background: The structural conversions in ginsenosides induced by steaming or heating or acidic condition could improve red ginseng bioactivities significantly. In this paper, the chemical transformations of red American ginseng from fresh Panax quinquefolium L. under steaming were investigated, and the possible mechanisms were discussed. Methods: A method with reversed-phase high-performance liquid chromatography coupled with linear ion trap mass spectrometry ($HPLC-MS^n$)-equipped electrospray ionization ion source was developed for structural analysis and quantitation of ginsenosides in dried and red American ginseng. Results: In total, 59 ginsenosides of protopanaxadiol, protopanaxatriol, oleanane, and ocotillol types were identified in American ginseng before and after steaming process by matching the molecular weight and/or comparing $MS^n$ fragmentation with that of standards and/or known published compounds, and some of them were determined to be disappeared or newly generated under different steaming time and temperature. The specific fragments of each aglycone-type ginsenosides were determined as well as aglycone hydrated and dehydrated ones. The mechanisms were deduced as hydrolysis, hydration, dehydration, and isomerization of neutral and acidic ginsenosides. Furthermore, the relative peak areas of detected compounds were calculated based on peak areas ratio. Conclusion: The multicomponent assessment of American ginseng was conducted by $HPLC-MS^n$. The result is expected to provide possibility for holistic evaluation of the processing procedures of red American ginseng and a scientific basis for the usage of American ginseng in prescription.

Durability Evaluation of High-Performance, Low-Heat Self-Compacting Concrete for Foundation of Tall Buildings (초고층 건축물 매트 기초용 고성능 콘크리트 내구성 평가)

  • Kim, Young-Bong;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.5
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    • pp.425-430
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    • 2022
  • Concrete used for the foundation of high-rise buildings is often placed through in an integrated pouring to ensure construction efficiency and quality. However, if concrete is placed integrally, there is a high risk of temperature cracking during the hydration reaction, and it is necessary to determine the optimal mixing design of high-performance, high-durable concrete through the replacement of the admixture. In this study, experiments on salt damage, carbonation, and sulfate were conducted on the specimen manufactured from the optimal high-performance low-heating concrete combination determined in the author's previous study. The resistance of the cement matrix to chlorine ion diffusion coefficient, carbonation coefficient, and sulfate was quantitatively evaluated. In the terms of compression strength, it was measured as 141% compared to the structural design standard of KCI at 91 days. Excellent durability was expressed in carbonation and chlorine ion diffusivity performance evaluation. In particular, the chlorine ion diffusion coefficient, which should be considered the most strictly in the marine environment, was measured at a value of 4.09×E-12m2/y(1.2898×E-10m2/s), and is expected to be used as a material property value in salt damage durability analysis. These results confirmed that the latent hydroponics were due to mixing of the admixture and high resistance was due to the pozzolane reaction.