• Title/Summary/Keyword: Heating-hydration

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Engineering-scale Test for Validating the T-H-M Behavior of a HLW Repository: Experimental Set-up

  • Lee, Jae-Owan;Baik, Min-Hoon;Cho, Won-Jin
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.194-198
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    • 2004
  • The thermo-hydro-mechanical (T-H-M) process is one of major issues in the performance assessment of a high level waste (HLW) repository. An engineering-scale test was planned and its experimental set-up has being installed, to validate the T-H-M behavior in the buffer of a reference disposal system. The experimental set-up consists of 4 major components: the confining cylinder with its hydration water tank, the bentonite block, the heating system, and the sensors and instruments. The monitoring and data acquisition system is employed to control the heater to maintain the temperature of $95^{\circ}C$ at the interface of the heater and bentonite blocks and to collect signals from sensors and instruments installed in the bentonite blocks.

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A Study on the Cold Weather Concrete using High Early Strength Concrete (조강시멘트를 이용한 한중콘크리트의 특성평가 연구)

  • 임채용;엄태선;유재상;이종열;이순기;이동호
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.261-264
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    • 2003
  • Cold weather can lead to many problems in mixing, placing, setting time, and curing of concrete that can have harmful effects on its properties and service life. Korean Concrete Institute (KCI) defines cold weather as a period when the average daily air temperature is less $4^{\circ}C$ and recommends to cast concrete with special care such as shielding, heating and so on. The use of high early strength cements may improve the rate of hardening characteristics of concrete in cold weather by making it possible to achieve faster setting time and evolving more hydration heat than ordinary Portland cement. Higher early strength can be achieved using Type III cement especially during the first 7 days. The strength increase property of Type III cement at low temperature was studied. As a conclusion the heat or heat insulation curing period can be reduced to 50~75%. So, it can be used for cold weather concreting to reduce construction cost and extend the construction season.

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Mechanical Properties of Blast Furnace Slag Fineness Mortar according to Alkali Activator (알칼리 자극제 종류에 의한 고로슬래그 미분말 모르타르의 강도 특성)

  • Kim, Jong-Hee;Kim, Gyu-Yong;Shin, Kyoung-Su;Nam, Jeong-Soo;Koo, Kyung-Mo;Yun, Yong-Sang
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.217-218
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    • 2011
  • The advantages of blast-furnace slag concrete may include lower hydration heating velocity, restraint on concrete temperature increase, long-age strength improvement due to latent hydraulic reaction, improved water tightness, and repulsion to chemical erosion. These advantages contribute to the high quality of the blast-furnace slag concrete. However, the blast-furnace slag concrete has its limitations as well. These disadvantages may include retarded setting and elongated retention of mold due to the weak strength of early-age. Nevertheless, much research is currently under way to improve the aforementioned issues. To improve activity of blast furnace slag powder, alkaline irritants has been used. In this study, we analyze effect on activity fineness and rate of substitution of Alkali Activator toward activity.

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Preparation of High-Temperature catalytic Support from Gibbsite II. Properties of Amophous Alumina as Precursor of Catalyst Support (깁사이트를 원료로 한 고온촉매용 담체의 제조 II, 비정질 알루미나의 담체 전구체로서의 특성)

  • 김성연;김연식
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.92-100
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    • 1996
  • Amorphous alumina(AA) the precursor of ${\gamma}$-alumina for catalyst support was made in the newly designed ball filled heating column. Some properties of AA as precursor were investigated. In observation of microstruc-ture and pore structure of AA and its derivatives scanning electronic microscope(SEM) and transmission electronic microscope(TEM) were used. It was found that the width of one particle in AA was 45~60$\AA$ and the average distance among the particles ranged 9~12 $\AA$ which suggested a micropore structure. When AA was reacted with water the shape of the surface was found to be altered and acicular bioehmite was formed inside AA which contributed inproved formability. Pore distribution was evaluated for the three samples of AA ground and granulated lump and La2O3 coated alumina. Acid sites were quantitatively determined by ammonia TPD method and the effect of impurity of Na on acid sites was discussed. Water adsorption capacity was evaluated in terms of a desiccant.

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Effects of Aggregate Mixing on the Strength Properties of Fire-Damaged Concrete (골재 혼입 유무가 고온수열 콘크리트의 강도 특성에 미치는 영향)

  • Kwon, Hyun-Woo;Kim, Young-Min;Heo, Young-Sun;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.133-134
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    • 2021
  • In this study, the effects of aggregates on the properties of concrete as a study to determine the mechanical properties of high-temperature damaged concrete were examined. The samples to be reviewed are cement paste, mortar, and concrete, and the strength characteristics were reviewed after heating the compression strength and tensile strength properties. The increase in magnetic shrinkage at around 100℃ showed a significant drop in strength in mortar, which does not contain aggregates or has a small diameter, and after 300℃, concrete showed a sharp drop in strength due to the hydration and aggregation of cement.

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A Study on the Durability of Concrete for High-rise Concrete Mat Foundation (초고층 콘크리트 매트 기초용 콘크리트 내구성에 관한 연구)

  • Park, Dong-Choen;Kim, Young-Bong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.115-116
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    • 2022
  • Large concrete mass members are commonly used as matte bases for skyscrapers. In general, Integral casting is preferred to secure construction convenience and durability quality rather than separate casting. However, there is a possibility that cracks may occur in the early stages due to the generation of a lot of hydration heat, and thus durability will decrease, so it is necessary to determine an appropriate mixture and verify it through experiments. The purpose of the study was to conduct a review on the durability of the optimal high-performance low-heating concrete combination derived through the experiment and to conduct a review analysis on the performance satisfaction and performance expression mechanism.

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Study on Hydration Properties of High Strength Mass Concrete to apply Precast Concrete (PC 적용을 위한 고강도 매스콘크리트의 수화특성에 관한 연구)

  • Park, Heung-Lee;Kim, Sung-Jin;Lee, Hoi-Keun;Lee, Seung-Hoon;Park, Byung-Keun;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.661-664
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    • 2008
  • As architectures have recently become high-risers and megastructured, stable high strength products have been ensured. Accordingly, use of precast concrete accouplement has been increased in order to facilitate air compression and rationalize construction. Since not only external heating but also internal temperature rise caused by the accumulation of cement hydration heat in manufacturing process, precast concrete members with large cross-section used for high-rise mega-structure's columns and beams may exhibit different temperature history compared to the precast concrete members for wall and sub-floor with relatively small cross-sections. Therefore, this study aims to elucidate the characteristics of temperature history of mass concrete members cast with high-strength concrete for precast concrete application. In this study, large cross-sectional precast concrete mock-up, unit cement quantity, and temperature histories in manufacturing precast concrete member under different curing condition were inclusively investigated.

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Study on the Hydration and Strength Properties of Fly-ash Modified Cement Paste and Mortar Using a CSA and Pulp Ash (CSA 및 제지애쉬를 혼합재료 사용한 플라이애쉬 시멘트 모르타르의 수화 및 강도 특성에 관한 연구)

  • Song, Tae-Hyeob;Lee, Sea-Hyun;So, Chee-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.81-88
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    • 2005
  • The fly ash has been widely used in the latest to complement the performance and economical efficiency of the concrete which uses only a normal portland cement, the pulp ash gained through the incineration of paper sludge is possible to be used as the material of concrete because it contains the properties similar to the previous fly ash in ingredients and physical characteristics. Therefore, this research has tested physical characteristics by replacing 20% of fly ash used with the paper ash to solve the problem which lowers the early strength caused when the fly ash was used. As a result, it showed that the fluidity becomes lower and the compressive strength becomes increased by using paper ash. In addition, after mixing the paper ash with the fly ash, it showed that time and heating amount of the 2nd peak of the minor heat of hydration affecting the revelation of strength was equivalent to the combination for normal portland cement, and also indicated that the compressive strength for 3 days is superior to the combination of the fly ash. Therefore, if the paper ash having a regular fineness is used, it was effective in improving the early strength of concrete used the fly ash.

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Carbonation Properties of Recycled Cement Mortar made of Cementitious Powder from Concrete Waste (폐콘크리트 미분말을 이용한 재생시멘트 모르터의 중성화 특성)

  • Kim Jin-Yang;Park Cha-Won;Ahn Jae-Cheol;Kang Byeung-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.61-64
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    • 2005
  • Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement s performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

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Bonding of nano-modified concrete with steel under freezing temperatures using different protection methods

  • Yasien, A.M.;Bassuoni, M.T.
    • Computers and Concrete
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    • v.26 no.3
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    • pp.257-273
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    • 2020
  • Concrete bond strength with steel re-bars depends on multiple factors including concrete-steel interface and mechanical properties of concrete. However, the hydration development of cementitious paste, and in turn the mechanical properties of concrete, are negatively affected by cold weather. This study aimed at exploring the concrete-steel bonding behavior in concrete cast and cured under freezing temperatures. Three concrete mixtures were cast and cured at -10 and -20℃. The mixtures were protected using conventional insulation blankets and a hybrid system consisting of insulation blankets and phase change materials. The mixtures comprised General Use cement, fly ash (20%), nano-silica (6%) and calcium nitrate-nitrite as a cold weather admixture system. The mixtures were tested in terms of internal temperature, compressive, tensile strengths, and modulus of elasticity. In addition, the bond strength between concrete and steel re-bars were evaluated by a pull-out test, while the quality of the interface between concrete and steel was assessed by thermal and microscopy studies. In addition, the internal heat evolution and force-slip relationship were modeled based on energy conservation and stress-strain relationships, respectively using three-dimensional (3D) finite-element software. The results showed the reliability of the proposed models to accurately predict concrete heat evolution as well as bond strength relative to experimental data. The hybrid protection system and nano-modified concrete mixtures produced good quality concrete-steel interface with adequate bond strength, without need for heating operations before casting and during curing under freezing temperatures down to -20℃.