• 제목/요약/키워드: Heating velocity

검색결과 362건 처리시간 0.038초

은행잎 바이오매스로부터 급속 열분해를 통한 바이오-오일 생산 및 특성 연구 (Preparation of Bio-oil from Ginkgo Leaves through Fast Pyrolysis and its Properties)

  • 황인준;전재락;김진수;김승수
    • 청정기술
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    • 제29권3호
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    • pp.200-216
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    • 2023
  • 은행잎은 자체에 존재하는 ginkgolide A, B, C, J 및 bilobalide의 강한 살충작용으로 인해 제대로 분해가 진행되지 않아 그대로 방치할 시 사고를 유발 할 수 있는 폐기물 바이오매스이다. 은행잎 바이오매스는 적절한 기술 적용을 통해 연료나 화학물질로 전환할 수 있다. 본 연구에서는 은행잎의 급속 열분해 반응과정에서 열분해 온도, 최소 유동화 속도, 샘플의 크기를 변화 시키면서 생성물 특성에 대한 연구를 수행하였다. 열분해 온도 400~550℃, 최소 유동화 속도 2.0~4.0 Umf, 그리고 바이오매스 샘플의 크기에 변화 따라 생성물의 수율과 특성의 변화를 확인하였다. 급속 열분해는 기포 유동층 반응기에서 모래를 층 물질로 사용하여 400~500℃ 구간에서 진행하였다. 열분해 후 액상 생성물의 수율은 온도에 따라 33.66~40.01 wt%였으며, 기상 생성물 중 CO2와 CO의 선택성이 높았고, 온도 증가에 따라 CO2의 선택성은 낮아지고 CO의 선택성은 높아졌다. 반응 온도 450℃, 유동화 속도 3.0×Umf, 0.43~0.71 mm 입자 크기에서 급속 열분해를 진행한 결과 40.01 wt%의 바이오-오일 수율을 얻었으며, 30.17 MJ/kg의 고위발열량을 나타냈다. 생성된 바이오-오일을 GC-MS를 통해 분석해본 결과 다양한 페놀 화합물 및 벤젠 유도체가 생성된 것을 확인하였다. 본 연구에서 은행잎 폐기물 바이오매스의 처리와 함께 활용 가능성을 급속 열분해를 통해 확인하였다.

성견에서 발치 직후 Hydroxylapatite의 축조와 조직 유도 재생술이 발치와의 골조직 치유에 미치는 영향 (EFFECT OF HYDROXYLAPATITE SYNTHETIC GRAFT AND GUIDED TISSUE REGENERATION TECHNIQUE ON HEALING OF EXTRACTION SOCKET IN MONGREL DOGS)

  • 한동후;심준성
    • 대한치과보철학회지
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    • 제34권1호
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    • pp.187-200
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    • 1996
  • After loss of tooth, initial healing process is critical to preserve residual alveolar process. This study was conducted to compare the effect of hydroxylapatite particle synthetic graft and guided tissue regeneration procedure on healing of extraction wounds in 5 mongrel dogs. To investigate the maturity of bone and velocity of bone heating, bone-labeled tracers were used. After 16 weeks healing period, dogs were sacrificed. The specimens were treated with Villanueva bone stain. Fluorescence microscopy and polarized microscopy were performed to exam the pattern of bone formation in the extraction socket. The results were following ; 1. Pattern of bone regeneration in the group of hydroxylapatie graft and the group of membrane protection after hydroxylapatite graft was following ; bone regeneration was slow, regenerated bone was immature, and thickness of cortical layer was thin compare to that of untreated control group. 2. Cortical layers in membrane protected group were somewhat thicker but less condense to that of untreated control group. 3. Infiltration of inflammation cells were found in the groups using hydroxylapatite graft and membrane. We concluded that grafting of replamineform hydroxylapatite particles into the extraction socket delayed healing of the wound and disturbed the formation of cortical bone at the roof of extraction socket. The placement of expanded polytetrafluoroethylene membranes on the extraction socket promotes the bone regeneration. But newly formed bone in cortical layer consists of the cortico-cancellous bone in comparison with the cortical bone of the control group.

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압출 적층 조형 기술을 이용한 TCP/HA 의 혼합비율에 따른 바이오 세라믹 인공지지체의 제작 및 특성 연구 (Characteristic Analysis and Fabrication of Bioceramic Scaffold using Mixing Ratios of TCP/HA by Fused Deposition Modeling)

  • 사민우;김종영
    • 대한기계학회논문집A
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    • 제38권11호
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    • pp.1273-1281
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    • 2014
  • 조직공학은 손상된 골 조직 및 장기를 복원, 재생, 그리고 복구할 수 있는 잠재력을 가진 새로운 학문 분야이다. 인산칼슘계 세라믹스인 삼인산칼슘과 수산회인회석은 골 조직 재생을 위해 골전도성과 생체적합성의 특성을 가진 우수한 재료로 알려져 있다. 본 연구에서, 혼합 용액 구조물은 적층 및 히터장치를 기반으로 한 압출 적층 조형 시스템을 이용하여 제작되었다. 바이오 세라믹 인공지지체는 $1,300^{\circ}C$의 고온에서 소결되었고, 또한 형태학적인 특성은 주사전자현미경을 통해 분석되었다. 게다가, TCP/HA 의 혼합비율에 따른 미세구조물과 수축률에 대한 효과는 연구되었다. 인공지지체의 기계적 특성은 1 mm/min 의 크로스헤드 속도로 압축 시험기를 통해 측정되었고, 인공지지체의 세포 증식평가를 위해 MG-63 세포를 이용하였다. 본 연구의 결과는 혼합된 TCP(75 wt%)/HA(25 wt%) 인공지지체가 골 조직 재생을 위해 적합한 인공지지체라는 것을 제안한다.

차량 내부 탑승자의 쾌적성 평가를 위한 초기 냉방운전 성능에 대한 수치해석적 연구 (Numerical Analysis on the Initial Cool-down Performance Inside an Automobile for the Evaluation of Passenger's Thermal Comfort)

  • 김윤기;양장식;백제현;김경천;지호성
    • 한국자동차공학회논문집
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    • 제18권5호
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    • pp.115-123
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    • 2010
  • Cool-down performance after soaking is important because it affects passenger's thermal comfort. The cooling capacity of HVAC system determines initial cool down performance in most cases, the performance is also affected by location, and shape of panel vent, indoor seat arrangement. Therefore, optimal indoor designs are required in developing a new car. In this paper, initial cool down performance is predicted by CFD(computational fluid dynamics) analysis. Experimental time-averaging temperature data are used as inlet boundary condition. For more reliable analysis, real vehicle model and human FE model are used in grid generation procedure. Thermal and aerodynamic characteristics on re-circulation cool vent mode are investigated using CFX 12.0. Thermal comfort represented by PMV(predicted mean vote) is evaluated using acquired numerical data. Temperature and velocity fields show that flow in passenger's compartment after soaking is considerably unstable at the view point of thermodynamics. Volume-averaged temperature is decreased exponentially during overall cool down process. However, temperature monitored at different 16 spots in CFX-Solver shows local variation in head, chest, knee, foot. The cooling speed at the head and chest nearby panel vent are relatively faster than at the knee and foot. Horizontal temperature contour shows asymmetric distribution because of the location of exhaust vent. By evaluating the passenger's thermal comfort, slowest cooling region is found at the driver's seat.

표면열처리용 변성가스의 위험성에 관한 연구 (A Study on the Hazard of Converted Gas for Surface Heating Treatment)

  • 최재욱;민철웅;임우섭;이병철;김동규
    • 한국가스학회지
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    • 제9권3호
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    • pp.9-14
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    • 2005
  • 변성가스의 폭발특성을 평가하기 위하여, 산소농도 변화와 수소의 첨가에 따른 변성가스 조성을 변화시켜 폭발거동에 대한 실험을 행하였다. 이러한 실험을 행한 결과 산소농도 $21\%$에서 변성가스와 수소의 농도가 증가할수록 폭발하한계는 낮아졌으며, 산소농도 $6\%$에서 폭발한계산소농도를 구하였다. 변성가스의 최대폭발압력은 $4.61 kg_f/cm^2$의 최적값을 얻었고, 이때 최대폭발압력상승속도는 변성가스 농도 $40\%$에서 $130.75 kg_f/cm^2/s$를 구하였다. 또한 폭발에 필요한 최소점화에너지는 변성가스 농도 $50\%$에서 0.13 mJ를 구하였다.

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곡률을 고려한 CFRP 복합재 적층쉘의 관통특성 -관통에 의한 파괴모드를 중심으로- (Penetration Characteristic of CFRP laminate shell by the curvature -A focus of fracture mode by the penetration-)

  • 조영재;김영남;심재기;양인영
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.1434-1439
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    • 2004
  • CFRP composite materials have wide application in structure materials of airplane, ships, and aero space vehicles because of their high strength and stiffness. This paper is to study the effects of curvature and orientation angle on the penetration characteristics of CFRP laminate shell. They are staked with 8 Ply specimens [0$_2$/90$_2$]$_{s}$, [0/90$_2$/0]$_{s}$ and the stacked of outer plates degree with 12 Ply specimens [0$_3$/90$_3$]$_{s}$, [0$_2$/90$_2$/0]$_{s}$ and [90$_3$/0$_3$], [90$_2$/0$_2$/90]S. They are manufactured to varied curvature radius (R=100,150,200mm and $\infty$). They are cured by heating to the appropriate harding temperature(13$0^{\circ}C$) by mean of a heater at the vaccum bag of the autoclave. Test specimens were prepared with dimensions 100mm$\times$140mm. When the specimen is subjected to transverse impact by a steel ball, the velocity of the steel ball was measured both before and after impact by determining the time for it to pass two ballistic-screen sensor located a known distance apart. In general, kinetic energy after impact-kinetic energy before impact rised in all specimens. This study observed a fracture mode inside the specimen after a penetration test using a digital camera and it examined a fracture mode and a penetration mode to stack of outer orientation angle and curvature.rvature.

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사염화탄소($CCl_4$) 소각을 위한 로타리 킬른 소각로 3차원 난류반응 컴퓨터 프로그램 개발( I ) (Development of a 3-Dimensional Turbulent Reaction Computer program for the Incineration of a Carbon Tetrachloride($CCl_4$) ( I ))

  • 엄태인;장동순
    • 한국안전학회지
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    • 제9권1호
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    • pp.100-109
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    • 1994
  • In this study, it is investigated that the possibility of the numerical simulation for the incineration of the hazardous material, crbon tetrachloride($CCl_4$). A 3-dimensional numerical technology is applied for turbulent reacting flows of the full-scale Dow Chemical incinerator. The calculations are made by a CRAY-2S, super computer. The major parameters considered in this study are kiln revolution rate (rpm), filling ratio of the solid waste(f), burner Injection velocity and angle, and turbulent air jets for swirl. And the employed turbulent reaction model is the eddy break-up model which is a kind of fast chemistry model assuming general equilibrium and used for a premixed flame. The calculated flow fields are presented and discussed. 1) The presence of turbulent air nozzles for swirl gives rise to visible increase of the convective motion over the region of the solid waste. This implies the possibility to enhance the mixing of the waste with the surrounding all and thereby to reduce thermal and species stratification, which were reported in a large rotary kiln operation. 2) Considering that the location of the recirculation region has a strong relation with the heating rate of the solid waste, the control of the recirculation region by the burner injection angle Is quite desirable in the sense of the flexible design of the rotary kiln incinerator for a carbon tetrachloride. 3) Finally, it is found that the eddy break-up model Is not suitable for carbon tetrachloride($CCl_4$) because this model is not incorporated the flame inhibition trend due to the presence $CCl_4$compound.

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중거리에서 대류경계층 연직방향 plume 확산의 일반화 (Generalization of Vertical Plume Despersion in the concective Boundary Layer at Long Distances on Mesoscale)

  • 서석진
    • 한국대기환경학회지
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    • 제16권2호
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    • pp.141-150
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    • 2000
  • In order to genralize the vertical dispersion of plume at long distances on mesoscale over complex terrain dispersion coefficients data have been obtained systematically according to lapsed time after release by using a composite turbulence water tank that simulates convective boundary layer. Dispersion experiments have been carried out for various combined conditions of thermal turbulence intensity mechanical turbulence intensity and plume release height at slightly to moderately unstable conditions. Results of tracer dispersion experiments conducted using water tank camera and image processing system have been converted into atmospheric dispersion data through the application of similarity law. The equation $\sigma$z/Zi=aX/(b+c X2)0.5 where $\sigma$2; vertical dispersion coefficient zi : mixing height X : dimen-sionaless downwind distance was confirmed to be an appropriate and general equation for expressing $\sigma$2 variation with turbulence intensity and plume release height, The value of "a" was found to be principally affected by mechanical turbulence intensity and that of "b" by mechanical turbulence intensity and release height. It was confirmed that the magnitude of "c" varies with release height. Results of water tank experiments on the relationship of $\sigma$2 vs downwind distance x have been compared with actual atmospheric dispersion data such as CONDORS data and Bowne's nomogram Operating conditions of a composite turbulence water tank for simulating the field turbulence situations of CONDORS experiments and Bowne's $\sigma$2(x) nomogram for suburban area have also been investigated in terms of water temperature difference between convection water tank and bottom plate heating tank grid plate stroke mixing water depth length scale and velocity scale. Moreover the effect of mechanical turbulence intensity on vertical dispersion has been discussed in the light of release height and downwind distance. height and downwind distance.

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A Study on Numerical Simulation of Gaseous Flow in SCR Catalytic Filter of Diesel Exhaust Gas Aftertreatment Device

  • Bae, Myung-Whan;Syaiful, Syaiful;Mochimaru, Yoshihiro
    • Journal of Advanced Marine Engineering and Technology
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    • 제34권3호
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    • pp.360-368
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    • 2010
  • A SCR catalytic filter system is used for reducing $NO_x$ and soot emissions simultaneously from diesel combustors. The amount of ammonia (as a reducing agent) must be controlled with the amount of $NO_x$ to obtain an optimal $NO_x$ conversion. Hence, gas mixing between ammonia and exhaust gases is vital to ensure that the SCR catalyst is optimally used. If ammonia mass distribution is not uniform, slip potential will occur in rich concentration areas. At lean areas, on the other hand, the catalyst is not fully active. The better mixing is indicated by the higher uniformity of ammonia mass distribution which is necessary to be considered in SCR catalytic filter system. The ammonia mass distributions are depended on the flow field of fluids. In this study, the velocity field of gaseous flow is investigated to characterize the transport of ammonia in SCR catalytic filter system. The influence of different injection placements on the ammonia mass distribution is also discussed. The results show that the ammonia mass distribution is more uniform for the injector directed radially perpendicular to the main flow of inlet at the gravitational direction than that at the side wall for both laminar (Re = 640) and turbulent flows (Re = 4255). It is also found that the mixing index decreases as increasing the heating temperature in the case of ammonia injected at the side wall.

HVAC 관련 매개변수 및 탑승조건에 따른 자동차 실내의 온열쾌적성 평가모델에 관한 수치해석적 연구 (A Numerical Study of Automotive Indoor Thermal Comfort Model According to Boarding Conditions and Parameters Related to HVAC)

  • 윤성현;박준용;손덕영;최윤호;박경석
    • 대한기계학회논문집A
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    • 제38권9호
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    • pp.979-988
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    • 2014
  • 자동차를 이용하는 시간이 늘어남에 따라 자동차 실내의 온열쾌적성에 대한 관심이 급증하고 있다. 그러나 아직까진 실제 자동차 중에서 공조시스템의 냉방성능은 자동차 제조사별로 온열쾌적성 지표를 통해 평가되지 않고, 실내의 공기 속도와 온도 등 열환경 기준에 의해 평가되고 있다. 또한 차 실내의 온열쾌적성을 수치해석으로 평가하는 경우 타당한 결과를 도출할 수 있는 수치기법에 대한 기준이 확립되지 않은 상황이다. 본 연구에서는 외부 열원을 모사하기 위하여 태양광선 추적모델을 사용하고, 공조시스템 작동 후 20 분까지 다양한 매개변수(공조시스템의 작동모드와 작동풍량, 인체모델 탑승조건)에 대한 자동차 실내의 온열쾌적성 평가를 수행하였다. 이를 통해 자동차 실내의 온열쾌적성 지표를 예측할 수 있는 평가모델을 도출하였다.