• Title/Summary/Keyword: Heat treatment process

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Effect of strontium ions on K2O-TiO2-SiO2 glass soaked in molten Sr(NO3)2 (Sr(NO3)2 용융염에서 이온교환이 K2O-TiO2-SiO2 glass에 미치는 영향)

  • Park, No-Hyung;Yoo, Eun-Sung;Lee, Hoi-Kwan;Huh, Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.5
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    • pp.214-217
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    • 2011
  • A fresnoite glass-ceramics has been investigating considerably because of the second order nonlinearity as well as its permanent optical nonlinearity. However, the chemical compositions of transparent glass-ceramics examined in the previous studies have been limited to adjust the composition close to fresnoite stoichiometrically. In this study, to investigate the effect of strontium ions in glass-ceramics on second order nonlinearity, $K_2O-TiO_2-SiO_2$ (KTS) glasses soaked in molten $Sr(NO_3)_2$ were prepared. Crystalline phases of the soaked glasses were measured by X-ray diffraction (XRD) as soaking times and additional heat treatment. The exchange of strontium ions into the glass was verified by Field Emission Scanning Electron Microscope (FE-SEM). And the phenomena of second order harmonic generation (SHG) was observed using Nd-YAG laser.

Bond Strength of SrZrO3 Coatings on Ag Sheathed Bi(2223) Mono-core Tape (은이 피복된 단심 Bi(2223) 초전도 선재에 대한 SrZrO3 코팅층의 접착강도 특성)

  • Lee, Se-Jong;Ye, Kyung-Hwan;Lee, Deuk-Yong;Song, Yo-Seung
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.1001-1006
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    • 2002
  • Bond strength of $SrZrO_3$ resistive oxide barrier on Ag sheathed Bi(2223) tapes prepared by the sol-gel and dip-coating method was evaluated with an aid of Taguchi method and $L_18(2^1{\times}3^7)$ orthogonal arrays to determine the optimal process combination of levels of factors that best satisfy the bigger is better quality characteristic. The observed optimal condition is as follows: Sr/Zr mol ratio(0.3/0.7), amount of organic vehicle(5 wt%), drying temperature and time(160${\circ}C$, 10 min), heat treatment temperature and time(500${\circ}C$, 20 min), respectively. ANOVA analysis suggested that the influence of the factors within ${\alpha}$=0.1 was significant with a 90% confidence level.

A Comparative Study on the Marginal Fit between Castable Ceramic(Dicor) Crowns and Metal-Ceramic Crowns (주조도재관과 도재전장주조관의 치경부 변연적합도에 관한 비교 연구)

  • Kim, Jeong-Ho;Yang, Jae-Ho;Lee, Sun-Hyung
    • The Journal of Korean Academy of Prosthodontics
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    • v.26 no.1
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    • pp.51-61
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    • 1988
  • The recently introduced castable glass ceramics incorporate properties characteristic of natural teeth and they are regarded as an ideal material to restore lost tooth structure. The purpose of this study was to compare the marginal fit of castable ceramic crown with that of the metal-ceramic crown in the process of heat treatment. Two master dies for castable ceramic crowns and metal-ceramic crowns were fabricated from being cast with the base metal. Each master die was duplicated with addition silicone and hard stone. Ten castable ceramic crowns were made on each hard stone die and their marginal openings were measured three times first, after casting; second, after ceramming; third, after shading. The other ten metal-ceramic crowns were made on each hard stone die and their marginal openings were measured three times : first, after casting; second, after degassing; third, after porcelain veneering. Each crown was seated on its master die with the constant force delivered by loading jig. And then, marginal openings were measured on four locations by optical projector at X50 magnification. The results were as follows: 1. The mean marginal openings of castable ceramic crowns were $31.1{\pm}12.7{\mu}m$ after casting; $44.6{\pm}12.8{\mu}m$ after ceramming; $51.2{\pm}16.8{\mu}m$ after shading. 2. The mean marginal openings of the metal-ceramic crowns were $26.2{\pm}13.8{\mu}m$ after casting; $29.8{\pm}10.3{\mu}m$ after degassing; $38.0{\pm}14.5{\mu}m$ after porcelain veneering. 3. There was significant increase in the marginal opening of castable ceramic crowns after ceramming, while metal-ceramic crowns sho(wed significant increase after porcelain veneering (p<0.05). 4. Marginal fit of metal-ceramic crown was better than that of castable ceramic crown (p<0.01).

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Separation of Phosvitin from Egg Yolk without Using Organic Solvents

  • Jung, Samooel;Ahn, Dong Uk;Nam, Ki Chang;Kim, Hyun Joo;Jo, Cheorun
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.11
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    • pp.1622-1629
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    • 2013
  • The objective of this study was to develop a new method to separate phosvitin from egg yolk without using organic solvents. Phosvitin was extracted from yolk granules using 10% NaCl or 10% $(NH_4)_2SO_4$ (final concentration) and then treated with heat to precipitate the lipoproteins from the extracted solution. The optimal pH for the phosvitin extraction from yolk granules was determined, and the iron-binding ability of the extracted phosvitin (final product) was tested. Adding 10% $(NH_4)_2SO_4$ disrupted the granules, and the subsequent thermal treatment at $90^{\circ}C$ for 1 h precipitated low density and high density lipoproteins, which enabled separation of phosvitin by centrifugation. The phosvitin concentration in the extract was significantly higher when the pH of the solution was adjusted to pH ${\geq}9$. The purity and recovery rate of phosvitin at the end of the separation process were approximately 78% and 56%, respectively. The separated phosvitin was confirmed to have ferrous and ferric iron binding ability. The advantages of this new method compared with the traditional methods include no organic solvents and high-priced equipment are needed for the separation. Also, this method is more environment and consumer friendly than that of the traditional methods.

Application of Pulsed Laser Deposition Method for ZnO Thin Film Growth and Optical Properties (ZnO 박막 성장과 광학적 특성 분석을 위한 펄스 레이저증착(PLD)방법 적용)

  • Hong Kwang Joon;Kim Jae Youl
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.2
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    • pp.33-41
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    • 2005
  • ZnO epilayer was synthesized by the pulsed laser deposition(PLD) process on Al$_2$O$_3$ subsorte after irradiating the surface of ZnO sintered pellet by ArF(193nm) excimer laser. The epilayers of ZnO were achieved on sapphire(A1203) substrate at the 境mperature of 400$^{circ}$C. The crystalline structure of epilayer was investigated by the Photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of ZnO epilayer measure with Hall effect by van der Pauw mothod are $8.27\times$1016cm$^{-3}$ and 299 cm$^{2}$/V$\cdot$s at 293 K respectively, The temperature dependence of the energy band gap of the ZnO obtained from the absorption spectra was well described by the Varshni's relation, E$_g$(T)= 3.3973 eV - ($2.69\times$ 10$^{-4}$ eV/K)T$^{2}$/(T + 463K). After the as-grown ZnO epilayer was annealed in Zn atmospheres, oxygen and vaccum the origin of point defects of ZnO atmospheres has been investigated by the photoluminescence(PL) at 10K. The native defects of V$_{Zn}$, V$_{O}$, Zn$_{int}$, and O$_{int}$ obtained by PL measurements were classified as a donor or acceptor type. In addition we concluded that the heat-treatment in the oxygen atmosphere converted ZnO thin films to an optical p-type. Also, we confirmed that vacuum in ZnO/Al$_2$O$_3$ did not firm the native defects because vacuum in ZnO thin films existed in the form of stable bonds.

Effects of Post-Harvest Bulk Management System Using Rice Processing Complex on Labor Saving and Quality of Barley (보리 산물처리에 의한 품질변화와 생력효과)

  • 이춘우;윤의병;구본철;백성범;손영구;서세정;남중현;김완석
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.6
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    • pp.475-478
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    • 2002
  • Post-harvest treatment for barley production requires many steps including drying, cleaning, and packing, and these steps be needed many labor input. Rice processing complex (RPC) is useful for post harvest management system in rice production. However, it is rare to be used for barley production. This study was conducted to explore the variations of quality and labor saving between conventional method and bulk-management system in post-harvest using RPC. The sorting rate was not different between manual method and bulk management. The hardness of non-polished grain was ranged 10,175-10,329 g/$3.14mm^2$, and that for non-polished grain was higher than that for polished grain, but there was not different between drying method. There was not be showed the hunter's value such as L, a and b according to drying method. Cooking characters such as water absorption ratio, swelling ratio, and water soluble extracts by circulated or continued dryer was higher than manual drying using solar heat. Labor input per ha for each cultivation process in bulk-management of barley using rice processing complex was 21 hours, compared to 46 hr/ha in the conventional method, labor input was greatly saved by up to 54.3% in the post-harvest bulk management system.

Development of Hi-Quality Bedding Items by Multi-Finishing System of Pile Knitted Fabrics - Physical Properties of Textile according to Yarn Types - (파일 니트의 복합 후가공 기술에 의한 고품위 침장제품 개발에 관한 연구 - 원사 종류에 따른 원단의 물리적 특성 고찰을 중심으로 -)

  • Son, Eun Jong;Hwang, Young Gu;Park, Shin Woong;Choi, Yun Seon;Jeong, Sung Hoon
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.231-238
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    • 2017
  • There are many kinds of elements and processes for the development of high quality bedding products like fiber, high-temperature heat treatment, dyeing process, tenter drying with softening agent and multiple final finishing. Especially we examined the mechanical characteristic properties of fabrics according to different yarn types. The critical physical properties of the yarn consisting the pile knitted fabrics were obtained for the development of the hi-grade bedding items. The material property and the exhaustion behaviour of the developed pile knitted fabrics composing of different yarns were measured and observed. The physical properties of the developed fabric were evaluated through the material property analysis of the yarn, the physical nature of the pile knitted fabrics and the data of the exhaustion performance; tensile strength, tensile elongation, tearing strength, cross section of yarn types, dyeing properties etc. And then high-class of bedding items were knitted using the double raschel machine to make the pile knitted fabrics.

Effect of Crystal Orientation on Material Removal Characteristics in Sapphire Chemical Mechanical Polishing (사파이어 화학기계적 연마에서 결정 방향이 재료제거 특성에 미치는 영향)

  • Lee, Sangjin;Lee, Sangjik;Kim, Hyoungjae;Park, Chuljin;Sohn, Keunyong
    • Tribology and Lubricants
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    • v.33 no.3
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    • pp.106-111
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    • 2017
  • Sapphire is an anisotropic material with excellent physical and chemical properties and is used as a substrate material in various fields such as LED (light emitting diode), power semiconductor, superconductor, sensor, and optical devices. Sapphire is processed into the final substrate through multi-wire saw, double-side lapping, heat treatment, diamond mechanical polishing, and chemical mechanical polishing. Among these, chemical mechanical polishing is the key process that determines the final surface quality of the substrate. Recent studies have reported that the material removal characteristics during chemical mechanical polishing changes according to the crystal orientations, however, detailed analysis of this phenomenon has not reported. In this work, we carried out chemical mechanical polishing of C(0001), R($1{\bar{1}}02$), and A($11{\bar{2}}0$) substrates with different sapphire crystal planes, and analyzed the effect of crystal orientation on the material removal characteristics and their correlations. We measured the material removal rate and frictional force to determine the material removal phenomenon, and performed nano-indentation to evaluate the material characteristics before and after the reaction. Our findings show that the material removal rate and frictional force depend on the crystal orientation, and the chemical reaction between the sapphire substrate and the slurry accelerates the material removal rate during chemical mechanical polishing.

A Study for Joining of Silicon Nitride with Crystallized Glass Solder of $SiO_2-Al_2O_3-MgO$ System ($SiO_2-Al_2O_3-MgO$계 결정화 유리 솔더에 의한 질화규소의 접합에 관한 연구)

  • 안병국
    • Journal of Welding and Joining
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    • v.21 no.1
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    • pp.107-113
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    • 2003
  • Joining of $Si_3N_4$ to $Si_3N_4$ with crystallized glass solder was studied. $SiO_2-Al_2O_3-MgO$ glass with $P_2O_5$ as a crystallizing reagent was used as a solder. To improve the hish temperature toughness of joined specimen, two stage heat treatment was applied to Joined sample for the crystallization of joined layer, Two factors, i.e. thickness of soldered layer and crystallization were taken and thier effects on joining strength were investigated by a SEM-EDX observation of joined interface and bending strength both at room and elevated temperatures. Obtained results are summarized as follows: (1) Nitrogen diffused from $Si_3N_4$ to solder during the Joining process. Average amount of nitrogen in soldered layer depended on the thickness of the soldered layer and increased with decrease of the thickness. (2) Joining strength of the specimen having a thinner soldered layer was stronger than that of thicker layer. This can be mainly attributed to the difference of the nitrogen content in the soldered layer. (3) Higher content of nitrogen in solder brought forth higher viscosity of the solder. Hence the crystallization of the solder become more difficult in thinner layer of the solder than thicker one. (4) Thus, the effect of crystallization was evaluated mostly by the thicker layer specimen. Crystallization of soldered layer improved markedly the fracure strength of joining at higher temperatures than the softening temperature of glass solder.

Ginsenoside (20S)Rg3 Ameliorates Synaptic and Memory Deficits in an Animal Model of Alzheimer's Disease

  • Kim, Tae-Wan
    • 한국약용작물학회:학술대회논문집
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    • 2011.09a
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    • pp.31-45
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    • 2011
  • The amyloid ${\beta}$-peptide ($A{\beta}$), which originates from the proteolytic cleavage of amyloid precursor protein (APP), plays a central role in the pathogenesis of Alzheimer's disease (AD). Mounting evidence indicates that different species of $A{\beta}$, such as $A{\beta}$ oligomers and fibrils, may contribute to AD pathogenesis via distinct mechanisms at different stages of the disease. Importantly, elevation and accumulation of soluble $A{\beta}$ oligomers closely correlate with cognitive decline and/or disease progression in animal models of AD. In agreement with these studies, oligomers of $A{\beta}$ have been shown to directly affect synaptic plasticity, a neuronal process that is known to be essential for memory formation. Our previous studies showed that $A{\beta}$ induces the breakdown of phosphatidylinositol 4,5-bisphosphate (PI(4,5)P2), a phospholipid that regulates key aspects of neuronal function. PI(4,5)P2 breakdown was found to be a key step toward synaptic and memory dysfunction in a mouse model of AD. To this end, we seek to identify small molecules that could elevate the levels of PI(4,5)P2 and subsequently block $A{\beta}$ oligomer-induced breakdown of PI(4,5)P2 and synaptic dysfunction.. We found that (20S)Rg3, an active triterpene glycoside from heat-processed ginseng, serves as an agonist for phosphatidylinositol 4-kinase IIalpha (PI4KIIalpha), which is a lipid kinase that mediates a rate-limiting step in PI(4,5)P2 synthesis. Consequently, (20S)Rg3 stimulates PI(4,5)P2 synthesis by directly stimulating the activity of PI4KIIalpha. Interestingly, treatment of a mouse model of AD with (20S)Rg3 leads to reversal of memory deficits. Our data suggest that the PI(4,5)P2-promoting effects of (20S)Rg3 may help mitigate the cognitive symptoms associated with AD.

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