• Title/Summary/Keyword: Heat transportation

검색결과 319건 처리시간 0.035초

이미다졸계 이온성 액체의 물성 (Physical and Thermodynamic Properties of Imidazolium Ionic Liquids)

  • 오수연;강정원;박병흥;김기섭
    • Korean Chemical Engineering Research
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    • 제50권4호
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    • pp.708-712
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    • 2012
  • 이온성 액체는 일반적으로 거대 헤테로 고리 양이온과 무기 음이온으로 이루어진 염으로, 상온에서 액체로 존재한다. 따라서 이온성 액체의 물성은 양이온과 음이온의 종류, 알킬기의 수에 영향을 받으므로 그 조합에 의해 이온성 액체 각각의 물성이 달라진다. 또한 비휘발성, 열적 안정성, 넓은 전기 화학적 범위를 가지므로 기존의 유기용매를 대체할 주목할 만한 청정 용매(Green solvent)이다. 본 연구에서는 1-Butyl-3-methylimidazolium bromide ([BMIM][Br]), 1-butyl-3-methylimidazolium Chloride ([BMIM][Cl]), 1-butyl-3-methylimidazolium iodide ([BMIM][I]) 그리고 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][$BF_4$])을 합성하였으며, 그 중 [BMIM][Br], [BMIM][I], [BMIM][$BF_4$]의 밀도, 점도, 굴절률, 열용량과 이온전도도를 293.2~323.2 K의 온도범위에서 측정하였다. 밀도와 굴절률은 [BMIM][I]가 세 이온성 액체 중 가장 높았으며, 점성은 [BMIM][Br]가 가장 높았다. 열용량은 [BMIM][Br]보다 [BMIM][$BF_4$]가 높았으며, 이온 전도도는 [BMIM][I]보다 [BMIM][$BF_4$]가 더 높았다.

다양한 ECA 소재를 활용한 shingled 구조의 태양전지 효율 비교 분석 (A Comparison Analysis on the Efficiency of Solar Cells of Shingled Structure with Various ECA Materials)

  • 장재준;박정은;김동식;최원석;임동건
    • 한국태양에너지학회 논문집
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    • 제39권4호
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    • pp.1-9
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    • 2019
  • Modules using 6 inch cells have problems with loss due to empty space between cells. To solve this problem made by shingled structure which can generate more power by utilizing empty space by increasing the voltage level than modules made in 6inch cell. Thus, in this paper, the c-Si cutting cells were produced using nanosecond green laser, and then the ECA was sprayed and cured to perform cutting cell bonding. Three types of ECA materials (B1, B2, B3) with Ag as the main component were used, and experimental conditions varied from 5 to 120 seconds of curing time, 130 to $210^{\circ}C$ of curing temperature, and 1 to 3 of curing numbers. As a results of experiments varying curing time, B1 showed efficiency 19.88% in condition of 60 seconds, B2 showed efficiency 20.15% in 90 seconds, and B3 showed efficiency 20.27% in 60 seconds. In addition, experiments with varying curing temperature, It was confirmed highest efficiency that 20.04% in condition of $170^{\circ}C$ with B1, 20.15% in condition of $150^{\circ}C$ with B2, 20.27% in condition of $150^{\circ}C$ with B3. These are because the Ag particles are densely formed on the surface to make the conduction path. After optimizing the conditions of temperature and curing time, the secondary-tertiary curing experiments were carried out. as the structural analysis, conditions of secondary-tertiary curing showed cracks that due to damp heat aging. As a result, it was found that the ECA B3 had the highest efficiency of 20.27% in condition of 60 seconds of curing time, $150^{\circ}C$ of curing temperature, and single number of curing, and that it was suitable for the manufacture of Solar cell of shingled structure rather than ECA B1 and B2 materials.

철도 도상자갈치기 발생토사의 재활용에 관한 연구 (A Study on Recycle of Excavated Soil from Ballast Cleaning)

  • 김영철;김연신;김경수;정찬일;이의학
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2011년도 춘계학술대회 논문집
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    • pp.1757-1763
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    • 2011
  • In recent years, accordance to industrial development project on railway investment, adverse environmental issues of the investment, such as disputed cases about recycling and usage of Ballast Cleaner excavated soil, have been continuously increasing. It will not only enhance the regulation of soil contamination but take considerable time and cost in future. In this study, we investigated soil contamination and burnability with soil of Chungang Line, Taebaek Line, Chungbuk Line, in order to seize a possibility of recycling Ballast Cleaner excavated soil for the natural materials and substantial heat sources, which are necessary resources for cement manufacturing process. As a result of this study, It is found that Ballast Cleaner excavated soil is satisfied with a standard. The excavated soil contains a lot of cement ingredients and fossil fuel dust incurred from freight transportation, so it is expected to use for ingredients of cement and replacement of heat sources.

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열전도성 실리콘 고무의 전압-전류 특성 (Properties of Current due to Voltage in Heat Conductive Silicone Rubber)

  • 이성일
    • 한국전기전자재료학회논문지
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    • 제27권9호
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    • pp.576-581
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    • 2014
  • This study used the heat conductive silicone rubber sample of 0.95 mm thickness to research the properties of current by changing voltage. When the 1, 10, 30, 60, and 90 minute have passed, the running current has been measured through the applied voltage range of 200 V~800 V on setting temperature of $110^{\circ}C{\sim}170^{\circ}C$. As the temperature increased in applied voltage of 800 V, so did the current value according to time in proportion to the increasing temperature. In an analysis of FT-IR (fourier transform infrared) spectrum, the hydroxyl radicals group(O-H) was created by effects of the hydrogen that methyl group is eliminated by addition of the cross-linking agent peroxide.

A Thermal Conductivity Model for Hydrating Concrete Pavements

  • 정진훈;김낙석
    • 콘크리트학회논문집
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    • 제16권1호
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    • pp.125-129
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    • 2004
  • Hydrating concrete pavement is typically subjected to temperature-induced stresses that drive cracking mechanisms at early concrete ages. Undesired cracking plays a key role in the long-term performance of concrete pavement systems. The loss of support beneath the concrete pavement due to curling caused by temperature changes in the pavement may induce several significant distresses such as punch out pumping, and erosion. The effect of temperature on these distress mechanisms is both significant and intricate. Because thermal conductivity dominates temperature flow in hydrating concrete over time, this material property is back-calculated by transforming governing equation of heat transfer and test data measured in laboratory. Theoretically, the back- calculated thermal conductivity simulates the heat movements in concrete very accurately. Therefore, the back- calculated thermal conductivity can be used to calibrate concrete temperature predicted by models.

판형 흡착열교환기를 사용한 폴리머-물 흡착식 냉동기의 성능예측 (Simulation of a Polymer-Water Adsorption Refrigerator using Plate-Type Adsorption Heat Exchangers)

  • 김동선;이대영
    • 설비공학논문집
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    • 제27권2호
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    • pp.94-102
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    • 2015
  • A hydroscopic polymer is used as the adsorbent in an adsorption refrigeration system. A pair of plate-type heat exchangers, thinly coated with the polymer, is simulated using a two-dimensional transient model to predict performance of the system. It is predicted that the system would yield 0.57 kW SCP and 0.47 COP at $80^{\circ}C$ heating and $30^{\circ}C$ cooling temperatures. In comparison with a conventional silica gel-water system, the COP is comparable but SCP is about three times larger. The slow mass diffusion rate of the polymer should be improved for better performance.

Brake Lining Can be Applied to Super High Speed Vehicle

  • Nakano, Satoru;Maejima, Takashi
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1305-1306
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    • 2006
  • A new material was developed to achieve improvement of heat durability, improvement of wear resistance, stability of friction coefficient and reduction in aggression to counterpart, because it is difficult to maintain braking properties by using currently available materials in the train wagons used for high-speed transportation. As a result, the new material showed a stable wear resistance even in the speed range of 350km/h, where improvement was also confirmed in reduction of aggression to counterpart material by more than approximately 10%. This development was adopted for the brake lining in the Taiwan High Speed Rail project.

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인산계 무기염을 이용한 콘크리트의 수화 발열 특성에 관한 실험적 연구 (An Experimental Study on the Hydration Heat of Concrete Using Phosphate based Inorganic Salt)

  • 정석만;김세환;양완희;김영선;기전도;이건철
    • 한국건축시공학회지
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    • 제20권6호
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    • pp.489-495
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    • 2020
  • 콘크리트 구조물의 대형화에 따라 매스 콘크리트의 수화열 제어에 대한 중요성이 커지는 반면, 기존의 관련 대책들은 효용성이나 실용성 측면에서 한계를 보이는 경우가 많다. 따라서 이 연구에서는 재료적인 대책으로 매스 콘크리트의 수화열을 제어하기 위해 시멘트의 경화를 제어하는 방향으로 수화열을 저감할 수 있는 방안을 검토하였다. 본 연구에서는 해외 연구사례를 참고하여 인산염계 지연제와 무기질 수화 제어물질이 결합 된 인산계 무기염 수화열 저감제를 사용하였으며, 이에 따라 인산계 무기염의 수화열 저감 효과는 단열박스에 페이스트와 콘크리트를 적용하여 검증하였다. 즉, 저발열을 위해 통상적으로 사용되는 2성분계 및 3성분계 배합에 있어서 인산계 무기염의 혼입 여부에 따른 수화열, 플로 또는 슬럼프, 압축강도 등을 비교하였다. 실험결과 페이스트와 콘크리트의 압축강도 성능에 있어서 인산계 무기염의 혼입 배합은 일반 배합과 동등 또는 그 이상의 성능을 나타내었다. 특히, 콘크리트 배합에서 인산계 무기염에 의해 초기 재령 강도가 저하되었던 부분이 알칼리 황산염에 의해 빠르게 회복되었고, 인산계 무기염의 혼입 배합의 강도는 미 혼입 배합과 비교할 때 7일은 유사, 28일은 더 크게 측정되었다. 수화열에 의한 내부 최대 온도상승량의 경우 인산염계 무기 지연제 혼입 시 페이스트에서는 9.5~10.6%, 콘크리트에서는 10.1~11.7%의 저감 효과를 나타내었다. 또한 실 구조물 내부의 수화열 발산에 유리한 최고온도 발생 시점의 지연 효과도 뚜렷이 나타났다. 따라서 본 연구에서 사용된 인산계 무기염은 시멘트 페이스트와 콘크리트의 수화열 저감에 상당 부분 기여 하는 것으로 확인되며, 앞으로 서중 콘크리트 혹은 고온다습한 동남아시아 등의 공사현장에서 매스 콘크리트 수화열 저감의 목적으로 활용이 가능할 것으로 판단된다. 따라서 본 연구와 같은 다양한 콘크리트의 수화열 저감과 관련된 연구가 필요하다고 사료된다.

RF 마그네트론 스퍼터링에 의해 합성된 Nb-doped TiO2 투명전극의 특성 (Properties of Nb-doped TiO2 Transparent Conducting Oxide Film Fabricated by RF Magnetron Sputtering)

  • 김민영;조문성;임동건;박재환
    • 한국전기전자재료학회논문지
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    • 제25권3호
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    • pp.204-208
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    • 2012
  • $TiO_2$ ($Ti_{1-x}Nb_xO_2$, x= 0.04~0.06) transparent conducting oxide film was fabricated by RF magnetron sputtering process and their electrical, optical, stability properties were studied. When the Nb 4 at% sputtering target was used with RF power 120 W, pressure 8 mTorr, post-annealing temperature $600^{\circ}C$, the resistivity of TNO film was $4{\times}10^{-4}\;{\Omega}-cm$. The optical transmittance in the visible wavelength was ca. 86%. TNO films require heat treatment during or after the deposition process. When the film was deposited at room temperature and post-annealed at $600^{\circ}C$, the lowest resistivity was obtained. When the TNO film was exposed to high temperature and humidity, the resistivity of the film was rather decreased. The stability to temperature and humidity implies that the TNO film could be a appropriate candidate for In-free, ZnO-free transparent conducting oxide materials.