• Title/Summary/Keyword: Heat stability

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Evaluation of the Cytotoxicity and Mechanical Strength of Dental Duplex Stainless Steel Orthodontic Wire (치과 교정용 듀플렉스 스테인리스 스틸 와이어의 기계적 강도 및 세포독성 평가)

  • Lee, Myung-Kon;Kim, Chi-Young
    • The Journal of the Korea Contents Association
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    • v.10 no.9
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    • pp.309-317
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    • 2010
  • The stainless steel wire is extensively used for the orthodontic treatment. But, the stainless steel wire that has commonly superior corrosion resistance has caused hypersensitive reaction or allergy as side effects because of corrosion in the oral environment. For improving the problem of corrosion, we was evaluated the suitability of the duplex stainless steel(DSS) as orthodontic wire through this study. The DSS wire was evaluated the mechanical strength and bio-stability for suitability and bio-compatibility as orthodontic wire. In this work, the DSS and stainless steel(SS) as common use of medical grade were prepared for the tensile strength test. The DSS wire were treated by heat. and Temperature conditions of the heat treatment were $28^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$, $700^{\circ}C$, $800^{\circ}C$, $900^{\circ}C$, respectively. And the DSS wires that treated by heat on the optimum temperature condition were conducted the bending moment test and calculated the S-Max value and the modulus of elasticity. For evaluating the bio stability, each materials were conducted in vitro test for measuring the cell survival rate. The most interesting results was that the tensile strength test of SS wire($8.17\times10^4\;N/mm^2$) and DSS wire($8.05\times10^4\;N/mm^2$) that treated at $500^{\circ}C$ by heat were similar in mechanical strength. In the bio-stability study, the DSS has no cytotoxicity (p=0.05) Thus, we could make a conclusion that the duplex stainless steel wire has vastly superior corrosion resistance was suitable as orthodontic wire.

A Study on the Risk of Spontaneous ignition to Butadiene Popcorn Polymer (Butadiene Popcorn Polymer의 자연발화 위험성에 관한 연구)

  • Koo, Chae-Chil;Lee, Jung-Suk;Choi, Jae-Wook
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.1-8
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    • 2019
  • This study was conducted to investigate the possibility of spontaneous ignition in Butadiene popcorn polymer, which is used as raw material and product in a chemical plant. A component analysis, thermogravimetric analysis, thermal stability analysis, spontaneous ignition point measurement and accelerated velocity calorimetric analysis were performed. As a result of analysis, various kinds of flammable components were measured and thermogravimetric analysis showed a weight loss of 95.6% in air and 89.2% in nitrogen. As a result of the thermal stability analysis, heat generation started at $88^{\circ}C$ in the air atmosphere, and the heat generation rate increased sharply in the vicinity of the natural ignition point ($220^{\circ}C$). The heat generation started at about $70^{\circ}C$ in nitrogen atmosphere, and the two exothermic peak values were observed up to $450^{\circ}C$. As a result of accelerated rate calorimetry, there was no exothermic phenomenon, and the lowest ignition temperature was $211.7^{\circ}C$ as a result of analysis of natural ignition point. Based on the results obtained from the thermal stability evaluation, it is considered that the possibility of inducing the thermal deformation of the column by the heat of reaction is sufficient.

Changes in chemical stability and biological activities of sinapinic acid by heat treatment under different pH conditions (다양한 pH조건에서 가열처리에 의한 시나핀산의 화학 안정성 및 생리활성 변화)

  • Heo, Yunseon;Hong, Jungil
    • Korean Journal of Food Science and Technology
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    • v.52 no.6
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    • pp.616-621
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    • 2020
  • Sinapinic acid is a widely-distributed phenolic acid in various edible plants. In this study, changes in chemical stability and biological activities of sinapinic acid by heat treatment were evaluated at different pH values. The decomposition of sinapinic acid with heating at 95℃ was accelerated at higher pH; the residual levels after 10 min of heating were 80, 45 and 24% at pH 6, 7 and 8, respectively. Levels of reactive oxygen species derived from sinapinic acid also increased after heating at pH 7 and 8. ABTS radical scavenging activities and ferric reducing antioxidant power of sinapinic acid were reduced significantly after heating at pH 7 and 8. The cytotoxic activity of sinapinic acid against HCT116 cells was significantly enhanced after heating at pH 8 with decreased glutathione levels. The results suggest that heat treatment causes changes in the chemical stability and biological activities of sinapinic acid, and such changes are more prominent at higher pH.

Construction of the Heat Pump System Using Thermal Effluents for Greenhouse Facilities in Jeju and Evaluation of Cooling Performance (제주 시설온실 냉난방을 위한 발전소 온배수 활용 열펌프 시스템 구축 및 냉방성능 평가)

  • Lee, Yeon-Gun;Heo, Jaehyeok;Lee, Dong-Won;Hyun, Myung-Taek
    • Journal of Energy Engineering
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    • v.27 no.4
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    • pp.70-79
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    • 2018
  • A heat pump system using the thermal effluent from the Jeju thermal power plant of KOMIPO was constructed with the capacity of 300 RT to supply cool or hot water to greenhouse facilities located 3 km from the power station. The way of transporting heat from the thermal effluent to greenhouses at a long distance was optimized, and a monitoring system to measure the water temperature and detect a leakage in a pipe conduit was also installed. This paper presents the system configuration of the constructed heat pump system for air conditioning and heating of greenhouse facilities in Jeju, and the characteristics of major components deployed in the system. The preoperational tests of the heat pump system were conducted during the summer season in 2018 for evaluation of its cooling performance. The operational stability and cooling performance of the heat pump system were confirmed by investigating the measured fluid temperature and flow rate, and COP of the heat pump in a cooling mode.

Improvement in the Dispersion Stability of Iron Oxide (Magnetite, Fe3O4) Particles with Polymer Dispersant Inject (고분자 분산제 주입을 통한 철산화물(Magnetite, Fe3O4) 입자의 분산 안정성 향상)

  • Song, Geun Dong;Kim, Mun Hwan;Lee, Yong Taek;Maeng, Wan Young
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.656-662
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    • 2013
  • The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.

Thermal Stability of Grubbs' Catalyst and Its Reactivity with Self-healing Agents (Grubbs' Catalyst의 열안정성 및 자가치료제와의 반응성 평가)

  • Yoon, Sung Ho;Shi, Ya Long;Feng, Jun;Jang, Se Yong
    • Composites Research
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    • v.28 no.6
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    • pp.395-401
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    • 2015
  • This study investigated the thermal stability of Grubbs' catalyst and its reactivity with self-healing agents for self-healing damage repair. Four types of Grubbs' catalyst supplied by manufacturers were considered and each catalyst was tested in as-received and grinded conditions. Four types of self-healing agents were prepared by varying the mixing ratio of dicyclopentadiene (DCPD) and 5-ethylidene-2-norbonene (ENB). Heat flows as a function of temperature were measured through a differential scanning calorimetry (DSC) to determine the thermal stability of catalysts. Reaction heats of self-healing agents with the catalyst were measured to evaluate the reactivity of the catalyst. For this evaluation, Fluka Chemika Grubbs' catalyst was used based on the maximum temperature and the time to reach the maximum temperature. According to the results, catalysts had different shapes depending on the manufacturer and the results showed that the smaller the size of the catalyst the higher the reactivity with self-healing agents. As the ENB ratio in self-healing agents increased, the maximum temperature increased, and the time to reach the maximum temperature decreased. As the amount of the catalyst increased, the maximum temperature increased, and the time to reach the maximum temperature decreased. Considering the thermal stability of the catalyst and its reactivity with the self-healing agent, combination of 0.5 wt% catalyst and the D3E1 self-healing agent was optimal for self-healing damage repair. Finally, as the thermal decomposition may occur depending on the environmental temperature, the catalyst must not be exposed to temperature higher than that is necessary to maintain the thermal stability of the catalyst.

Improvement in Storage Stability of Danmooji (Salted Radish) by High Hydrostatic Pressure and Heat Treatment (초고압과 열처리를 통한 단무지의 저장성 향상)

  • Kim, Byong-Ki;Hong, Kwan-Pyo;Park, Ji-Yong
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.132-138
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    • 1998
  • This study was conducted to evaluate the storage stability of danmooji(salted radish) treated with high hydrostatic pressure $(300{\sim}686\;MPa)\;and\;heat\;(55^{\circ}C)$. Danmooji pressurized at 500 MPa and 686 MPa for 5 min showed $4{\sim}6log-cycle$ reductions in total microorganism, while danmooji heated at $55^{\circ}C\;for\;2\;hr\;showed\;3{\sim}5log-cycle$ reductions. However, danmooji pressurized at 300 MPa for 5 min showed a 2 log-cycle reduction, indicating that pressurization at lower than 300 MPa is insufficient for sterilization. After pressurized at 300 MPa, 500 MPa and 686 MPa for 5 min, pectinesterase (PE) activity of danmooji was increased by approximately 35%, 76% and 64%, respectively; and polygalacturonase (PG) activity of danmooji was increased by 109%. 163% and 120%, respectively. After heated at $55^{\circ}C$ for 2 hr, PE and PG activities of danmooji were increased by 18% and 200%, respectively. This indicates that PE in danmooji was more activated bypressure than heat, while PG was mostly activated by heat. Pressurized and heat-treated danmooji had higher hardness than control and maintained its hardness during storage at $30^{\circ}C$.

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Stability of antibody during heat treatment and storage in immunized milk with Helicobacter pylori antigen (Helicobacter pylori 항원을 이용한 면역우유의 열처리와 저장 중 항체의 안전성)

  • Jeong Eun-Ju;Park La-Young;Bae Man-Jong;Lee Shin-Ho
    • Food Science and Preservation
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    • v.13 no.2
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    • pp.223-227
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    • 2006
  • Optimal heat treatment conditions for maintaining the immune-activity of immunized milk with Helicobacter pylori antigen were studied Total bacterial count of immunized milk with H. pylori antigen decreased according to the increasing heating temperature and time. The viable tell number of immunized milk was $10^3\;CFU/mL$ after heat treatment for 30 min at $60^{\circ}C$, and coliform bacteria did not appear in immunized milk after heat treatment Immune-activity measured in terms of IgG concentration was maintained up to 99.99% after heat treatment for 30min at $60^{\circ}C$, but decreased rapidly below 50% after heat treatment above $70^{\circ}C$. The quality characteristics of immunized milk were examined during storage at $2^{\circ}C,\;4^{\circ}C\;and\;10^{\circ}C$. The pH, titratable acidity and total bacterial count were not changed significantly during 21 day storage at $2^{\circ}C\;and\;4^{\circ}C$, but rapidly changed after 7 day storage at $10^{\circ}C$. The immune-activity was kept well for 14 day storage at $2^{\circ}C,\;4^{\circ}C\;and\;10^{\circ}C$ but decreased rapidly after 14 days at every temperatures tested.

Heat-Induced Reaction of Bovine Whey Proteins (열처리로 야기되는 우유 유청 단백질의 반응)

  • 이유라;홍윤호
    • Food Science of Animal Resources
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    • v.22 no.2
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    • pp.179-182
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    • 2002
  • Using differential scanning calorimetry (DSC), changes underwent by a mixture of $\alpha$-lactalbumin ($\alpha$-La) and $\beta$-lactoglobulin ($\beta$-Lg) during heat treatment were studied, yielding useful information for the dairy industry. Results of the DSC showed that the heat denaturation temperature of the hobo-$\alpha$-La was higher than that of apo-$\alpha$-La, suggesting hole-$\alpha$-La‘s greater stability. The denaturation temperature of a mixture of holo-$\alpha$-La and $\beta$-Lg was also slightly lower than that of holo-$\alpha$-La alone. The denaturation temperature of an apo-$\alpha$-La and $\beta$-Lg mixture was higher than that of holo-$\alpha$-La and $\beta$-Lg, suggesting that the heat stability of apo-$\alpha$-La was increased by $\beta$-Lg. Based on these results, it is possible to conclude that a mixture of holo-$\alpha$-La and $\beta$-Lg is more intensively affected by an increase in temperature than other samples, and that free sulphydryl groups seem to take part in this heat-induced denaturation.

A study of flow oscillations in a upright heated pipe (직립전열관에서의 유체진동에 관한 연구)

  • 박진길;진강규;오세준
    • Journal of Advanced Marine Engineering and Technology
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    • v.8 no.1
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    • pp.85-99
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    • 1984
  • The stability of the two-phase flow in a heated channel is of great importance in the design and operation of the boilers and light water nuclear reactors, because it can cause flow oscillations and lead to a violation of thermal limits with resultant overheating of the channels and cladding. This paper presents a systematic evaluation to the variation effects of the basic four (4) dimensionless parameters in a homogeneous equilibrium model. The flow stability is examined on the ground of static characteristic curves. The complicated transfer function of flow dynamics which gives consideration to the transport lag of density wave is derived, and the transient flow stability is analysed by applying the Nyquist stability criterion in control engineering. The analysis results summed up as follows 1. The coolant flow becomes stable in large friction number and specific flow, while it is unstabale in small friction number and flow. 2. Large phase-change number and Froude number destabilize the two-phase flow, but small numbers stabilize it. The effect to variation of phase-change number is more dominant compared with Froude number. 3. The dynamic analysis is required to hold the sufficient safety of heated channels since only static results does not keep it. The special attention could be payed in the design and operation of heat engines, because the unstaable region exists within the stable boundary at small and middle phase-change number and Froude number.

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