• Journal of Welding and Joining
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• 제21권1호
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• pp.107-113
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• 2003

Joining of $Si_3N_4$ to $Si_3N_4$ with crystallized glass solder was studied. $SiO_2-Al_2O_3-MgO$ glass with $P_2O_5$ as a crystallizing reagent was used as a solder. To improve the hish temperature toughness of joined specimen, two stage heat treatment was applied to Joined sample for the crystallization of joined layer, Two factors, i.e. thickness of soldered layer and crystallization were taken and thier effects on joining strength were investigated by a SEM-EDX observation of joined interface and bending strength both at room and elevated temperatures. Obtained results are summarized as follows: (1) Nitrogen diffused from $Si_3N_4$ to solder during the Joining process. Average amount of nitrogen in soldered layer depended on the thickness of the soldered layer and increased with decrease of the thickness. (2) Joining strength of the specimen having a thinner soldered layer was stronger than that of thicker layer. This can be mainly attributed to the difference of the nitrogen content in the soldered layer. (3) Higher content of nitrogen in solder brought forth higher viscosity of the solder. Hence the crystallization of the solder become more difficult in thinner layer of the solder than thicker one. (4) Thus, the effect of crystallization was evaluated mostly by the thicker layer specimen. Crystallization of soldered layer improved markedly the fracure strength of joining at higher temperatures than the softening temperature of glass solder.

• Journal of Welding and Joining
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• 제16권6호
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• pp.35-43
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• 1998

In this paper, the fracture toughness evaluation of the various microstructures such as HAZ, F.L and W.M in weldment of TMCP steel which has the softening zone owing to high heat input welding was carried out by using of the small punch(SP) test. In addition, the fracture toughness with the specimen orientation of rolled TMCP steel was investigated by means of SP test and the crack opening displacement (COD) test and then was compared with that of conventional SM50YB steel. From the results of SP test for TMCP steel, it could be seen that the SP energy transition curves of three different orientation were shifted to higher temperature side in order of S, T and L. But the {TEX}$DBTT_{SP}${/TEX} of each orientation specimen did not show a lot of differences and were quite lower than those of conventional SM50YB steel. The mechanical properties of HAZ structure in weldment of TMCP steel such as hardness, SP energy at room temperature and -196$^{\circ}C$ and the upper shelf energy of SP energy transition curve were lower than those of base metal due to softening. The {TEX}$DBTT_{SP}${/TEX} of each microstructure in weldment of TMCP steel increased in order of HAZ, F.L and W.M against base metal, but all microstructures showed a quite lower {TEX}$DBTT_{SP}${/TEX} than those of SM50YB steel.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1991년도 하계학술대회 논문집
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• pp.174-177
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• 1991

Fluorine-doped $SnO_2\;(SnO_2:F)$ films were prepared in ordinary atmosphere on borosilicate glass substrates using pyrosol deposition method starting from the solutions composed of $SnCl_4-5H_2O-NH_4F-CH_3OH-H_2O-HCl$ in an attempt to develop transparent conductors for use in amorphous silicon (a-Si) solar cello. The deposition rate of films increased with the increase in the content of $H_2O$, whereas it decreased with increasing the content of $CH_3OH$. When air was used as the carrier gas, the lowest electrical resistivity was obtained from a solution having $CH_3OH/H_2O$ mol ratio of about $2{\sim}3$ in the solution. The use of $N_2$ of the same flow rate as the carrier gab resulted always in the high resistive films, but the resistivity of the films decreased continuously with the increase in the content of $H_2O$. The surface morphology and preferred orientation of films were also affected by the solvent composition and the content of HCl in the solution. The room-temperature resistance of the films were fairly stable after heat-treatments up to $600^{\circ}C$.

• 한국식품영양학회:학술대회논문집
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• 한국식품영양학회 2001년도 동계 학술심포지움
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• pp.126-126
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• 2001

The Rhus verniciflua contains alkly(en)-catechol type allergens with a saiurated or unsaturated alkly chain of 15 or 17 carbon atoms. It has been recognized as an extremely active allergen causing skin reactions similar In poison ivy. The allergic contact dermatitis induced by the urushiol is known to be mediated be T lymphocytes whicht specifically recognize the hepten urushiol. Therefore. direct use of this plant as a medicinal purpose might imply a considerable hazard in Korea. In this study, using the established method for the detoxification from the stem bark of Rhus verniciflua, an strong antioxidant substance was isolated and characterized DPPH (diphenypricryl hydrazyl) assay measures hydrogen atom-donating activity and hence provides a measure of free radical scavenging antioxidant activity. DPPH, a purple-colored stable free radical, is reduced to yellow-colored diphenylpicryl hydrazine by antioxidants to deducing agents. Antioxidative effects of the water extract from RV were measured by DPPH assay. Twenty microliters of the extract was added to 1ml of 100mM DPPH solution in ethanol The mixture was shaken and left to stand for 10min at room temperature. The crude water extracts was purified by using HPLC method with a DEAE (anionic type), CN, ODS column. The purified compound remained stable at pH 3.0-6,0, but unstable above pH 6.5. It was stable heat at 10$0^{\circ}C$ for 4 hours, but still had about 80% of residual activity after treatment at 10$0^{\circ}C$ for 5 hours. The elemental composition of the HR-EI mass spectrum at m/z 170.02 was estimated the empirical formula as $C_{7}$ $H_{6}$ $O_{5}$. $C_{10}$ $H_4$ $O_2$N$_1$, $C_{5}$ $H_4$ $O_4$N$_3$, $C_{8}$$H_2O$$_1$N$_4$. In antimicrobial test, no inhibition was observed against Gram-positive and negative bacteria. This compound was stronger than that of commercial antioxidant by DPPH test, such as BHT, BHC at the same concentration (20$\mu$g/ml).ml).

• 한국전기전자재료학회논문지
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• 제25권3호
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• pp.204-208
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• 2012

$TiO_2$ ($Ti_{1-x}Nb_xO_2$, x= 0.04~0.06) transparent conducting oxide film was fabricated by RF magnetron sputtering process and their electrical, optical, stability properties were studied. When the Nb 4 at% sputtering target was used with RF power 120 W, pressure 8 mTorr, post-annealing temperature $600^{\circ}C$, the resistivity of TNO film was $4{\times}10^{-4}\;{\Omega}-cm$. The optical transmittance in the visible wavelength was ca. 86%. TNO films require heat treatment during or after the deposition process. When the film was deposited at room temperature and post-annealed at $600^{\circ}C$, the lowest resistivity was obtained. When the TNO film was exposed to high temperature and humidity, the resistivity of the film was rather decreased. The stability to temperature and humidity implies that the TNO film could be a appropriate candidate for In-free, ZnO-free transparent conducting oxide materials.

• Journal of Advanced Marine Engineering and Technology
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• 제37권1호
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• pp.29-34
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• 2013

용접과정 중에 용접부가 공기에 노출되면 용접성능을 약화시킨다. 불활성가스 텅스텐 아크용접(GTAW)법을 사용하여 티타늄 용접을 하는 경우 용접부가 자주/적색, 청색, 노란색, 회색, 흰색 등의 빛깔을 보이면 이는 용접 시 공기 중의 산소와 질소에 오염된 것을 의미한다. 따라서 용접부를 대기로부터 보호하기 위한 방법으로 실딩 가스를 사용한다. 이것은 대기에 의한 오염을 방지할 뿐만 아니라 용착부와 열영향부도 상온까지 냉각될 때까지 대기로부터 차단시킨다. 본 연구에서는 Trailing Shielding Jig 의 모양과 형태 그리고 토치보호($13{\sim}20{\ell}/min$), 후방보호($22{\sim}30{\ell}/min$), 이면보호($25{\sim}30{\ell}/min$)등 건전한 용접부에 적합한 실딩 가스에 대한 결과를 도출하였다.

• 한국의류학회지
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• 제30권7호
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• pp.1090-1102
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• 2006

The purpose of this study is to develop an improved work clothing which is much safe, comfortable, mobility and convenient than what workers currently wear at construction site. The investigation has been conducted to evaluate current work clothing to grasp any problems, discomforts and damages related to the work clothing. For the best and accurate data, hands-on investigation and a short-interview have been performed at the construction site as well as formulating a questionnaire. The questionnaires was answered by 425 workers and safety manager of 13 different construction site. The result of the questionnaire enables us to design a sample work clothing, many pa π s such as material, pattern and design have been improved. To improve the amenity of heat, the surface of a material was used by $Aerocool^{\circledR}$ fiber which contains inside dryness function. In order to absorb perspiration on the back the armpits, mesh martial that is mixture of $Coolever^{TM}$ fiber and $Mirawave^{TM}$ fiber was used to absorb perspiration in an effective manner. And a sleeve's bottom part and trousers' bottom part's cover method have been changed. Sample work clothing was shorten at the side of upper garment up to 2cm and lengthen the length of the back by 3cm. To reduce the tightness around armpit more room was given in that area. Darts were added to the elbow, the hip, and the knees that also followed an ergonomic pattern. A sample work clothing evaluated an objective assessment and subjective assessment to compare to a current work clothing. Assessment group consists of seven subject groups and nine expert groups to evaluate external appearance and adaptability to the movements. In all aspects of the test, the result of evaluation process of the sample work clothing received more positive assessment than the current work clothing.

• 한국분말재료학회지
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• 제18권1호
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• pp.14-17
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• 2011

$TiO_2$ nanopowders with anatase structure were firstly prepared by controlling the pH value of a precursor solution without any heat-treatment at room temperature. The prepared $TiO_2$ nanopowders were hydrothermally treated in 10M NaOH solution at $170^{\circ}C$. Then, the samples were washed in DI water or 0.1M HCl. The $TiO_2$ nanotubes were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The gas sensitivity of $TiO_2$ nanotubes for toluene gas was also investigated. The results show that $TiO_2$ nanotubes can be prepared by hydrothermal treatment. The morphology of $TiO_2$ nanotubes prepared by 0.1M HCl washing is destroyed to some extent. $TiO_2$ nanotubes with DI water washing show better sensitivity than that with 0.1M HCl washing.

• 한국분말재료학회지
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• 제15권1호
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• pp.23-30
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• 2008

Ni-20Cr-20Fe-5Nb alloy with or without $Y_2O_3$ was manufactured by mechanical alloying process and consolidated by spark plasma sintering (SPS). The grain size of the alloy with $Y_2O_3$ was smaller than that of alloy without $Y_2O_3$ which results from the effect of $Y_2O_3$ suppressing grain growth. The tensile strength at room temperature was increased by the addition of $Y_2O_3$ but decreased abruptly at temperature above $600^{\circ}C$. It seems to result from the change of deformation mechanism due to fine grain size, that is, grain boundary sliding is predominant at above $600^{\circ}C$ while internal dislocation movement is predominant at below $600^{\circ}C$. After conventional heat treatment process of solution treatment and aging, a small amount of ${\delta}(Ni_3Nb)$ phase was formed in Ni-20Cr-20Fe-5Nb alloy while a large amount of ${\gamma}"(Ni_3Nb)$ was formed in Inconel 718 in the previous report. This is due to exhaustion of Nb content by the formation of NbC during consolidation.

• Applied Microscopy
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• 제4권1호
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• pp.5-10
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• 1974

본 실험에서는 여비압연이 4. 6%Mg-0.5% Mn-0.18%Cr의 알루미늄합금의 균질화처리 및 그의 기계적 성질에 마치는 영향을 조사하였다. 여비압연후 균질화 열처리된 시편은 주조상태의 시편에 비하여 실온 인장강도 및 연신률이 증가되고 있음을 보여주었다. $400^{\circ}C$의 고온 인장시험의 결과는 여비압연후 균질화열처리한 시편이 주조상태 또는 그의 균질화처리만 시행한 것에 비하여 다소 낮은 인장강도와 현저히 향상된 연신률을 소지함을 보여주었다. 여비압연후 균질화열처리된 시편의 금속현미경조직은 다른 시편들에 비해 결정입계에 ${\beta}$ 상등의 제2상이 현저히 감소되고 있음을 나타내고 있다. 시편의 결정입내 및 입계에 있어서의 주된 합금첨가원소인 Mg 분포상태를 EPMA를 사용하여 조사하였다. 이 결과는 균질화처리를 시행하기 전에 여비압연을 도입함으로써 균질화처리의 효과가 증대되고 있음을 보여주고 있다.