• Archives of Pharmacal Research
• /
• v.28 no.8
• /
• pp.983-987
• /
• 2005

Hydrogels composed of glycidyl methacrylate dextran (GMD) and poly(acrylic acid, PM) were prepared by UV irradiation method for colon-specific drug delivery. GMD was synthesized by coupling of glycidyl methacrylate to dextran in the presence of 4-(N,N-dimethylamino)pyridine. GMD was photo-polymerized by ammonium peroxydisulfate as initiating system in phosphate­buffered solution (0.1 M, pH 7.4). And then, acrylic acid monomer was added and subsequently heat-polymerized by 2,2'-azobisisobutyronitrile as an initiator. The hydrogels exhibited high swelling ratio (about 20) at $37^{\circ}C$, and showed a pH-dependent swelling behavior. In addition, the swelling ratio of the hydrogel was remarkably enhanced to about 45 times in the presence of dextranase at pH 7.4. The swelling-deswelling behavior proceeded reversibly for the GMD/PM hydrogels between pH 2 and pH 7.4. Release of 5-aminosalicylic acid from the GMD/PAA hydrogels was evaluated in simulated gastrointestinal pH fluids in the absence or presence of dextranase. We concluded that the hydrogels prepared could be used as a dual-sensitive drug carrier for sequential release in gastrointestinal tract.

• Journal of KSNVE
• /
• v.7 no.6
• /
• pp.985-991
• /
• 1997

Combustion instability is a common phenomenon in a ducted flame burner and is known as accompanying low frequency oscillation. This is due to the interaction between unsteady heat release rate and sound pressure field, that is, thermoacoustic feedback. In Rayleigh criterion, combustion instability is triggered when the heat addition is in phase with acoustic oscillation. A Rijke type burner with a pre-mixed flame is built for investigating the effect of Reynolds number and equivalence ratio on thermoacoustic oscillation. The results suggest that the frequency of max, oscillation is dependent on Reynolds number and equivalence ratio whereas its magnitude is not a strong function of these two parameters.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 1997.04a
• /
• pp.621-626
• /
• 1997

Combustion instability is a common phenomenon in a ducted flame burner and is known as accompanying low frequency oscillation. This is due to the interaction between unsteady heat release rate and sound pressure field, that is, thermoacoustic feedback. In Rayleigh criterion, combustion instability is triggered when the heat additions is in phase with acoustic oscillation. A Rijke type burner with a pre-mixed flame is built for investigating the effect of Reynolds number and equivalence ratio on thermoacoustic oscillation. In addition, the effect of wall temperature is presented. The results suggest that the frequency of max. oscillation is dependent on Reynolds number and equivalence ratio whereas its magnitude is not a strong function of these two parameters. On the other hand, the wall temperature distribution has much strong effects on the oscillation, even creates different mode of acoustic resonance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.7
• /
• pp.615-622
• /
• 2004

Recently, the hybrid system combining fuel cell and gas turbine has drawn much attention owing to its high efficiency and ultra low emission. It is now on the verge of world wide development and various system configurations have been proposed. A national project funded by Korean government has also been initiated to develop a pressurized hybrid system. This work aims at presenting design performance analysis for various possible system configurations as an initial step for the system development. Study focuses are given to major design options including the power ratio between gas turbine and fuel cell, reforming method (internal or external), reforming heat source (reforming burner, cathode hot air, fuel cell heat release) and steam supply method for reformer (anode gas recirculation, external steam generator). A wide variation in performance among different configurations has been predicted.

• Elastomers and Composites
• /
• v.42 no.3
• /
• pp.177-185
• /
• 2007

Polyamic acid(PAA)/organoclay nanocomposites containing phosphorous were prepared by solution blending of phosphorylated PAA(PPAA) and organically modified montmorillonite(O-MMT) as a type of layered clays. The nanocomposites were characterized by FT-IR, DSC, TGA, PCFC, SEM, and XRD. The preparation of nanocomposites was confirmed by FT-IR and XRD. SEM pictures showed that the organoclay was dispersed well in the PAA matrix relatively. XRD results indicated that the O-MMT layers were intercalated. The thermal stability and flame retardancy of O-MMT/PPAA nanocomposites were higher than those of pure PAA. PCFC results also showed that the heat release capacity and total heat release values of O-MMT 4 wt%/PPAA-0.2, 0.4, 0.6 composites were decreased with increasing the mole ratio of phosphorous. It was found that the nanocomposite films had the potential to be used as a fire safe material.

• Journal of ILASS-Korea
• /
• v.27 no.4
• /
• pp.203-210
• /
• 2022

Combustion and performance of a spark-ignition engine fueled with propane and butane were analyzed under different compression ratio. The electricity efficiencies of propane and butane increased with increasing the electricity production. The heat release rates of propane and butane were similar at a compression ratio of 9:1 because both fuels had similar optimal ignition timings without knocking combustion. Therefore, the difference in electricity efficiencies of engine generators was insignificant. However, at a higher compression ratio of 11:1, the butane engine generator had a lower electricity efficiency than the propane engine generator because its ignition timing retarded to suppress the knocking combustion.

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.6
• /
• pp.768-776
• /
• 2015

This study was performed to understand combustion properties four major Indonesian wood species such as Albizia, Gmelina, Mangium and Mindi were investigated by cone-calorimeter for better utilization of theses wood species. Heat release rate (HRR), total heat release (TSR), specific mass loss rate (SMLR), effective heat of combustion (EHC), time to ignition (TTI), flame time (FT), specific extinction area (SEA), smoke production rate (SPR) and CO compound production rate were measured. HRR, THR and FT were proportional to the density of woods. Albizia showed the highest HRR, while Mindi had the lowest HRR. For SPR, Albizia showed the highest value due to its higher SEA. On the other hand, Mindi had the lowest SPR due to a lower SEA value. The highest smoke emission was for Albizia at the beginning of combustion. After 300 seconds, smoke emission of Gmleina and Mangium was increased greatly. Mangium and Mindi showed the highest total carbon dioxide emission. Expecially, Gmelina released the highest carbon monoxide during the combustion period and presented three times higher $CO/CO_2$ ratio than those of other species due to incomplete combustion.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.2 s.257
• /
• pp.202-207
• /
• 2007

In order to understand the phenomena of combustion instability, an experimental study was conducted at the moderate pressure and ambient temperature conditions. The flame behavior and the pressure fluctuations were measured in a dump combustor. Various types of combustion modes occurred in accordance with the equivalence ratio and the fuel supplying conditions. The fluctuation of pressure, heat release and equivalence ratio were measured by piezoelectric pressure sensor, high speed Intensified Charge Coupled Device (HICCD) camera and gas chromatography respectively. Two representative modes were self-excited pressure oscillations at the resonance of combustion chamber (200Hz) and instabilities related to the modulated fuel flow rate through the fuel holes (10Hz). It is found that, especially in an unchoked fuel flow condition, the modulation of the fuel flow rate affects the characteristics of flame behavior and pressure fluctuations in a lean premixed flame.

• Korean Journal of Materials Research
• /
• v.29 no.4
• /
• pp.264-270
• /
• 2019

As a case study on aspect ratio behavior, Kaolin, zeolite, $TiO_2$, pozzolan and diatomaceous earth minerals are investigated using wet milling with 0.3 pai media. The grinding process using small media of 0.3 pai is suitable for current work processing applications. Primary particles with average particle size distribution D50, ${\sim}6{\mu}m$ are shifted to submicron size, D50 ${\sim}0.6{\mu}m$, after grinding. Grinding of particles is characterized by various size parameters such as sphericity as geometric shape, equivalent diameter, and average particle size distribution. Herein, we systematically provide an overview of factors affecting the primary particle size reduction. Energy consumption for grinding is determined using classical grinding laws, including Rittinger's and Kick's laws. Submicron size is obtained at maximum frictional shear stress. Alterations in properties of wettability, heat resistance, thermal conductivity, and adhesion increase with increasing particle surface area. In the comparison of the aspect ratio of the submicron powder, the air heat conductivity and the total heat release amount increase 68 % and 2 times, respectively.

• Journal of Institute of Convergence Technology
• /
• v.9 no.1
• /
• pp.13-19
• /
• 2019

The purpose of this study is to suggest a new method to determine a combustion phase (start of combustion and end of combustion) using a combustion pressure data. Unlike previous research method that used heat release amount, the difference between the combustion pressure measured in the combustion chamber and the motoring pressure was used to determine the combustion phase. This research was conducted using a single-cylinder diesel engine with a compression ratio of 17.7. The test was conducted under various injection timing. The newly proposed method showed high accuracy in combustion mode with early injection, as well as the conventional combustion mode. It is expected that this method will be used to study new combustion strategies such as HCCI (homogeneous charge compression ignition) and RCCI (reactivity controlled compression ignition) that are applying early injection strategies as well as existing combustion modes.