• Title/Summary/Keyword: Heat of reaction

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Arginyl-fructosyl-glucose and Arginyl-fructose, Compounds Related to Browning Reaction in the Model System of Steaming and Heat-drying Processes for the Preparation of Red Ginseng

  • Suzuki, Yukio;Choi, Kang-Ju;Uchida, Kei;Ko, Sung-Ryong;Sohn, Hyun-Joo;Park, Jong-Dae
    • Journal of Ginseng Research
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    • v.28 no.3
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    • pp.143-148
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    • 2004
  • Brown color intensity has been a major factor to estimate the quality of red ginseng and its products. This study deals with the relationship between the browning reaction of ginseng root and two compounds, arginyl-fructosyl-glucose(Arg-fru-glc) and arginyl-fructose (Arg-fru), in the model system of steaming and heat-drying processes for the preparation of red ginseng. During the steaming process, a marked decrease of starch and a considerable formation of maltose occurred in main roots of raw ginseng, but the formation of glucose was scarcely observed. After the heat-drying process, the brown color intensity of the powdered preparation of steamed main roots was 3 to 4 times higher than that of the powdered preparation of raw main roots. Also, when the heat- drying process was done with the addition of L-arginine, brown color intensity of the powdered preparation of steamed main roots was 12 to 13 times higher than that of the powdered preparation of raw main roots. The amount ratios of browning reaction products formed from sugar compounds and amino acids in the model system of steaming and heat-drying treatments in vitro were in order of xylose > glucose > fructose > maltose > dextrin (DE 9) > sucrose > dextrin (DE 8) and soluble starch. Each solution of Arg-fru-glc and Arg-fru that were synthesized chemically from maltose plus L-arginine and glucose plus L-arginine, respectively, changed from colorless to brown color during the heat-drying treatment. Amino acids or sugars were effective on the acceleration of each browning reaction of Arg-fru-gIc and Arg-fru during the heat-drying treatment.

A Study on the Heat Storage System for Chemical Heat Pump Using Inorganic Hydrates (III) -Numerical Analysis of Heat Transfer in Ca(OH)2 Dehydration Packed Bed- (화학열펌프에 있어서의 무기수화물계 축열시스템에 관한 연구(III) -Ca(OH)2 탈수반응층의 전열해석-)

  • Park, Young-Hae;Lee, Young-Sei;Kim, Jong-Shlk
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1181-1191
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    • 1996
  • To develope chemical heat pump, which is operated by heat of high temperature using available energy sources such as solar heat and many kinds of waste thermal energy we have studied theoretically the enhancement effects of inserted fins on the rate of heat transfer and reaction in cylinderical $Ca(OH)_2$ packed bed reactor. The results obtained by numerical analysis about profiles of temperature, completion time of reaction and exothermic heat amount released from the reactor read as the inserted copper fins in reator reduce the completion time of dehydration reaction in packed bed by half, and the rate of thermochemical reaction depends on the temperature and concentration, and it is also governed by the boundary conditions and the rate of heat transfer in the particle packed bed.

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A Study on Expedite Heat Transfer in Packed Bed of Hydration Calcined Dolomite for Chemical Heat Pump (소성 Dolomite 수화물 화학열펌프의 고체반응층 전열촉진 연구)

  • Kim, Jong-Shik;Lee, Han-Gyu;Park, Young-Hae
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.434-439
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    • 2005
  • The reaction of hydration proceeded at the same time the vapor was introduced into the reactor that was filled with calcined dolomite. It has shown that the temperature has begun to fall from the bottom of reactor after increase of temperature by the heat of hydration reaction. The reaction initiated at the pipe wall and the heat was transfer to the center of block between the fins. The results show that the use of copper fin in the reactor reducted the hydration reaction time by half when compared to the case without using the fins.

A Technical Review of Endothermic Fuel Use on Supersonic Flight (고속비행체에서 흡열연료의 이용기술 동향)

  • Kim, Joong-Yeon;Park, Sun-Hee;Chun, Byung-Hee;Kim, Sung-Hyun;Jeong, Byung-Hun;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.93-96
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    • 2009
  • Advances in high speed flight technologies and engine efficiencies increase heat load on the aircraft. As the temperature of air flow is too high to cool the structure at hypersonic flight speeds, it is necessary to utilize the aircraft fuel as the primary coolant. By undergoing endothermic reaction, such as thermal decomposition or catalytic decomposition, aircraft fuels have heat sink potential. These fuels are called endothermic fuels. The endothermic reaction can be improved by catalysts, but limited by coke deposition. In this study the essential technologies of endothermic fuels are described, and intended to be used for basic research.

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Hazard Evaluation of Runaway Reaction in Deboronation Process Using H2O2 in DIET Synthesis of Pharmaceutical Raw Material (의약품 원료 DIET 합성 중 H2O2를 이용한 붕소제거 반응공정에서의 폭주반응 위험성 평가)

  • Kim, Won Sung;Lee, Keun Won
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.49-54
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    • 2018
  • In the Active Pharmaceutical Ingredient(API) manufacturing company, since the product is produced by the chemical reaction, fire and explosion are frequently occurred in the process of inputting the raw powder as the chemical reaction stage. There are not many studies on safety measures through analysis of cause of accident in the actual chemical reaction stage. In this study, we investigated the heat flow in the boron removal reaction process to investigate the risk in the chemical reaction stage. The study reaction process was performed by using the reaction calorimeter for the products synthesized at the actual raw material in pharmaceutical factory. The risk was estimated by comparing the maximum temperature of the synthesis reaction, which can generate heat due to the failure of cooling in the actual manufacturing process, and the technical temperature. These results are applied to commercial manufacturing sites and safety measures to control the risk of runaway reaction due to reaction heat are suggested.

Evaluation Methods on ONDOL Thermal Environmental Index (온돌 온열환경지표 평가방법)

  • Kim, Sung-Jo
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.1
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    • pp.101-110
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    • 2022
  • For this purpose, the authors proposed and proved usefulness of the modified mean skin temperature which is integrated mean radiation temperature and the effect of floor contacted heat conduction. The mean radiation temperature is applied form factor between half cross-legged human body and surrounding wall of indoor. In addition the floor contacted heat conduction is applied heat transfer coefficient of half cross-legged human body. Eight Korean young men were targeted for the experiment. From the experiment the authors excerpted physiological reaction and psychological reaction in Ondol environment which is combined physiccal environmental factor of artificial climate chamber, air and floor temperature. As a result of the experiment it is confirmed that heat conduction has more impact than heat exchange from existing research for the heat exchange between half cross-legged human body and surrounding wall in Ondol thermal environment. Thereby, it is proved the effectiveness of the modified mean skin temperature which is added floor contacted temperature to the Ondol thermal environmental evaluation index.

Fabricability of Reaction-sintered SiC for Ceramic Heat Exchanger Operated in a Severe Environment (원자력 극한환경용 세라믹 열교환기 소재로서 반응소결 SiC 세라믹스 제작성)

  • Jung, Choong-Hwan;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.52-56
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    • 2011
  • Silicon carbide (SiC) is a candidate material for heat exchangers for VHTR (Very High Temperature Gas Cooled Reactor) due to its refractory nature and high thermal conductivity. This research has focused on demonstration of physical properties and mock-up fabrication for the future heat exchange applications. It was found that the SiC-based components can be applied for process heat exchanger (PHE) and intermediate heat exchanger (IHX), which are operated at $400{\sim}1000^{\circ}C$, based on our examination for the following aspects: optimum fabrication technologies (design, machining and bonding) for compact design, thermal conductivity, corrosion resistance in sulfuric acid environment at high temperature, and simulation results on heat transferring and thermal stress distribution of heat exchanger mock-up.

A Study on the Performance Improvement of an Air Spring System (에어스프링 시스템의 성능 개선에 관한 연구)

  • Jang, J.S.
    • Journal of Drive and Control
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    • v.10 no.2
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    • pp.1-6
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    • 2013
  • This study describes a method which can attenuate reaction force effectively for an air spring system composed of an air spring and auxiliary chamber. For the analysis, the nonlinear governing equation of the air spring system is derived. For a performance improvement of the system, change of the heat transfer effect and the mass flow rates is included in the analysis of the air spring system. The simulation study is presented to show the reaction force is changed by variations in heat transfer characteristics and the air spring system of isothermal process has the best performance. As a result, to improve attenuation characteristics of reaction force, a process in the air spring system should be maintained near isothermal process.

Experimental and Theoretical Study on the Effect of Pressure on the Surface Reaction over Platinum Catalyst (백금촉매의 표면반응에 미치는 압력의 영향에 관한 실험 및 이론적 연구)

  • Kim, Hyung-Man
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.1-6
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    • 2000
  • Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.

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Study of Heat of Reaction Between Plasma Polymer Coated Silica Fillers and Biphenyl Epoxy Resin (플라즈마 코팅된 실리카와 에폭시 수지간의 반응성 연구)

  • Kim N. I.;Kang H. M.;Yoon T. H.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.96-99
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    • 2004
  • Silica fillers were coated by plasma polymer coatings of 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allyl mercaptan and allyl alcohol using RF plasma (13.56 MHz). The coated fillers were then mixed with biphenyl epoxy, phenol novolac (curing agent) and/or triphenylphosphine (catalyst), and subjected to DSC analyses in order to elucidate the chemical reaction between functional moieties in the plasma polymer coatings and the epoxy resin. Only the samples with 1,3-diaminopropane and allylamine plasma polymer coated silica fillers showed heat of reaction peaks when they were mixed with biphenyl epoxy resin only, while these samples as well as the samples with 1,3-diaminopropane, allylamine and pyrrole plasma polymer coated silica fillers exhibited heat of reaction peaks when mixed with both biphenyl epoxy and phenol novolac (curing agent).

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