• 한국지하수토양환경학회지:지하수토양환경
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• 제17권6호
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• pp.43-51
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• 2012

Rreactivity of persulfate (PS) for oxidation of TCE under various conditions such as heat, $Fe^{2+}$, and UV was investigated. It was found that degradation rate of TCE increased with increasing temperature from 15 to $35^{\circ}C$. At pH 7.0, the rate constants (k) at 15, 25, 30, and $35^{\circ}C$ were 0.07, 0.30, 0.74, and $1.30h^{-1}$, respectively. For activation by $Fe^{2+}$, removal efficiency of TCE increased with increasing $Fe^{2+}$ concentration from 1.9 mM to 11 mM. The maximum removal efficiency of TCE was approximately 85% when pH of the solution dropped from 7.0 to 2.5. Degradation of TCE by UV-activated PS was the most effective, showing that the degradation rate of TCE increased with inreasing PS dosage; the rate constants (k) at 0.5, 2.5, and 10 mM were 34.2, 40.5, and $55.9h^{-1}$, respectively. Our results suggest that PS activation by UV/PS process could be the most effective in activation processes tested for TCE degradation. For oxidation process by PS, however, pH should be observed and adjusted to neutral conditions (i.e., 5.8-8.5) if necessary.

• 한국산학기술학회논문지
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• 제20권11호
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• pp.527-536
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• 2019

본 연구에서는 PTT BCF의 열과 자외선에 의한 취화거동과 분산염료의 열 및 자외선에 의한 퇴색거동을 연구하였다. 염료의 퇴색과 PTT BCF의 취화를 억제시킬 수 있는 첨가제를 방사과정에서 첨가하여 그 효과를 알아보았다. PTT BCF의 열처리 이후 취화거동은 열처리 온도와 노출시간이 증가할수록 취화현상이 가속화되어 시료의 인장강도 저하가 두드러졌다. 시료가 120℃까지의 온도에 노출하였을 때는 인장강도의 저하가 크지 않으나 그 이상의 온도인 150℃에서는 노출시간에 비례하여 급격한 인장강도 저하를 보였다. 열에 의한 취화는 산화방지 첨가제가 높은 온도에서는 그 효과가 안정적이지 않으며 산화반응이 급격하였다. 열처리 이후 시료의 퇴색은 열처리 온도가 증가할수록 K/S 값이 감소하였고, 노출시킨 시간이 증가할수록 퇴색되는 경향이 강하게 나타났다. 특히 고온으로 갈수록 열에 의한 퇴색 거동이 급격하게 증가하였으며 열퇴색 억제제가 그 효과를 발휘하지 못했다. 자외선 조사 이후 PTT BCF의 취화거동과 퇴색거동을 인장강도 변화와 K/S 값 변화로 각각 살펴보았다. 자외선 조사에 따른 취화는 열처리 시의 취화보다 더 크게 나타났으며, 특히 장시간 동안 노출된 경우 인장강도의 저하가 급격하였다. 또한 K/S 값의 변화 역시 온도와 노출시간이 증가할수록 퇴색거동이 강하게 나타났다. 시료의 취화거동과 퇴색거동은 자외선 조사의 경우가 더 가혹하게 나타났다. 열 및 자외선 모두가 분산염료의 퇴색에 영향을 주며, 자외선 조사는 같은 온도에서 노출했을 때에 비해 아주 높은 퇴색 속도를 보였다. 결론적으로 열과 자외선에 의한 퇴색과 취화는 특정 산화방지제와 자외선흡수제에 의해 다소 억제되어 저하되었다.

• 한국재료학회지
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• 제30권6호
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• pp.279-284
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• 2020

In this work, a carbon-doped carbon nitride photocatalyst is successfully synthesized through a simple centrifugal spinning method after heat treatment. The morphology and properties of the prepared photo catalyst are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectrophotometer (UV-vis), and specific surface area. The results show that the band gap of the prepared sample, g-CN-10 is 2.1 eV, is significantly lower than that of pure carbon nitride, 2.7 eV. As the amount of cotton candy increased, the absorption capacity of the prepared catalyst for visible light is significantly enhanced. In addition, the degradation efficiency of Rhodamine B (RhB) by sample g-CN-10 is 98.8 % over 2 h, which is twice that value of pure carbon nitride. The enhancement of photocatalytic ability is attributed to the increase of specific surface area after the carbon doping modifies carbon nitride. A possible photocatalytic degradation mechanism of carbon-doped carbon nitride is also suggested.

• 한국의류학회지
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• 제34권11호
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• pp.1859-1869
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• 2010

This study provides improved wrinkle recovery and UV protection capabilities as well as an antibacterial and deodorizing function to linen fabrics for summer shirts. The results obtained from this study are as follows. By setting catalyst concentration to 1.2% and DMDHEU concentration to 6% respectively and applying a heat treatment to them at $160^{\circ}C$ for 5 minutes, the decrease of fabric strength could be minimized and the crease resistance of linen fabrics improved. Compared to the treatment with DMDHEU only, the crease resistance of linen fabrics could be maintained and degradation of their properties could be more effectively prevented by applying the mixture of the UV absorber and the nano silver to the DMDHEU resin. The UV protection of fabrics could be improved by adding the UV absorber. Although the separate treatment of resin or the nano silver had no effect on the improvement of the UV protection properties for treated fabrics, they could increase the UV protection capability when they were combined with the UV absorber. Linen fabrics could possess an antibiosis and deodorizing capability by applying the mixture of the UV absorber, the nano silver, and the resin. The UV protection, crease resistance and flexibility of finished fabrics were maintained even after laundering. Washed treated fabrics maintained excellent antibiosis and odor free capabilities compared to untreated fabrics.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1697-1699
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• 1996

EPDM compound can be cured with either the sulfur and peroxide based systems. In this study, heat resistance and weatherability of EPDM compounds depending on curing systems were investigated. The test results showed that the peroxide-cured EPDM was more resistant to heat ageing and UV photo-degradation than the sulfur-cured EPDM and it is due to C-C bond is more stable than C-S, S-S bond.

• 한국결정성장학회지
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• 제19권3호
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• pp.144-151
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• 2009

Photocatalytic degradation of methylene blue (MB) in aqueous solution was investigated using $TiO_2$ coated on various acid modified activated carbon fiber (ACF). The ACFs/$TiO_2$ composites were prepared from titanium n-butoxide (TNB) as titanium precursor and various acid modified ACFs. The prepared samples are heat treated at 973 K. Then the ACF/$TiO_2$ composites were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX). Moreover, photocatalytic degradation of MB by the ACF/$TiO_2$ composites was determined under UV irradiation. The results shows that the photocatalytic activity of ACF/$TiO_2$ composites ($AT1{\sim}AT4$) prepared with TNB and various acid modified ACF was much better than that of ACF/$TiO_2$ composite (AT) prepared with TNB and non-acid modified ACF, and the effects improved with order of sample AT3 > AT4 > AT1 > AT2.

• 한국세라믹학회지
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• 제47권2호
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• pp.136-141
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• 2010

ACF/ZnO photocatalyst was synthesized by a sol-gel method using activated carbon fiber (ACF) and Zn $(NO_3)_2$ as precursors. Samples were characterized by Brunauer-Emmett-Teller measurements (BET), scanning electron microscope (SEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX). The XRD results showed that ACF/ZnO composites only included a hexagonal phase by heat-treated temperature at $400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$, and $700^{\circ}C$. The SEM analysis revealed that the ACF/ZnO composites did not exhibit any morphological changes of the catalyst surface according to the different heat-treated temperatures. The photocatalytic activity of the samples was tested for degradation of methylene blue (MB) solutions under ultraviolet (UV) light and ultrasonication respectively. The results showed that the photocatalytic activity of ACF/ZnO composites heat-treated at $500^{\circ}C$ was higher than other samples, which is ascribed to the fine distribution of ZnO particles on the surface of the ACF. In addition, an ultrasound of low power (50 W) was used as an irradiation source to successfully induce ACF/ZnO composites to perform sonocatalytic degradation of MB. Results indicated that the sonocatalytic method in the presence of ACF/ZnO composites is an advisable choice for the treatments of organic dyes.

• 한국세라믹학회지
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• 제34권9호
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• pp.993-1001
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• 1997

The (0.8PPV+0.2DMPPV) copolymer and silica/borosilicate composites were synthesized by sol-gel process. The organic-inorganic hybrid solution was prepared by using of (0.8PPV+0.2DMPPV) copolymer precursor solution as a raw material for organic components and TEOS and TMB for glass components. Then by drying the solution in vacuum at 5$0^{\circ}C$ for 7days and subsequent heat treatment in vacuum at 15$0^{\circ}C$~30$0^{\circ}C$ for 2h~72h with heating rate of 0.2$^{\circ}C$/min and 1.8$^{\circ}C$/min, the organic-inorganic composites were synthesized. Microstructural evolution of the composites was characterized by DSC, IR spectrocopy, UV/VIS spectroscopy, and TEM. Elimination of the polymer precursor and degradation of the polymer were observed by DSC and Si-O and trans C=C absorption peaks were identified by IR spectra. The polymer was found to be successfully incorporated into the glass matrix and it was confirmed by the absorption peaks from the polymer in the UV/VIS spectra and the TEM results. The absorption peak of the composites was found to shift toward short wavelength side compared to that of the pure polymer and the amount of the blue shift increased with increasing the heat treatment temperature and heat treatment time and with decreasing the heating rate.

• 대한환경공학회지
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• 제39권5호
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• pp.246-254
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• 2017

호소, 하천 등에 다량의 영양염류의 유입과 수문학적, 지리학적, 생물학적 요소 등으로 인해 남조류가 대량 발생하게 되며 대표적 독성물질인 마이크로시스틴-LR(MC-LR)이 증가한다. MC-LR이 포함된 지표수를 적절하게 처리하기 위하여 정수처리공정에서는 고도산화공정을 적용하고 있다. 다양한 고도산화공정 중 특히 UV, $UV/H_2O_2$, $UV/O_3$, $UV/TiO_2$ 등에 대한 연구는 꾸준히 되어왔다. 기존의 UV램프의 짧은 교체주기, 수은 폐기물 발생, 큰 열 손실 등의 단점을 보완한 UV-LED를 MC-LR제거에 적용하였다. MC-LR 초기농도 $100{\mu}g/L$을 280 nm의 파장인 LED-L ($0.024mW/cm^2$)와 LED-H ($2.18mW/cm^2$)를 이용하여 산화시켰을 때 각각 최대 약 30%, 95.9%의 MC-LR 제거율을 나타냈다. LED-H를 조사 시 자연유기물 변화는 휴믹물질, UVD, SUVA가 감소하는 경향을 보였고 방향족 유기물이 지방족 유기물로 분해되어 저분자 물질이 되었다. $LED-H/H_2O_2$($H_2O_2$: 1, 2, 5, 10 mg/L)산화반응에 의한 MC-LR제거율은 LED-H 단독에 의한 MC-LR 제거율과 유사하였다. 남조류가 발생한 낙동강 원수를 대상으로 LED-L산화를 적용하여 수질분석을 통하여 특성변화를 확인하였다. DOC 및 TOC의 변화는 거의 없었으나 SUVA와 $UV_{254}$의 감소로 인하여 유기물의 분해되었으며 조류유래물질인 용존 및 총 MC-LR, geosmin, 2-MIB농도가 시간이 지남에 따라 서서히 감소하였다.

• 대한전자공학회논문지TE
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• 제39권3호
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• pp.8-14
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• 2002

본 연구는 고분자 재료의 표면열화 발생 및 진행경로를 해석하기 위한 일환으로 열, 자외선 및 방전에 의한 열화를 각각 임의로 모의하여 접촉각 특성을 측정하여 열화 발생메커니즘을 해석하였으며, 특히 기존의 열화 연구와 달리 화학적 측면과 정전적 측면을 연계시킨 상관적 특성분석을 수행하였다. 표면활성화 상태를 측정한 접촉각 변화에 있어서, 일반적인 고분자의 표면은 73$^{\circ}$~91$^{\circ}$의 약소수성을 나타낸다. 그러나, 방전처리 및 350 nm 이하의 자외선 파장에 노출된 표면은 13.8$^{\circ}$ 및 20$^{\circ}$로 급격한 친수화를 나타내었고, 열처리 및 430~500nm 파장의 가시광 파장에 노출된 표면은 90$^{\circ}$와 80.1$^{\circ}$의 최대 접촉각 상승을 보이며 소수화를 나타냈다.