• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.295-301
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• 2013

Long-term global energy-demand growth is expected to increase driven by strong energy-demand growth from developing countries. Fusion power offers the prospect of an almost inexhaustible source of energy for future generations, even though it also presents so far insurmountable scientific and engineering challenges. One of the challenges is safe handling of hydrogen isotopes. Metal hydrides such as depleted uranium hydride or ZrCo hydride are used as a storage medium for hydrogen isotopes reversibly. The metal hydrides bind with hydrogen very strongly. In this paper, we carried out a modeling and simulation work for absorption/desorption of hydrogen by ZrCo in a horizontal annulus cylinder bed. A comprehensive mathematical description of a metal hydride hydrogen storage vessel was developed. This model was calibrated against experimental data obtained from our experimental system containing ZrCo metal hydride. The model was capable of predicting the performance of the bed for not only both the storage and delivery processes but also heat transfer operations. This model should thus be very useful for the design and development of the next generation of metal hydride hydrogen isotope storage systems.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.3
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• pp.43-48
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• 2008

The economics of a passive solar heating system (PSHS) with the pebble bed heat storage was evaluated, and the applications of the PSHS were analyzed, in this study. The results are as follows: The heating load, solar heat gain, and stored heat/year of the PSHS in the solar house model were found to be 10,778MJ, 3,438MJ, and 11,682MJ, respectively. The yearly energy expenses of the PSHS and the alternative heating system (conventional coal heating system, CCHS), which uses coal, were found to be USD 1.60/year and USD 60.90/year, respectively, and the yearly expenses of the PSHS were found to be 38 times less than those of the alternative heating system (CCHS). If it will be supposed that the life cycle of the passive solar heating system, according to the results of the LCC analysis in the two systems, is 40 years, the total expenses for the life cycle of the PSHS and the CCHS will be USD 1,431.50 and USD 2,740.00, respectively. The period for the investment payback of the PSHS is six years.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.1
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• pp.34-41
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• 2004

The chemical heat pump based on the Dehydration/Hydration process with a MgO/$H_2O$ system has been researched. The reactor bed could be expected to store the heat around 200∼37$0^{\circ}C$ by the dehydration reaction and to release the heat around 100∼16$0^{\circ}C$ by the hydration reaction under the heat amplification mode operation. The heat output rate of the heat pump system was evaluated using the experimentally determined parameters. The results show that 6∼50 W/kg of heat output and 0.5∼0.8 of heat recovery ratio are attainable. The heat pump will be applicable for a load leveling in a co-generation system by chemical storage of surplus heat at low heat demand and by supplying heat in the peak load period.

• Solar Energy
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• v.14 no.2
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• pp.91-101
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• 1994

Heat release characteristics of a CaO packed bed reactor which is used for a chemical heat storage device has been studied. We employed Cu-plate fins to release the heat of reaction of the CaO packed bed inside the reactor fast and effectively. Two-dimensional analysis of unsteady state heat flow inside the bed was performed as a function of time and under various conditions of the Cu-plates. It is noted that the time required to release the heat of reaction with Cu fins is reduced more than twice fast compared to that without Cu fins. That was largely dependent upon the number of Cu-plate, as well.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.2
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• pp.175-182
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• 2007

The objective of the present study is to investigate the heat storage characteristics of a packed bed according to periodically oscillating flows. Experiments have been performed to measure transient temperature distributions in solid and fluid Phases of the porous media. A simplified analytical model has been developed with intra-particle and dispersion effects neglected, and non-dimensional parameters have been derived. The transient temperature distributions according to the simplified numerical model agree well with the experimental results. Heat storage efficiencies defined in two different ways are obtained for various time periods and face velocities.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.518-529
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• 1996

To develope chemical heat pump using available energy sources such as solar heat and many kinds of waste thermal energy we have studied the enhancement effect of inserted fins in cylindical packed bed reactor. Two dimensionnal(radial and circumferential) partial differential eqaetions, concerning heat and masstransfer in CaO packed bad, are solved numerically to describe the characteristics of the reaction of fins inserted reactor and heat transfer. The results obtained by numerical analysis about two dimensional profiles of temperature and conversion in the reactant in the packed bed and exothermic heat amount released from the reactor are follows; -. The insertion of fins in reactor can redue the reaction completion time by half. -. The rate of thermochemical reaction depends of the temperature and concentration and it is also governed by the boundary conditions and heat transfer rate in the particle packed bed.

• Applied Chemistry for Engineering
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• v.7 no.6
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• pp.1181-1191
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• 1996

To develope chemical heat pump, which is operated by heat of high temperature using available energy sources such as solar heat and many kinds of waste thermal energy we have studied theoretically the enhancement effects of inserted fins on the rate of heat transfer and reaction in cylinderical $Ca(OH)_2$ packed bed reactor. The results obtained by numerical analysis about profiles of temperature, completion time of reaction and exothermic heat amount released from the reactor read as the inserted copper fins in reator reduce the completion time of dehydration reaction in packed bed by half, and the rate of thermochemical reaction depends on the temperature and concentration, and it is also governed by the boundary conditions and the rate of heat transfer in the particle packed bed.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.8 no.2
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• pp.81-88
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• 1979

The performance of air type solar heating system has been investigated for a system which has been operating continuously for two years. Design factors of a collector, such as the effective transmittance-absorptance and heat transfer factor were also determined experimentally. The flat plate collector is fabricated from steel sheet metal with two sealed glass covers. Solar heat is stored in a pebble bed of primarily granitic rock approximately 20-40 mm in diameter. The system is controled by automatically driven motors and dampers. The ratio of useful collected solar heat divided by the total solar radiation on the collector dropped was the range of 35 to 42 percent in monthly average. As it result, the air system was found fairly competitive with the water system, however, the heat supply from storage was limited because of using the pebble as the heat storage media.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.7 no.2
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• pp.80-86
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• 1978

The distribution of temperature obtained by the solution of Schumann equation and that of experimentally obtained on tile cooling process of packed bed of citrus unshu show a good agreement, and the maximum deviation is only $1-2^{\circ}C$. The agreement means that it is possible to apply the Schumann model to the cooling process of packed bed of citrus unshu. In considering respiration heat, the numberical result by the solution of the equation is that in case of the velocity of gas $(3^{\circ}C)$ is above 1m/sec, becomes below 0.01 and effect of respiration heat is negligible and in case of below 1m/sec the velocity of gas $(3^{\circ}C)$ is above 0.01 and the effect of respiration heat must be consideied. We Present the Practically easily applicable figure of cooling characteristic line on the both . cases of short term cooling Process and long time storage of citrus unshu.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.507-515
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• 1992

This study was carried out to investigate the heat-storage/-release characteristics of the thermochemical reaction of the calcined dolomite and steam system for the application of regenerative heat exchangers with the packed bed shape experimental apparatus. The experimental data were obtained at the following conditions ; the hydration temperature was $150-400^{\circ}C$, the dehydration temperature was $700-800^{\circ}C$ and the steam mass flow rates were 294, 430 and 567 g/hr. In the present study, it was found that MgO of the calcined dolomite was not hydrated during the hydration process under the studied experimental conditions. Therefore, MgO of the calcined dolomite can be regard as an inert material. Because the reaction was proceeded from the packed bed input to packed bed output and from wall to center, it could be thought that the rate determining step is not the reaction itself but the heat transfer.