• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.878-883
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• 2018

A circulating fluidized bed (CFB) has been used in various chemical industries because of good heat and mass transfer. In addition, the methanol to olefins (MTO) process requiring the CFB reactor has attracted a great deal of interest due to steep increase of oil price. To design a CFB reactor for MTO pilot process, therefore, we has examined the hydrodynamic properties of spherical catalysts with different particle size and developed a correlation equation to predict catalyst holdup in a riser of CFB reactor. The hydrodynamics of micro-spherical catalysts with average particle size of 53, 90 and 140 mm was evaluated in a $0.025m-ID{\times}4m-high$ CFB riser. We also developed a model described by a decay coefficient to predict solid hold-up distribution in the riser. The decay coefficient developed in this study could be expressed as a function of Froude number and dimensionless velocity ratio. This model could predict well the experimental data obtained from this work.

• Nuclear Engineering and Technology
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• v.51 no.3
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• pp.746-754
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• 2019

Vitrification of radioactive liquid waste (RLW) provides a feasible solution for isolating radionuclides from the biosphere for an extended period. In vitrification, base glass and radioactive waste are added simultaneously into the melter. Determination of heat and mass transfer rates is necessary for rational design and sizing of melter. For obtaining an assured product quality, knowledge of reaction kinetics associated with the thermal decomposition of waste constituents is essential. In this study Thermogravimetry (TG) - Differential Thermogravimetry (DTG) of eight kinds of nitrates and two oxides, which are major components of RLW, is investigated in the temperature range of 298-1273 K in the presence of base glasses of five component (5C) and seven component (7C). Studies on thermal behavior of constituents in RLW were carried out at heating rates ranging from 10 to $40\;K\;min^{-1}$ using TG - DTG. Thermal behavior and related kinetic parameters of waste constituents, in the presence of 5C and 7C base glass compositions were also investigated. The activation energy, pre-exponential factor and order of the reaction for the thermal decomposition of 24% waste oxide loaded glasses were estimated using Kissinger method.

• Journal of the Korean Society of Safety
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• v.36 no.2
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• pp.111-119
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• 2021

Multi-dimensional analysis of reactor safety-KINS standard (MARS-KS) is a thermal-hydraulic code to simulate multiple design basis accidents in reactors. The code has been essential to assess nuclear safety, but has mainly focused on light water reactors, which are in the majority in South Korea. Few previous studies considered pressurized heavy water reactor (PHWR) applications. To verify the code applicability for PHWRs, it is necessary to develop MARS-KS input decks under various transient conditions. This study proposes an input model to simulate small-break loss of coolant accidents for PHWRs. The input model includes major equipment and experimental conditions for test B9802. Calculation results for selected variables during steady-state closely follow test data within ±4%. We adopted the Henry-Fauske model to simulate break flow, with coefficients having similar trends to integrated break mass and trip time for the power supply. Transient calculation results for major thermal-hydraulic factors showed good agreement with experimental data, but further study is required to analyze heat transfer and void condensation inside steam generator u-tubes.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.1
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• pp.1-10
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• 2021

Water electrolysis technology, which generates hydrogen using renewable energy resources, has recently attracted great attention. Especially, the polymer electrolyte membrane water electrolysis system has several advantages over other water electrolysis technologies, such as high efficiency, low operating temperature, and optimal operating point. Since research that analyzes performance characteristics using test bench have high cost and long test time, however, model based approach is very important. Therefore, in this study, a system model for water electrolysis dynamics of a polymer electrolyte membrane was developed based on MATLAB/Simulink®. The water electrolysis system developed in this study can take into account the heat and mass transfer characteristics in the cell with the load variation. In particular, the performance of the system according to the stack temperature control can be analyzed and evaluated. As a result, the developed water electrolysis system can analyze water pump dynamics and hydrogen generation according to temperature dynamics by reflecting the dynamics of temperature.

• Computers and Concrete
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• v.30 no.2
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• pp.143-150
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• 2022

In this paper, the non-linear mathematical problem is solved via numerical scheme by utilizing shooting method. Brownian diffusion and thermophoresis along mass and heat transfer are accounted for. Non-linear expression is reduced via non-dimensional variables. The simplified ordinary differential equations are tackled by shooting technique. Behavior of distinct influential parameters is investigated graphically and analyzed for temperature and concentration profile. Our finding indicates that temperature profile is enhanced for the thermophoresis, Brownian motion coefficient, Prandtl number, Eckert number and temperature slip parameter. Comparison of numerical technique with the extant literature is made and an acceptable agreement is attained. Graphs are plotted to examine the influence of these parameters.

• Progress in Superconductivity and Cryogenics
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• v.8 no.4
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• pp.30-33
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• 2006

Several crucial issues are discussed in the design of cryogenic cooling system for high field magnets. This study is mainly motivated by our ongoing program to develop a 21 T Fourier Transform Ion Cyclotron Resonance Mass Spectrometer (FT-ICR MS). The magnets of this system will be built horizontally to accomplish the requirement of user friendliness and reliability, and the replenishment of cryogen will not be necessary by a closed-loop cooling concept. The initial cool-down and safety are basically considered in this paper. The effects of the helium II volume and the gap distance of the weight load relief valve (or safety valve) on the cool-down time and temperature rising during an off-normal state are discussed. The total amount of cryogenic cooling loads and the required helium flow rate during cool-down are also estimated by a relevant heat transfer analysis. The temperatures of cryogen-free radiation shield are finally determined from the refrigeration power of a cryocooler and the total cryogenic loads.

• Structural Engineering and Mechanics
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• v.88 no.6
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• pp.521-533
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• 2023

In the present study, the finite volume method is applied for the thermal performance prediction of the natural ventilation system using vertical solar chimney whereas, design parameters are optimized through the response surface methodology (RSM). The computational simulations are performed for various parameters of the solar chimney such as absorber temperature (40≤T_abs≤70℃), inlet temperature (20≤T₀≤30℃), inlet height of (0.1≤h≤0.2 m) and chimney width (0.1≤d≤0.2 m). Analysis of variance (ANOVA) was carried out to identify the design parameters that influence the average Nusselt number (Nu) and mass flow rate (ṁ). Then, quadratic polynomial regression models were developed to predict of all the response parameters. Consequently, numerical and graphical optimizations were performed to achieve multi-objective optimization for the desired criteria. According to the desirability function approach, it can be seen that the optimum objective functions are Nu=25.67 and ṁ=24.68 kg/h·m, corresponding to design parameters h=0.18 m, d=0.2 m, T_abs=46.81℃ and T₀=20℃. The optimal ventilation flow rate is enhanced by about 96.65% compared to the minimum ventilation rate, while solar energy consumption is reduced by 49.54% compared to the maximum ventilation rate.

• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.57-63
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• 2016

Thermally induced phase separation (TIPS) and nonsolvent induced phase separation (NIPS) were simultaneously induced for the preparation of flat PVDF membranes. N-methyl-2-pyrrolidone (NMP) was used as a solvent and dibutyl-phthlate (DBP) was used as a diluent for PVDF. When PVDF was melt blended with NMP and DBP, crystallization temperature was lowered for TIPS and unstable region was expanded for NIPS. Ratio of solvent to diluent changed the phase separation mechanism to obtain the various membrane structures. Contact mode of dope solution with nonsolvent determined the dominant phase separation behavior. Since heat transfer rate was greater than mass transfer rate, surface structure was formed by NIPS and inner structure was by TIPS. Quenching temperature of dope solution also affected the phase separation mechanism and phase separation rate to result in the variation of structure.

• BMB Reports
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• v.40 no.1
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• pp.72-81
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• 2007

In order to screen the aging related proteins in human normal colon epithelia, the comparative proteomics analysis was applied to get the two-dimensional electrophoresis (2-DE) profiles with high resolution and reproducibility from normal colon epithelial tissues of young and aged people. Differential proteins between the colon epithelia of two age groups were found with PDQuest software. The thirty five differential protein-spots were identified by peptide mass fingerprint (PMF) based on matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) and database searching. Among them there are sixteen proteins which are significantly up-regulated in the colonic mucosal epithelia of young people group, which include ATP synthase beta chain, electron transfer flavoprotein alpha-subunit, catalase, glutathione peroxidase 1, annexin A2 and heat shock cognate 71 kDa protein, etc.; There are nineteen proteins which are significantly up-regulated in the colonic mucosal epithelia of aged people group, which include far upstream element-binding protein 1, nucleoside diphosphate kinase B, protein disulfide-isomerase precursor and VDAC-2, etc.. The identified differential proteins appear to be involved in metabolism, energy generation, chaperone, antioxidation, signal transduction, protein folding and apoptosis. The data will help to understand the molecular mechanisms of human colon epithelial aging.

• Journal of the Korean Solar Energy Society
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• v.29 no.1
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• pp.44-49
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• 2009

Steam reforming of methane in the high temperature solar chemical reactor bas advantage in its heating method. Using concentrated solar energy as a heating source of the reforming reaction can reduce the $CO_2$ emission by 20% compared to hydrocarbon fuel. In this paper, the simulation result of methane-steam reforming on a high temperature solar chemical reactor(SCR) using Fluent 6.3.26 is presented. The high temperature SCR is designed for the Inha Dish-1, a Dish type solar concentrator installed in Songdo city. Basic SCR performance factors are referred to the former researches of the same laboratory. Inside the SCR porous metal is used for a receiver/reactor. The porous metal is carved like a dome shape on the incident side to increase the heat transfer. Also, ring-disc set of baffle is inserted in the porous metal region to increase the path length. Numerical and physical models are also used from the former researches. Methane and steam is mixed with the same mole fraction and injected into the SCR. The simulation is performed for a various inlet mass flow rate of the methane-steam mixture gas. The result shows that the average reactor temperature and the conversion rate change appreciably by the inlet mass flow rate of 0.0005 kg/s.