• 한국환경보건학회지
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• 제47권2호
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• pp.155-165
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• 2021

Objectives: Acute exposure to high concentrations of chemicals can occur when a chemical accident takes place. As such exposure can cause ongoing environmental pollution, such as in the soil and groundwater, there is a need for a tool that can assess health effects in the long term. The purpose of this study was assessing the health risks of residents living near a chemical accident site due to long-term exposure while considering the temporal concentration changes of the toxic chemicals leaked during the accident until their extinction in the environment using a multimedia environmental dynamics model. Methods: A health risk assessment was conducted on three cases of formaldehyde chemical accidents. In this study, health risk assessment was performed using a multimedia environmental dynamics model that considers the behavior of the atmosphere, soil, and water. In addition, the extinction period of formaldehyde in the environment was regarded as extinction in the environment when the concentration in the air and soil fell below the background concentration prior to the accident. The subjects of health risk assessment were classified into four groups according to age: 0-9 years old, 10-18 years old, 19-64 years old, and over 65 years old. Carcinogenic risk assessment by respiratory exposure and non-carcinogenic risk assessment by soil intake were conducted as well. Results: In the assessment of carcinogenic risk due to respiratory exposure, the excess carcinogenic risk did not exceed 1.0×10-6 in all three chemical accidents, so there was no health effect due to the formaldehyde chemical accident. As a result of the evaluation of non-carcinogenic risk due to soil intake, none of the three chemical accidents had a risk index of 1, so there was no health effect. For all three chemical accidents, the excess cancer risk and hazard index were the highest in the age group 0-9. Next, 10-18 years old, 65 years old or older, and 19-64 years old showed the highest risk. Conclusion: This study considers environmental changes after a chemical accident occurs and until the substance disappears from the environment. It also conducts a health risk assessment by reflecting the characteristics of the long-term persistence and concentration change over time. It is thought that it is of significance as a health risk assessment study reflecting the exposure characteristics of the accident substance for an actual chemical accident.

• 한국산업보건학회지
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• 제33권3호
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• pp.317-331
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• 2023

Objectives: Construction workers are exposed to various hazardous substances simultaneously. However, little is known about the exposure hazards in construction industry. This study was aimed at identifying the risk of exposure hazards among construction workers. Methods: The expert survey (n=29) was conducted, including construction industry health managers (n=11) and work environment monitoring experts (n=18), on exposure probability, intensity and risk of hazardous substances by construction occupations Results: The exposure hazards of 30 construction occupations were identified and summarized through a literature review and expert survey. The most prevalent hazards were in order of noise, awkward posture, heat/cold, crystalline silica, cement/concrete dust, metal fumes, and volatile organic compounds. The hazards with highest risk score(over seven points) at construction occupations were noise(formwork carpenter, concrete finisher, rebar worker, demolition worker, driller/rock blaster), hazardous rays(welder), heat/cold (earthworks, formwork carpenter, rebar worker, concrete placer, scaffolder), awkward posture(bricklayer, caulker/tile setter, rebar worker) and heavy lifting(bricklayer, rebar worker). Among construction workers, the job types with the highest risk of exposure to carcinogens, and in which occupational cancer has been reported, were in order of stonemason, concrete finisher, rock blaster, welder, insulation installer, painter, scaffolder, plant worker and earthworks in order Conclusions: Systematic research and discussion on occupational disease among construction workers and its various hazardous factors are needed to establish job exposure matrix for facilitating standard for promptly processing the workers' compensation.

• 한국산업보건학회지
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• 제23권4호
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• pp.384-392
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• 2013

Objective: This study inspected incident cases, legal control levels, and GHS(Globally Harmonized System of Classification and Labeling of Chemicals) classification results of strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid, which have been responsible for many recent chemical accidents. As a result, it is deemed necessary for legal control levels of these strong acids to be revised and GHS classification be managed nation-wide. Methods: This study inspected incident cases and legal control levels for strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid. The study analyzed and compared chemical information status and GHS classification results. Results: There were 76 domestic incidents involving strongly acidic hazardous materials over the five years between 2007 and 2011. They include 37 leakage incidents(46.7%) within a workplace, 30 leakage incidents(39.5%) during transportation, and nine leakage incidents(13.8%) following an explosion. The strongly acidic materials in question are defined and controlled as toxic chemicals according to the classes of Substances Requiring Preparation for Accidents, Managed Hazardous Substance, Hazardous Chemical(corrosive) as set forth under the Enforcement Decree of the Toxic Chemicals Control Act and Rules on Occupational Safety and Health Standards of Occupational Safety and Health Act. Among them, nitric acid is solely controlled as a class 6 hazardous material, oxidizing liquid, under the Hazardous Chemicals Control Act. The classification results of the EU ECHA(European Chemicals Agency) CLP(Commission Regulation(EC) No. 790/2009 of 10 August 2009, for the purposes of its adaptation to technical and scientific progress, Regulation(EC) No 1272/2008 of the European Parliament and of the Council on classification, labeling and packaging of substances and mixtures) and NIER (National Institute of Environmental Research) are almost identical for the three chemicals, with the exception of sulfuric acid. Much of the classification information of NITE (National Institute of Technology and Evaluation) and KOSHA(Korea Occupational Safety and Health Agency, KOSHA) is the same. NIER provides 12(41.4%) out of 29 classifications, as does KOSHA.

• 농약과학회지
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• 제19권3호
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• pp.151-160
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• 2015

2010년부터 2012년까지 서울 가락동 농수산물도매시장에서 경매되는 채소류 중 들깻잎 4,063건 상추 2,248건을 대상으로 잔류농약 검사를 실시하였다. 들깻잎은 812건에서 농약이 검출되었고 40건이 부적합판정을 받았다. 상추의 경우 108건에서 농약이 검출되었고 잔류허용기준을 초과한 상품은 10건이었다. 검출된 농약은 들깻잎 61종, 상추는 28종이었다. 들깻잎 및 상추 섭취에 따른 다종농약 성분에 대한 안전성 평가는 들깻잎이 0.05% 이하, 상추가 0,1% 이하로서 인체에 대한 위해성은 낮은 것으로 평가되었다.

• 한국환경보건학회지
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• 제46권2호
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• pp.150-158
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• 2020

Objective: This study is designed to measure the concentration of DBPs (disinfection by-products) in pool water and in air and to estimate the carcinogenic potential through the evaluation of inhalation exposure. Methods: The subjects were six indoor swimming pools with many users in Gwangju. Samples of pool water and indoor air were taken every one month from August 2018 to August 2019 and analyzed for eight swimming pool standards. Three-liter air samples were collected and the VOCs were analyzed using GC/MS directly connected to thermal desorption. Results: pH was 6.8-7.5 and the concentration of free residual chlorine in pool water was 0.40-0.96 ?/ℓ. Physicochemical test items such as KMnO₄ consumption and heavy metal items such as Aluminum met existing pool hygiene standards. No VOC materials were detected except for the DBPs. The concentration of THMs in the pool water was 11.05-41.77 ㎍/L and the THMs mainly consist of Chloroform (63-97%) and BDCM (3-31%). The concentration of indoor air THMs is 13.24-32.48 ㎍/㎥ and consists of Chloroform. The results of carcinogenic assessment of chloroform in the indoor swimming pool via inhalation exposure were 2.0 to 6.4 times higher than the 'acceptable risk level' suggested by the US EPA. Conclusions: The concentration of THMs in the pool water is 11.05-41.77 ㎍/L, most of which is chloroform. In addition, the concentration of indoor air THMs is 13.24-32.48 ㎍/㎥. The result of carcinogenic assessment of chloroform was 2.0 to 6.4 times higher than the 'acceptable risk level' suggested by the US EPA.

• 한국안전학회지
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• 제22권4호
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• pp.96-101
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• 2007

Usually pictograms embedded in safety signs are such final means to transmit hazard information that the importance of them cannot be emphasized too much. Nevertheless, in Korea, few people are interested in safety signs and their functions so that evaluation of safety signs are seldom committed nor safety signs draw workers' attention to fulfill their functions. Therefore this research aimed to standardize the procedure for developing safety signs in order not only to give practical help to industrial workers but to match them international standards, and to develop a few examples through the suggested standard procedure. As results, a procedure for developing industrial safety signs was developed by combining both ANSI Z535.3 and ISO 9186 with a special emphasis on action inducibility as the former emphasized as well as comprehensibility as the latter suggested. According to test results with undergraduate students as well as industrial workers on a few signs developed through the suggested procedure, action inducibility was higher whereas confusion rate was lower than expected on one hand, and it could be concluded that the procedure would supply results that can be satisfied on the other hand.

• 한국안전학회지
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• 제27권5호
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• pp.70-76
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• 2012

For the safe handling of n-tetradecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-tetradecane were calculated. The lower flash points of n-tetradecane by using closed-cup tester were measured $104^{\circ}C$ and $112^{\circ}C$. The lower flash points and fire point of n-tetradecane by using open cup tester were measured $113^{\circ}C$ and $115^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tetradecane. The experimental AIT of n-tridecane was $207^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $104^{\circ}C$ and upper flash point $140^{\circ}C$ for n-tetradecane were 0.63 Vol.% and 3.18 Vol%.

• Environmental Analysis Health and Toxicology
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• 제24권2호
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• pp.95-105
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• 2009

Chemical Ranking and Scoring (CRS) system is a useful tool to screen priority chemicals of large body of substances. The relative ranking of chemicals based on CRS system has served as a decision-making support tools. Exposure potential and toxicity are significant parameters in CRS system, and there are differences in evaluating those parameters in each CRS system. In this study, the parameters of exposure potential, human toxicity, and ecotoxicity were extensively compared. In addition the scoring methods in each parameter were analyzed. The CRS systems considered in this study include the CHEMS-1 (Chemical Hazard Evaluation for Management Strategies), SCRAM (Scoring and Ranking Assessment Model), EURAM (European Union Risk Ranking Method), ARET (Accelerated Reduction/Elimination of Toxics), and CRS-Korea. An comparative analysis of the several CRS systems is presented based on their assessment parameters and scoring methods.

• 대한수의학회지
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• 제38권2호
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• pp.265-272
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• 1998

The effects of mixtures of diazinon(DA;5mg/kg), toxaphene(TOX;40mg/kg) and/or endrin(END; 5mg/kg) on the hepatic mixed-function oxygenase(MFO) system were stuided in ICR mice(18~22g) by oral intubation daily for 7 days. In general, TOX and TOX-containing mixtures were found to induced the metabolism of aminopyrine(22~60%), aniline(42~85%), phenacetin(145~194%) and benzo [a]pyrene(158~210%), and pentobaribtal biotransformation in the 9,000g liver supernatants and to increased the hepatic cytochrome p-450 contents(47~89%). Results of these may be, at least in part, associated with the MFO system. TOX pretreatment increased the aliesterase activity in the serum and liver homogenates and supernatants by 23~145%. The toxicity of TOX and TOX-containing mixtures would be lower than that of diazinon because of TOX-induced increase in the metabolism of diazinon(DA) or diazioxon(DO) and capability of TOX to stimulate the metabolism of diazinon and diazioxon and provide a pool of non-critical enzymes. These results suggest that this information might be helpful in the evaluation of the potential hazard due to occupational and/or environmental exposures to pesticides and their mixtures.

• Journal of Nutrition and Health
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• 제37권8호
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• pp.722-731
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• 2004

The objective of this study was to evaluate the microbiological quality of non-heat-processed foods for implementation of a HACCP (Hazard Analysis and Critical Control Point) system in day-care center foodservice operations. The evaluating points were microbial assessment of foods, utensils, and employee's hands during preparation, cooking, and serving. The temperature of non-heated food being served was also measured. Microbiological quality was assessed using 3 M Petrifilm/syp TM/ to measure total plate count and coliforms for food and utensils and Staphylococcus aureus for hands in five Gumi day-care centers. Results showed low microbiological quality of non-heated foods. This was probably due to contaminated raw ingredients and cross-contamination that occurred during preparation and cooking (e.g., unsatisfactory washing and disinfection of raw materials and utensils). These results suggest that it is essential to educate employees on good personal hygiene (hand washing) , prevention of cross-contamination through use of properly washed and sanitized utensils, and proper washing and disinfection of raw vegetables. Establishing Sanitation Standard Operating Procedures (SSOPs) are an essential part of any RACCP system in day-care center foodservice operations.