• Title/Summary/Keyword: Hazardous materials

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Tafel Characteristics by Electrochemical Reaction of SnAgCu Pb-Free Solder (SnAgCu계 무연솔더의 전기화학적 반응에 따른 타펠 특성)

  • Hong Won Sik;Kim Kwang-Bae
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.536-542
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    • 2005
  • Recently European Council(EU) published the RoHS(restriction of the use of certain hazardous substances in electrical and electronic equipment) which is prohibit the use of Pb, Hg, Cd, $Cr^{+6}$, PBB or PBDE in the electrical and electronic equipments. So EU member States shall ensure that, from 1 July 2006, new electrical and electronic equipment put on the market does not contain 6 hazardous substances. The one of the most important in electronics manufacturing process is soldering. Soldering process use the chemical substances which are applied in fluxing and cleaning processes and it can generate the malfunction of electronics caused by corrosion in the fields conditions. Therefore this study researched on the polarization and Tafel properties of Sn40Pb and Sn3.0Ag0.5Cu(SAC) solder based on the electrochemical theory. We prepared SnPb specimens which was aged in $150^{\circ}C,\;180^{\circ}C$ for 15 minutes ana Sn3.0Ag0.5Cu specimens that was aged in $180^{\circ}C,\;220^{\circ}C$ for 10 minutes. Experimental polarization curves were measured in distilled ionized water and $3.5 wt\%$, 1 mole NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrode, respectively. To observe the electrochemical reaction, polarization test was conducted from -250 mV to +250 mV. From the polarization curves that were composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density(Icorr). In these results, corrosion rate for two specimen were compared Sn3.0Ag0.5Cu with SnPb solders

Environmental Toxicity of ACQ-Treated Wood Based on the Fish Acute Test (어류급성독성 시험에 의한 ACQ 방부목재의 환경 독성)

  • Woo, Ji-Keun;Kim, Du-Won;Kim, Sung-Kyun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.14 no.2
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    • pp.107-115
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    • 2011
  • The purpose of the study is to analyze the environmental characteristics of fish acute toxicity that is dependent on the harmfulness of ACQ (Alkaline Copper Quat)-Treated Wood and Oryzias latipes mortality in a comprehensive way, provide objective verification method on the eco-toxicity and environment-friendliness of landscaping materials and methods, and utilize it as a basic datum for evaluation criteria. The main results are summarized as follows : 1. As a result of analysis on the harmfulness characteristics, each experimental plot showed different values respectively. In particular, it has been found that in proportion to the volume of testing materials, COD and Cu increases at a constant rate, compared to the input water. In the plot C with three testing materials, COD increased 67 times more than that of the input water, and Cu increased up to 12.36mg/L. 2. In case of fish toxicity, plot C, B, A all showed a mortality rate of 100%, indicating that fish toxicity is strong. In particular, the mortality rate of each plot within the initial time of one and a half hour showed clearly, which suggests that the fish toxicity is influenced by the increased concentration of hazardous substances depending on the volume ratio of testing materials. 3. As a result of comparison and analysis on the harmfulness and fish toxicity, the harmfulness showed different values on each experimental plot but, we found that the changing rate of values of toxicity of COD and Cu is mutually similar to that of mortality in the initial hour according to the experiment of fish toxicity, which shows that COD and Cu are major factors to increase fish toxicity.

Development of Certified Reference Materials for Analysis of Heavy Metals in Paints to Cope with Environmental Regulations (환경규제 대응을 위한 페인트 중의 중금속 분석용 인증 표준물질 개발)

  • Yu, Byung Kyu;Sun, Yle Shik
    • Journal of Environmental Analysis, Health and Toxicology
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    • v.21 no.4
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    • pp.209-219
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    • 2018
  • In the areas of RoHS, WEEE, ELV and REACH, reinforcement of environmental regulations against harmful substances is a global trend not only in EC but also in all over the world. In the fields of Korea's major export products such as material parts, electrical and electronic products and automobile parts, we are responding to these regulations consistently. To develop reference material for analyzing lead and cadmium in paints, the candidate materials were produced through the screening process which separated shapes and sizes. To secure the traceability of the candidate materials produced, the characteristics and uncertainties are estimated by ICP-AES analysis using the primary reference material. The short-term and long-term stabilities also are evaluated in parallel. In order to calculate the final certification value of the candidate material, the verification were carried out by the performance evaluation through the comparison among the KOLAS (Korea Laboratory Accreditation Scheme) laboratories, and the CRM was produced in accordance with ISO Guide 35. The certified values and uncertainties of Pb and Cd of the final paint standard, determined according to the joint analysis among laboratories, are Pb [($191.4{\pm}3.1$) mg/kg, ($944.1{\pm}5.6$) mg/kg] and Cd [($45.0{\pm}2.6$) mg/kg, ($225.5{\pm}3.5$) mg/kg]. These standard materials were developed to enhance the reliability of measurement analysis, including the validity and traceability of measurement results. Also it is expected that the CRM will be used as QCM (quality control material) for the product design and the process monitoring, so that regulation and management of hazardous heavy metals can be systematically implemented.

A Neural Network-Based Tracking Method for the Estimation of Hazardous Gas Release Rate Using Sensor Network Data (센서네트워크 데이터를 이용하여 독성물질 누출속도를 예측하기 위한 신경망 기반의 역추적방법 연구)

  • So, Won;Shin, Dong-Il;Lee, Chang-Jun;Han, Chong-Hun;Yoon, En-Sup
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.38-41
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    • 2008
  • In this research, we propose a new method for tracking the release rate using the concentration data obtained from the sensor. We used a sensor network that has already been set surrounding the area where hazardous gas releases can occur. From the real-time sensor data, we detected and analyzed releases of harmful materials and their concentrations. Based on the results, the release rate is estimated using the neural network. This model consists of 14 input variables (sensor data, material properties, process information, meteorological conditions) and one output (release rate). The dispersion model then performs the simulation of the expected dispersion consequence by combining the sensor data, GIS data and the diagnostic result of the source term. The result of this study will improve the safety-concerns of residents living next to storage facilities containing hazardous materials by providing the enhanced emergency response plan and monitoring system for toxic gas releases.

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A Landfill Mining Technology by Trommel Screen System (트롬멜 스크린 시스템을 이용한 Landfill Mining기술)

  • Choe, Gap-Seok;Choe, Dong-Sun;Na, Gyeong-Deok;Lee, Byeong-Seon
    • 연구논문집
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    • s.34
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    • pp.1-10
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    • 2004
  • Landfill Mining is becoming more widely used in many closed landfill sites in the world. Many of existing landfills will be excavated inevitably owing to building the clean environment with the new structures and developing the cities in cramped country. This paper aimed at the introducing the design technology of the trommel screen and its in-site applied performance of the trommel screen system through experiments , which system is under developing by one of the national project and the analysis results of influencing factors to the environment . The result of the theoretical estimation agrees well with the experimental data, so that the sorting system could be able to be applied with the requirements of the purpose of end-items. As a result of the analysis, any hazardous materials including heavy metals met the limitions of the criteria in this experiment. In geotechnical enngineering, it will. desireable to use the sorted soils mixing with another soils in accordance with the requirements of the usages.

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A Study on the Fire Safety Performance of Interior Surface Materials in a Building (건축물의 실내건축 재료에 관한 화재안전성 연구)

  • Seo, Su-Eun;Shin, Seung-Woo
    • Proceedings of the Safety Management and Science Conference
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    • 2013.11a
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    • pp.275-290
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    • 2013
  • The main cause of building fire fatalities occur in the combustible material heat, smoke and toxic gases are. Building interior decoration, etc., especially as much of the harmful substances generated during combustion, and, used in domestic architecture wallpaper, ceiling, and other plastics, built-in foam insulation also analyzed recognition of fire hazards approach to test the conkalrorimiteo test, choedaeyeolbangchulryul through, chongbal heat, mass loss rate, generates carbon monoxide gas hazard ratio tests, analysis and evaluation rigid foam index testing the toxicity of hazardous material generated by performing a gas clean up and assess the material test results, the minimum order to provide data to quantify the risk of fire. Ensure fire safety of building materials, composite materials in order to test the various risk factors could be considered organic to the introduction of testing and evaluation is needed urgently.

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Study of Junior Furniture Design with LPM (LPM을 이용한 학생용 가구디자인 연구)

  • Lee, Hyun Jung
    • Journal of the Korea Furniture Society
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    • v.23 no.4
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    • pp.355-363
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    • 2012
  • From the end of the 20th century, there has been increased interest for life Well-Being and LOHAS. Attracting the interest of consumers for eco-friendly materials, the furniture in the finish of the interior space of interest. In the finish of the interior space and living furniture, eco-friendly materials and the process of development and research has led to a surface treatment for reducing hazardous substances. By a combination of natural materials and the latest eco-friendly rating, recognized in LPM (Low Pressure Melamine) has been developed. LPM was used birch and eco-friendly materials, the development of student furniture can be expanded depending on the growth.

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Solidification of Hazardous Wastes from Electroplating Industry (도금공장 유해폐기물의 고형화에 관한 연구)

  • Shin, Hang Sik;Her, Nam Ryoung;Koo, Ja Kong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.2
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    • pp.89-98
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    • 1988
  • This research evaluated factors on cement-based solidification process designed for hazardous sludge produced from electroplating industry. Four factors of sand/cement ratio, water/cement ratio, amount of wet sludge and amount of a precipitator, were investigated in terms of leachability and compressive strength of the solidified materials. Results of triplicate tests and statistical analysis indicated that sand/cement ratio(S/C) had the greatest effect on leaching of Cr(VI) from the solidified materials while water/cement ratio(W/C) on Zn and compressive strength. Cr(VI) was fixed better than Zn by portland cement. An experimental modeing was developed to estimate leached metal concentration and compressive strength at a given condition. Proper mixing criteria were also suggested for the use of the solidified mixture as construction materials. In solidification of 30g dry sludge, optimal condition was studied for S/C ratio, W/C ratio and the weight of precipitator which were 1, 1.5 and 1.075g respectively.

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Analysis of Non-compliance of Food Utensils, Containers, and Packages in Foreign Countries During 2011-2019 (2011-2019년 식품용 기구 및 용기·포장의 제외국 부적합 정보 분석)

  • Cho, Seung Yong;Lee, Ye Yeon;Cho, Sanggoo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.3
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    • pp.141-147
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    • 2021
  • The foreign trends of noncompliance occurring frequently in food contact materials during the period of 2011-2019 was investigated by analyzing the food safety risk information DB in the National Food Safety Information Service (NFSI). A total of 2,042 cases of noncompliance of food utensils, containers, and packages were classified into 5 violation categories; administrative procedures, manufacturing and processing standards, residues and migration standards, labeling and advertising, and quality standards. This was again subcategorized according to non-compliance causative factors. The non-compliances in residues and migration standards comprised the largest proportion (76.4%) of the violative categories. The number of noncompliance information collected in 2011 was 88 cases and increased to 373 cases in 2019. A 72.8% of the non-compliance case was identified to be products of 4 countries (China 64.2%, Germany 4.0%, Japan 3.2%, and Taiwan 3.1%), those produce large quantities of containers and packaging products. During the period of 2011-2019, the number of illegal use of hazardous materials and illegal recycling of waste synthetic resins has decreased to less than one a year since 2014. On the other hand, after 2016, inconsistency of heat-resisting temperature labeling (Taiwan), non-compliance in paper container's strength standards, violation of printing standards, and the risk of consumer injury while using the products were newly reported due to the strengthening of consumer safety protection regulations. Migration of hazardous substances in synthetic polymer products such as heavy metals, melamine and formaldehyde in melamine tableware, primary aromatic amines which are colorant components in kitchenware such as ladles and spatulas, and phthalate plasticizers have been continuously reported with high frequency.

Monitoring of the Source of Gelatin in Dietary Supplement Capsules Sold on the Internet

  • Kang, Tae Sun;Kim, Mi-Ra;Hong, Yewon;Lee, Jae-Hwang;Kwon, Kisung
    • Journal of Food Hygiene and Safety
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    • v.32 no.4
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    • pp.254-261
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    • 2017
  • Determining the origin of the components in commercially available gelatin, a purified protein derived mostly from pig skin and bovine tissue, is a challenge, leading to concerns on the grounds of religious beliefs and health. Therefore, regular monitoring of labeling compliance by food control authorities is also necessary. In this study, we monitored the origin of gelatin capsules from 181 commercial dietary supplements that were available for purchase on the internet, using species-specific PCR assays. Fifty five products were labeled correctly, declaring that they used bovine-, fish- and plant-derived gelatin, whereas the other 126 capsules were labeled "gelatin" without specifying the origin. Gelatin in these capsules was obtained from cattle (n = 51), pigs (n = 31), or both (n = 44). Therefore, it is important to declare all of the raw materials used to produce gelatin capsules on the labels to best protect consumers' rights, religious beliefs, and health.