• Title/Summary/Keyword: Hazardous and noxious chemicals

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A Study on a Safety System for Preventing Atmospheric Diffusion of Hazardous and Noxious Chemicals in Dike (방유벽 내 위험·유해화학물질 대기 확산 방지를 위한 안전시스템 연구)

  • Lee, Deok-Jae;Song, Chang-Geun
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.97-104
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    • 2019
  • Behind the growth of the chemical industry which is a cornerstone of the Korean economy, dozens of hazardous and noxious chemical accidents occur every year, resulting in enormous casualties and environmental damages. Many cases among chemical accidents are caused by the carelessness of workers in handling facilities such as hydrochloric acid and hydrofluoric acid, and the aging of handling facilities. In order to mitigate the damage by such chemical accidents, a safety system for preventing atmospheric diffusion of hazardous and xoxious chemicals in dike was proposed. The atmospheric diffusion prevention safety system consists of leak detection phase, alarm and measurement phase, suppression and blocking phase. Through the proposed the atmospheric diffusion prevention safety system, the need for 2nd chemical accident prevention such as atmospheric diffusion in dike can be posed.

Analysis of Performance Requirements of Mechanical System for Recovery of Deposited Hazardous and Noxious Substances from Seabed around Seaport (항만 해저침적 위험유해물질(HNS) 회수용 기계장치의 성능요건 분석)

  • Hwang, Ho-Jin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.6
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    • pp.681-688
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    • 2020
  • Approximately 6,000 chemicals are transported through the sea, including hazardous and noxious substances (HNS), which cause marine pollution and are harmful to marine life. The HNS discharged into the sea during the maritime transportation process undergoes physical and chemical changes on the sea surface and in seawater, and some types of HNS sink and are deposited on the seabed. The HNS deposited on the seabed adversely affects the benthic ecosystem, and hence, it is desirable to detect, treat, and recover the HNS on the seabed. Therefore, this study was conducted to analyze the performance requirements that should be considered as the top priority when developing a mechanical system for recovering the HNS deposited on the seabed. Various types of existing dredging devices used for collecting and recovering pollutants from river beds and seabeds were investigated, and 10 performance indices for the mechanical devices were selected. The new performance requirements for the development of the seabed-deposited HNS recovery system were proposed using performance indices. By considering the depth of water in domestic seaports, some of the performance requirements of the mechanical system for recovering deposited HNS from the seabed were obtained as follows: production rate (50-300 ㎥/hr), maximum operation depth (50 m), sediment type (most forms), percentage of solids (10 % or higher), horizontal operating accuracy (±10 cm), limiting currents (3-5 knots). These performance requirements are expected to be useful in the conceptual and basic design of mechanical systems for recovering seabed-deposited HNS.

A Study on the Fabrication of Multi-Walled Nanotubes (MWCNT) Based Thin Film and Chemical Sensor Operation Characteristics (Multi-Walled Carbon Nanotubes (MWCNT) 인쇄박막의 제작과 화학센서 동작 특성에 관한 연구)

  • Noh, Jae Ha;Choi, Junseck;Ko, Dongwan;Seo, Joonyoung;Lee, Sangtae;Jung, Jung-Yeul;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.181-185
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    • 2020
  • Hazardous and noxious substance (HNS) detection sensors were fabricated using multi-walled carbon nanotubes (MWCNTs) and various binder materials for ion batteries. To obtain uniformly printed films, the printing precision according to the substrate cleaning method was monitored, and the printing paste mixing ratio was investigated. Binders were prepared using styrene butadiene rubber + carboxymethyl cellulose (SBR+CMC), polyvinylidene fluoride + n-methyl-2-pyrrolidene (PVDF+NMP), and mixed with MWCNTs. The surface morphology of the printed films was examined using an optical microscope and a scanning electron microscope, and their electrical properties are investigated using an I-V sourcemeter. Finally, sensing properties of MWCNT printed films were measured according to changes in the concentration of the chemical under the various applied voltages. In conclusion, the MWCNT printed films made of (SBR+CMC) were found to be feasible for application to the detection of hazardous and noxious chemicals spilled in seawater.

Prioritizing Noxious Liquid Substances (NLS) for Preparedness Against Potential Spill Incidents in Korean Coastal Waters (해상 유해액체물질(NLS) 유출사고대비 물질군 선정에 관한 연구)

  • Kim, Young-Ryun;Choi, Jeong-Yun;Son, Min-Ho;Oh, Sangwoo;Lee, Moonjin;Lee, Sangjin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.7
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    • pp.846-853
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    • 2016
  • This study prioritizes Noxious Liquid Substances (NLS) transported by sea via a risk-based database containing 596 chemicals to prepare against NLS incidents. There were 158 chemicals transported in Korean waters during 2014 and 2015, which were prioritized, and then chemicals were grouped into four categories (with rankings of 0-3) based on measures for preparedness against incident. In order to establish an effective preparedness system against NLS spill incidents on a national scale, a compiling process for NLS chemicals ranked 2~3 should be carried out and managed together with an initiative for NLS chemicals ranked 0-1. Also, it is advisable to manage NLS chemicals ranked 0-1 after considering the characteristics of NLS specifically transported through a given port since the types and characteristics of NLS chemicals relevant differ depending on the port. In addition, three designated regions are suggested: 1) the southern sector of the East Sea (Ulsan and Busan); 2) the central sector of the South Sea (Gwangyang and Yeosu); and 3) the northern sector of the West Sea (Pyeongtaek, Daesan and Incheon). These regions should be considered special management sectors, with strengthened surveillance and the equipment, materials and chemicals used for pollution response management schemes prepared in advance at NLS spill incident response facilities. In the near future, the risk database should be supplemented with specific information on chronic toxicity and updated on a regular basis. Furthermore, scientific ecotoxicological data for marine organisms should be collated and expanded in a systematic way. A system allowing for the identification Hazardous and Noxious Substances (HNS) should also be established, noting the relevant volumes transported in Korean waters as soon as possible to allow for better management of HNS spill incidents at sea.

Mycoherbicidal Potential of Phaeoacremonium italicum, A New Pathogen of Eichhornia crassipes Infesting Harike Wetland, India

  • Singh, Birinderjit;Saxena, Sanjai;Meshram, Vineet;Kumar, Maneek
    • Mycobiology
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    • v.44 no.2
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    • pp.85-92
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    • 2016
  • Mycoherbicides are exclusive biotechnology products which offer a non-chemical solution to control noxious weeds on the land as well as aquatic in systems, viz a viz saving environment from hazardous impact of synthetic chemicals. The present paper highlights the mycobiota associated with Eichhornia crassipes infesting Harike wetland area of Punjab and evaluation of their pathogenic potential for futuristic application as a mycoherbicide. Of the 20 isolates tested by leaf detached assay and whole plant bioassays, only one isolate (#8 BJSSL) caused 100% damage to E. crassipes. Further, the culture filtrate of this isolate also exhibited a similar damage to the leaves in an in vitro detached leaf assay. The potential isolate was identified as Phaeoacremonium italicum using classical and modern molecular methods. This is the first report of P. italicum as a pathogen of E. crassipes and of its potential use as a biological control agent for the management of water hyacinth.

A Study on the Improvement of Marine Pollution and Marine Litter Managements in Korea (우리나라 해양오염 및 해양폐기물관리 개선에 관한 연구)

  • Park, Kwang-Ha;Kwon, Young-Du;Kim, Jong-Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.4
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    • pp.33-43
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    • 2013
  • That occur in the ocean and the efficient management of marine litter on marine pollution oil spill response one step further strategies are needed. Marine pollution accidents occurred in 2011, a total of 287 and was found in runoff 369 kL, respectively compared to the previous year decreased by 13% and 39%. Average amount of marine materials during 5-years represent the oil flow of 310.5 kL (heavy fuel oil of 106.0 kL, diesel of 178.9 kL, oily bilge water of 22.3 kL, other oil of 7.7 kL) and the waste of 62.3 tons, the hazardous and noxious substances (HNS) was 510.6 kL. Marine emissions in 2011 by type of waste that a total amount of dumping 3,972 $m^3$, and livestock manure 795 $m^3$(20%), waste water 1,431 $m^3$(36%), sewage sludge 887 $m^3$(22%), wastewater sludge, 813 $m^3$(21%), manure 5 $m^3$(0.1%), other 41 $m^3$(0.9%), respectively. The concept of marine waste and needs to be more clearly defined. Integrated management of hazardous chemicals according to the incident management system should be established. To remove of coastal pollution, response officer needs korean coast response system. Like the marine pollution response, coastal pollution response systems also require step response.

Analysis on Response System in US for Chemicals Driven Marine Pollution Accidents and Korean Response Policy Plan (화학물질 해양오염사고에 대한 미국의 방제체제 분석과 국내의 방제정책 방안)

  • Choi, Jong-Wook;Lee, Seung-Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.3
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    • pp.205-212
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    • 2009
  • With an entry into force of OPRC-HNS on June 14th 2007, response system against any large scale accidents related to HNS is required to respond rapidly and effectively in a national scale, US national response system and national contingency plan for any chemicals in operation were analyzed to understand the characteristics of management system and response system for any HNS driven accidents in the Us. Main characteristics of the US system were well described as an unified information window and an integrated incident command system supported by response facilities, manpower and technical support from other response organizations through good cooperation. In general, response activities are conducted by private sectors, however, the government will take over response activities in case large scale accidents occur in the Us. Expected expenses for response activities are covered by a type of Superfund in the Us. Several applicable ways are proposed to enable NGO to participate in and reorganize response system in ROK, and are feasible in collaboration with other response organizations and private sectors in the aspects of equipment, technology and manpower, Based upon the above activities, it is desirable to reorganize domestic rules and/or regulations related to response measures in ROK.

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A Study on Response System of Marine Pollution Accident by Chemicals in United States (화학물질 해양오염사고에 대한 미국의 방제체제 연구)

  • Choi, Jong-Wook;Lee, Seung-Hwan
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.61-67
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    • 2007
  • With an entering into force of OPRC-HNS started in June 14th 2007, establishment of response system in a nationwide scale to take care of accidents is required to respond rapidly and effectively. This necessities drove us to analyze national contingency plan for chemicals including national response system against accidents, which is in operation in the US. Main characteristics of the system are well described as an integrated incident command system with a cooperation of responsibilities facilities, manpower, and technical support. In addition, state anψor local authorities tend to have responsibilities on management of disaster with its response activities. Polluters are also charged to pay expenses 3 times expensive provided state or local authorities are conducted. In general, response activities are conducted by private sectors. However, the government will take action with Superfund if the response capacity is over than the polluters can. However, safety are regarded as a primary factor to be considered in the response activities, and try not to recover any pollutants. Personals belonging to USCG and EPA are required to complete specialized courses to promαe professional skills, and are also welcomed to participate in "certification program"

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The Present State of Domestic Acceptance of Various International Conventions for the Prevention of Marine Pollution (해양오염방지를 위한 각종 국제협약의 국내 수용 현황)

  • Kim, Kwang-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.4 s.27
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    • pp.293-300
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    • 2006
  • Domestic laws such as Korea Marine Pollution Prevention Law (KMPPL) which has been mae and amended according to the conclusions and amendments of various international conventions for the prevention a marine pollution such as MARPOL 73/78 were reviewed and compared with the major contents of the relevant international conventions. Alternative measures for legislating new laws or amending existing laws such as KMPPL for the acceptance of major contents of existing international conventions were proposed. Annex VI of MARPOL 73/78 into which the regulations for the prevention of air pollution from ship have been adopted has been recently accepted in KMPPL which should be applied to ships which are the moving sources of air pollution at sea rather tlnn in Korea Air Environment Conservation Law which should be applied to automobiles and industrial installations in land. The major contents of LC 72/95 have been accepted in KMPPL However, a few of substances requiring special care in Annex II of 72LC, a few of items in characteristics and composition for the matter in relation to criteria governing the issue of permits for the dumping of matter at sea in Annex III of 72LC, and a few of items in wastes or other matter that may be considered for dumping in Annex I of 96 Protocol have not been accepted in KMPPL yet. The major contents of OPRC 90 have been accepted in KMPPL. However, oil pollution emergency plans for sea ports and oil handling facilities, and national contingency plan for preparedness and response have not been accepted in KMPPL yet. The waste oil related articles if Basel Convention, which shall regulate and prohibit transboundary movement of hazardous waste, should be accepted in KMPPL in order to prevent the transfer if scrap-purpose tanker ships containing oil/water mixtures and chemicals remained on beard from advanced countries to developing and/or underdeveloped countries. International Convention for the Control if Harmful Anti-Fouling Systems on the Ships should be accepted in KMPPL rather tlnn in Korea Noxious Chemicals Management Law. International Convention for Ship's Ballast Water/Sediment Management should be accepted in KMPPL or by a new law in order to prevent domestic marine ecosystem and costal environment from the invasion of harmful exotic species through the discharge of ship's ballast water.

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