• 제목/요약/키워드: Hazardous Chemicals

검색결과 350건 처리시간 0.024초

PCB 제조공정을 위한 화학약품 용액의 실시간 모니터링 시스템 (Real-time Chemical Monitoring System using RGB Sensor toward PCB Manufacturing)

  • 안종환;이석준;김이철;홍상진
    • 한국전기전자재료학회논문지
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    • 제21권5호
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    • pp.397-401
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    • 2008
  • Most of the topic in PCB industry was about increasing the volume of product for the development of electronics in numerous industrial application area. However, it has been emerged that yield improvement quality manufacturing via detecting any suspicious process in order to minimize the scrapped product and material waste. In addition, recently, restriction of hazardous substances (RoHS) claims that electronic manufacturing environment should reduce the harmful chemicals usage, thus the importance of monitoring copper etchant and detecting any mis-processing is crucial for electronics manufacturing. In this paper, we have developed real-time chemical monitoring system using RGB sensor, which is simpler but more accurate method than commercially utilized oxidation reduction potential (ORP) technique. The developed Cu etchant monitoring system can further be utilized for copper interconnect process in future nano-semiconductor process.

S 전자 근로자 집단 백혈병 사건 (Workers' Compensation of Semiconductor Leukemia Victims)

  • 박영만
    • 한국산업보건학회지
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    • 제22권1호
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    • pp.26-31
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    • 2012
  • Objectives: To review the occurrence of cancer cluster in S Electronics semiconductor factories, process of epidemiological researches and lawsuit for industrial accident compensation. Methods: Occupational Safety and Heatlh Research Institute (OSHRI) epidemiological research report, Seoul National University (SNU) field survey report and Seoul Administrative Court ruling were investigated. Result:: OSHRI denied the association between working environment and outbreak of cancers, but SNU survey team reported that carcinogens do exist in workplace and the workers are exposed to them. Seoul Administrative Court ruled that 2 victims got cancer due to hazardous chemicals in working environment and be compensated but 3 victims were not acknowledged. Conclusions: Procedure of current OSHRI epidemiological research should be reassessed by the purpose of Occupational Accident Compensation Insurance Law.

국내 일부 소각장 근로자와 주변지역주민들의 PCDDs/Fs 노출과 건강 영향 평가 (Exposure Assessment of PCDD/Fs and Monitoring of Health Effects on Workers and Resident near the Waste Incinerators in Korea)

  • 홍윤철;이관희;권호장;장재연;임종한
    • Journal of Preventive Medicine and Public Health
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    • 제36권4호
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    • pp.314-322
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    • 2003
  • Objectives : In this study, the exposure status of the hazardous substances from incinerators, such as polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), were studied , and the relationship between the exposure of these hazardous substances and their heath effects on the workers and residents near municipal solid waste (MSW) incinerators and an industrial incinerator investigated. Methods : Between July 2001 and Jure 2002, 13 workers at two MSW incinerators, 16 residents from the area around the two MSW incinerators, 6 residents from the control area, and further 10 residents near an industrial incinerator, estimated to emit higher levels of hazardous substances, were interviewed. Information, including sociodemographic information, personal habits, and work history, detailed gynecologic and other medical history were collected through interviews. Blood samples were also collected from 45 subjects, and analyzed for PCDD/DFs, by high resolution gas chromatography -high resolution mass spectrometry, using the US EPA 1613 method. In addition to the questionnaire survey, urinary concentrations of 8-hydroxydeoxyguanosine (8-OH-dG) and malondialdehyde (MDA) were measured as oxidative injury biomarkers. The urinary concentrations of 8-OH-dG were determined by in vitro ELISA, and the MDA by HPLC, using u adduct with thiobarbituric acid. Results : The PCDD/DFs concentrations in the residents near the industrial incinerator were higher than those in the controls, workers and residents near the MSW incinerators. The average TEQ (Toxic Equivalencies) concentrations of the PCDD/DFs in residents near the industrial incinerator were 53.4pg I-TEQs/g lipid. The estimated daily intakes were within the tolerable daily intake range (1-4 pg I-TEQ/Kg bw/day) suggested by WHO (1997) in only 30% to the people near the industrial incinerator. Animal studies have already shown that even a low body border of PCDD/DFs, such as 10 ng TEQ/kg bw, can cause oxidative damage in laboratory animals. Our study also showed that the same body burden of PCDD/DFs can cause oxidative damage to humans. Conclusions : The exposures to PCDD/DFs and the oxidative stress of residents near the industrial incinerator, were higher than those in the controls, workers and residents near the MSW incinerators. Proper protection strategies against these hazardous chemicals are needed. Because a lower body burden of PCDD/Fs, such as 10ng TEQ/kg bw, can cause oxidative damage, the tolerable daily intake range should be restrictedly limited to 1pg I-TEQ/kg bw/day.

항만 해저침적 위험유해물질(HNS) 회수용 기계장치의 성능요건 분석 (Analysis of Performance Requirements of Mechanical System for Recovery of Deposited Hazardous and Noxious Substances from Seabed around Seaport)

  • 황호진
    • 해양환경안전학회지
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    • 제26권6호
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    • pp.681-688
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    • 2020
  • 해상을 통하여 운송되는 화학물질은 6,000여종에 이르며, 이러한 화학물질에는 해양을 오염시키거나 해양생물에 해로운 HNS(Hazardous and Noxious Substances)가 포함되어 있다. 해상운송 과정에서 바다로 유출된 HNS는 해상 및 해중에서 물리적, 화학적 변화를 거치게 되는데, 어떤 종류의 HNS는 해저로 침강하여 퇴적되기도 한다. 해저에 침적된 HNS는 해저생태계에 커다란 악영향을 주기 때문에 해저침적 HNS를 탐지·처리하여 회수하는 것이 바람직하다. 따라서 본 연구는 해저침적된 HNS를 회수하기 위한 기계장치를 개발할 때, 최우선으로 고려해야 하는 성능요건을 제시하였다. 해저의 오염물질을 회수하기 위하여 현재 사용되는 다양한 방식의 준설장비에 대하여 조사하고, 준설장비의 방식별 성능지표를 분석함으로써 기계장치에 대한 10가지의 성능지표를 선정하였다. 이러한 성능지표를 활용하여 해저침적 HNS 회수용 기계장치의 개발을 위한 성능요건을 제안하였다. 국내 항만의 수심을 고려하여, 해저침적 HNS 회수용 기계장치의 성능요건을 생산율(50 ~ 300 ㎥/hr), 최대운용수심(50 m), 저질 종류(대부분의 저질 형태), 고형률(10 % 이상), 수평 작업 정확도(± 10 cm), 제한 유속(3 ~ 5 knot) 등으로 제안하였다. 이러한 성능요건은 해저침적 HNS 회수용 기계장치의 개념설계와 기본설계에 활용될 것으로 기대된다.

유해화학물질 분석을 위한 생태조사 기반의 타깃 후보어종 선정법 (Target candidate fish species selection method based on ecological survey for hazardous chemical substance analysis)

  • 김지윤;진상현;조민재;최혜지;안광국
    • 환경생물
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    • 제41권2호
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    • pp.109-125
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    • 2023
  • 본 연구는 우리나라에서 수생태계에 유입되는 주요 유해화학물질 축적 분석을 위한 타깃 후보종 선정과 이에 따른 어류 군집의 영향을 분석하였다. 레퍼런스 하천 선정과 함께 유해화학물질 유입의 영향을 직접적으로 받는 하수종말처리장(T1)과 수계로 유입된 유해화학물질이 집중되는 금강하구언(T2)의 테스트배드를 분석하였다. 유해화학물질 분석을 위한 타깃 후보종 선정을 위해 7-메트릭 다변수 모델을 개발하였으며, 세부항목은 (1) 상업적으로 유용하며 식용으로 이용하는 어종, (2) 최상위 육식종 어종, (3) 유기물 섭취 어종, (4) 내성도가 높은 어종, (5) 개체수가 풍부한 어종, (6) 채집 가능성이 높은 어종, (7) 광범위하게 분포하는 어종 등 총 7개 메트릭으로 구성되었다. 타깃 후보어종에 대한 7개 메트릭 모델을 기반으로 8종이 대상 후보로 선정되었다. 타깃 후보종과 함께 공서하는 우점어종은 내성종(50%)이었으며, 이는 수질 오염 지표로 자주 사용되는 내성종의 풍부도가 가장 높은 것으로 나타났다. 또한, 수생태계 건강성 평가를 위한 다변량 어류 기반 모델 분석에서는 생태계 건강성이 "나쁨 상태"까지 진단되는 것으로 나타났다. 이화학적인 수질 변수는 테스트배드에서 섭식 및 내성길드에 영향을 미치는 것으로 나타났다. 8개의 수질 변수는 T1 지점에서 높게 나타나 하수처리장의 방류수에 따른 영향이 컸으며, T2 지점은 대규모 녹조 현상이 나타나 클로로필 농도가 레퍼런스 지점보다 약 15배 높은 것으로 나타났다.

학교사고에 영향을 미치는 학교안전 관리구조 실태 조사 -서울시 일부 고등학생을 대상으로- (The Research on the effect of School Safety Management System on Accident in School -Based on study of high schools in Seoul-)

  • 박지은;이명선
    • 보건교육건강증진학회지
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    • 제19권2호
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    • pp.57-72
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    • 2002
  • Students spend most of their time in school. Schools have the possibility of unanticipated accidents, however, and the rate of accidents in schools is increasing. The purpose of this study were to understand the accidents that arise in schools as well as the school safety management system and by analyzing affects that school safety management system has on accidents in schools, to come lip with a preventive plan. 906 high school sophomore students attending in Seoul were surveyed 1Tom November 12th to 23rd 2001. The results were following: 1. Students surveyed comprised of the following: Male 48.9%, Female 51.1% Public Schools 32.6%, Private Schools 67.4% Boys Schools 48.9%, Girls Schools 51.1% 2. In the past year, male students had more accidents(p〈.05) in school. 3. In examining students safety management control, 94.0% said that, there is an infirmary, there is a clear distinction between the playing fields and pathways(74.8%), and the chemicals in the labs are kept in a safe manner(77.2%). The above items were generally well maintained. However, the following recorded low scores. There are warning signs in hazardous places and facilities(30.5%), There is guiding principle to examine the safeness on a regular basis(24.9%), and There are slogans and posters preventing accidents(40.3%). 4. In examining the facilities of the schools that were surveyed, the majority answered, yes to the following. There are hazardous facilities or materials at school(62.9%), There are sharp edges in educational supplies and equipment(59.8%), There are nails or other components that are sticking out of desks and chairs(75.9%), There are slippery spots in the corridors and classrooms(69.3%), There are stones, scrap metal, broken glass, and trash on the playing fields(66.6%). Furthermore, the students surveyed said, yes to the following although in low percentages. The amount of sand on the playing fields is sufficient(49.1%), The soccer and basket goal posts are fastened (53.7%), There are safety bars on the windows of classrooms and corridors (27.4%), There are safety mats on the entrance to restrooms preventing slips (14.2%), The stairs have slip protection measures(49.1%). 5. In analyzing the affect that the school safety management system has on accidents in school, schools that had slogans and posters preventing accidents had a 50% less chance of accidents(p〈.05), schools with chemicals and equipment in the labs that were safely maintained had an 80% less probability of accidents(p〈.0l), and the schools that had sharp edges in the educational supplies and equipment had an 80% greater chance of accidents(p〈.01).

자동차 정비업체 도장공정의 작업환경 및 근로자 노출 실태에 관한 연구 (A Study of Working Environment for Automotive Painting in Auto Repair Shops and Workers' Exposure to Hazardous Chemicals)

  • 심상효;정춘화;임진숙;이형구;김윤신
    • 한국환경보건학회지
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    • 제35권3호
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    • pp.153-161
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    • 2009
  • The purpose of this paper is to evaluate 1) blood lead levels of workers at auto repair shops as Biological Exposure Indices (BEI) of toxic substances such as lead and toluene that are produced during automotive painting process, 2) the differences depending on personal characteristics of workers who have been exposed to toluene by using urine hippuric acid concentration as a marker and 3) the correlation between the concentration of hazardous chemicals in each workplace and the BEL. All subjects were male with a mean age of 36.2 years. In terms of age, most were in the 30 to 40 age group (13 persons, 48.1%). In relation to the length of work experience, the highest proportion had experience of 10 years of less (18 persons, 66.7%). Twenty three workers were cigarette smokers (85.2%) while 4 (14.8%) were non-smokers. In addition, more than 80% of the workers drank alcohol. Dust concentration and toluene exposure during automotive painting showed no significant difference with age, length of work experience, smoking and drinking while a significant difference (p<0.05) has been detected between lead concentration and smoking. The geometric mean of dust concentration, lead concentration and toluene concentration were $0.38mg/m^3,\;0.0021mg/m^3$ and 1.08ppm respectively. In addition, the geometric mean of blood lead levels and urine hippuric acid concentration were $1.70{\mu}g/dl$ and 0.25g/g respectively, which were lower than the standard levels suggested by the Ministry of Labor. To determine the influential factors on blood lead and urine hippuric acid concentrations, a correlation analysis has been conducted with variables of air, lead and toluene concentrations, age, length of work experience and amount of cigarette smoking. According to the analysis, a relatively high correlation (p<0.01) has been observed between air lead concentration and biological sample concentration.

유해화학물질 도급신고 제도가 화학사고 감소에 미치는 영향 연구 (A Study on Contribution to Reducing Chemical Accidents of Reporting for Awarding a Contract of Hazardous Chemicals)

  • 김성범;곽대훈;정성경;김희태;문다희;오준
    • 한국재난정보학회 논문집
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    • 제15권3호
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    • pp.409-417
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    • 2019
  • 연구목적: 화학물질관리법이 시행된 이후 우리나라 화학사고 연도별 발생횟수 자료와 관할기관에 접수처리된 취급자의 도급자료를 활용하여 도급신고 제도 시행 이후 화학사고 감소 기여도 영향을 통계자료로 정리하여 지역별 특성, 월별 특성, 유사 업종별 상관성, 유형별, 인명피해 등을 비교분석하였다. 연구방법: 2015부터 2018년까지 4년 동안의 화학사고 통계자료와 2003년 이후 화학사고 사례와 관련 안전정보를 제공하는 화학안전정보공유시스템(Chemical Safety Clearing-house, CSC)의 자료를 활용하였다. 연구결과 결론: 유해화학물질 취급 공정을 일시 중단하여 작업을 진행하는 기간 동안에 다수의 비숙련 작업자가 작업 현장에 투입되면서 사고 발생의 위험성이 증가한다. 도급신고를 통해 사업자는 비숙련 작업자의 취급자 교육 및 개인 보호장비 착용을 통하여 화학사고 안전관리를 강화할 필요성이 있다.

디아지논 취급 근로자의 건강 위험성 평가 (Health Risk Assessment for Workers Exposed to Diazinon Insecticide)

  • 정우진;김치년;원종욱;김기연;노재훈
    • 한국산업보건학회지
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    • 제22권2호
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    • pp.100-106
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    • 2012
  • Objectives: Diazinon is an insecticide which acts as a contact stomach and respiratory poison, and used throughout the world to control a wide range of sucking and chewing insects and mites on a range of crops. In this study, the airborne diazinon levels were measured for farmers, pest control operaters, landscapers, and agricultural chemicals sellers, and an assessment of the health risk to the workers was presented. The exposure scenario was based on the route of inhalation and skin absorption. The "OSHA Method No. 62" was used to sample and measure the airborne diazinon levels. The skin wipe method was applied to measure the level of the diazinone exposure through the skin. For the determination of exposure scenario, the exposure factors were surveyed for the daily average inhalation rate and the exposure period and frequency and time of diazinone as well as the body weight and lifetime of the workers. The median values of exposure frequency and exposure time were selected after evaluating the validity of those. Methods: The highest level of the diazinon exposure in the air was $107.21ug/m^3$ in farmers, followed by $93.53ug/m^3$ in landscapers, at $31.40ug/m^3$ in pest control operators, and $1.04ug/m^3$ in agricultural chemical seller. The amount of skin absorption was the highest in farmers at 63.39 ug/day, followed by landscapers at 10.47 ng/day, pest control operaters at 4.26 ng/day, and agricultural chemicals sellers at 0.34 ng/day. The hazardous indices calculated using toxicological reference value were 2.79 for pest control operaters, 0.41 for landscapers, 0.07 for agricultural chemicals sellers, and 0.06 for farmers. Conclusions: While the farmers were exposed to the high levels of diazinon through the air and skin, the pest control operaters, landscapers and agricultural chemicals sellers have more the diazinon hazards than the farmer based on the risk assessment in this study.

유해화학물질 대응시스템 적용을 위한 제도 개선 연구 (A Study on Improvement of Legal System for Harmful Chemical Substance Response Management System)

  • 옥영석;이영섭
    • 한국산학기술학회논문지
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    • 제18권4호
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    • pp.216-223
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    • 2017
  • 화학물질은 전 세계적으로 1,500만 여종 이상 상업적으로 이용되고 있을 정도로 현대사회의 필수적인 요소이다. 그러나 이러한 화학물질 중에서 국민의 건강과 환경을 위협하는 위험성을 내포하고 있는 유해화학물질이 상당수 존재한다. 과거 사례를 통해 화학사고가 발생하면 인간의 생명에 얼마나 큰 위험성을 내포하고 있는지 알 수 있다. 화학물질사고의 특성상 짧은 시간에 큰 피해로 확산할 수 있으므로, 사전에 예방하고 사고발생 후에는 즉각적이고 신속한 대응이 매우 중요하다. 이에 국내의 화학물질에 대한 법제도가 2015년 기준으로 "유해화학물질관리법"에서 "화학물질의 등록 및 평가 등에 관한 법률"과 "화학물질관리법"의 체계로 이원화되었다. 그러나 현행법상 화학물질종합정보시스템과 화학물질정보처리시스템의 구축 및 운영을 하고 있지만, 여전히 화학사고는 지속적으로 발생하고 있다. 이러한 시스템은 화학물질사고 대응시스템이라기보다는 화학물질 정보에 그 목적을 둔 종합정보시스템이기에, 실질적인 사고대응에는 한계가 존재한다. 본 연구에서는 유해화학물질의 정보관리체계, 대응관리체계 및 화학물질 관리 지원 근거에 대해 분석하고, 이를 통한 현행 화학물질관리법 등의 개정방향과 지자체별 화학물질대응시스템을 개발 운영할 수 있도록 법제도 개선방안을 제안하고자 한다.