• Title/Summary/Keyword: Hazard material

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The Prediction and Analysis of Bed Changes Characteristics in the Seomjin River Downstream (섬진강 하류의 하상변동 특성 분석 및 예측)

  • Ceon, Ir-Kweon;Kim, Min-Hwan
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.115-121
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    • 2009
  • It is to use effectively for stream channel and watershed management as the prediction and the analysis of bed changes characteristics in the Seomjin river downstream. The necessary data (section, bed composition material, pivot point water elevation, coefficient of roughness) with regard to analysis of the bed changes characteristics were based upon the survey data and analysis results in the Seomjin river maintenance basic plan. The prediction of bed changes was also completed with HEC-6 model. The study results were summarized as follows: The main factor of bed changes in the Seomjin river downstream can be decided by extreme extraction of bed aggregate rather than the change of hydrological data. According to the analysis of bed stability based on the relation between friction velocity and representative grain size, and the relation between dimensionless tractive force and representative grain size, the Seomjin river downstream appears to be increased overall. The bed composition material in the stream channel of the Seomjin river of 2003 year shows higher composition rate of gravel and lower composition rate of sand as compared to those of 1989 year. According to result that the prediction of bed changes, it is estimated that the bed will be risen approximately 1.5 m to the place up to 9 km from the estuary, have been repetitively risen and fallen up to 1 m to the place between $9{\sim}21\;km$ section, and fallen about 0.5m to the place between $22{\sim}25\;km$ section. As a result, the bed of the Seomjin river downstream can be decided to be risen gradually. However, since the prediction of this study is based on the assumption that there will be no forced aggregate picking, the bed changes can be much greater than expected when there is a massive aggregate picking as it had happened before.

Performance of Constructed Facilities: Pavement Structural Evaluation of William P Hobby Airport in Houston, Texas

  • Kim, Sung-Hee;Jeong, Jin-Hoon;Kim, Nak-Seok
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.21-25
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    • 2009
  • The results of a recent case study for material characterizations and structural evaluation to design asphalt overlay thickness of William P Hobby airport in Houston, Texas are presented herein. The existing runway 12R-30L of Hobby airport consisted of thick asphalt overlay over Portland Cement Concrete (PCC) and the localized surface shoving as evident in the closure of surface groove has been observed recently. Using the field cored asphalt concrete mixtures, measurements of percent air voids, asphalt content and aggregate gradation were conducted to find out the causations of surface shoving and groove closure. The FAA layered elastic program, LEDFAA was utilized to evaluate pavement structural conditions for new asphalt overlay. Two different composition assumptions for existing pavement were made to evaluate the pavement as followings: 1) APC, Asphalt Concrete Overlay over PCC pavement and 2) AC, Asphalt Concrete pavement. Based on laboratory testing results, a ratio of percent passing #200 to asphalt content ranged 1.1 to 2.2, which is considered a high ratio and a tendency of tender mix design was observed. Thus, the localized surface shoving and groove closure of the runway 12R-30L could be attributed to the use of excessive fine contents and tender mix design. Based on the structural evaluation results, it was ascertained that the analysis assuming the pavement structure as AC pavement gives more realistic structural life when the asphalt overlay is thicker enough compared to PCC layer because the existing PCC pavement under asphalt overlay acts more like a high quality base material.

A Study on Hazard Classification by Metal Element analysis of Paints Containing Inorganic Pigment (무기안료를 함유한 도료의 금속 원소 분석에 의한 유해성 분류에 관한 연구)

  • Jeong-Hee Han;Do-Hee Lee;Na-Roo Lee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.34 no.3
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    • pp.193-201
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    • 2024
  • Objectives: Paints contain various types of metal substances. However, our review of MSDS (Material Safety Data Sheets) for paints found that their components were often kept secret or exact content information was otherwise not provided. We analyzed the metal elements in various inorganic pigment-based paints available in South Korea in this study and checked whether they contain hazardous metal substances as defined by the Occupational Safety and Health Acts. We investigated issues of health hazard classification related to the metal elements. The study is intended to contribute to strengthening the management of hazardous substances by suggesting improvements to MSDS. Methods: We randomly selected 19 samples that were predicted to contain hazardous inorganic pigments after reviewing MSDS among paints currently in use. The samples were analyzed using XRF (X-ray Fluorescence spectrometry), ICP_OES (Inductively Coupled Plasma-Optical Emission Spectroscopy) and SP-ICP-MS (Single Particle-ICP-Mass Spectroscopy). Results: The most common elements in the samples were Al (aluminum), Fe (iron), Ti (titanium), Ca (calcium), and Si (silica). One sample contained more lead than allowed by the limits. There were ten samples that could potentially contain nanoforms, seven samples that contained titanium dioxide, and six samples that contained complex inorganic color pigments (CICPs). Conclusions: Inorganic pigments in paints should be evaluated for hazards separately from other metallic compounds and reflected in the MSDS because they have different characteristics than other metallic compounds. These include particle size, crystal structure, and complex substances. The results of this study can be helpful for determining whether a paint contains sufficient hazardous metal compounds to affect its classification, and it can be a guideline for improving MSDS through comparative review and rationalization with the manufacturer's MSDS. This would make it possible to contribute to the management of chemical substances in the workplace through the proper MSDS disclosure of paints.

A Study on the Application of the Regulation of the Interior Materials in Entertainment Occupancy (다중이용업소의 내장재 규정의 적용에 관한 연구)

  • 이주헌;윤명오;김운형
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.100-107
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    • 2001
  • A Interior material, a main cause of fire-growth and generating toxic gas when it burns, should be dealt with great care in life safety design. Nonetheless, it has been used recklessly with undue attention to its contribution to fire in particular in entertainment occupancy and causes many victims in fire. Therefore, this study attempts to examine the current use of interior material in Korea and find out what to be improved and enhanced in terms of related regulations. Based on the comparison and analysis of the Korea regulation with those of advanced nations, suggestions are made for an effective and efficient improvement and complement to the current system. What can be suggested from this study are as follows. The use of interior material should be controlled under the unified regulation of fire-safety codes. Code should be set up so that the current construction enforcement should be applied in retroactive to those entertainment buildings that obtained a license prior to the implementation of the system certifying that the building is fire-resistant and fire-protective. The legislation should be made to control the fire-protection facilities of small-sized, underground entertainments. It should be obliged to present the blueprint displaying the use of interior material at the time of changing occupancy. Or, it should be compelled to report changes that go way without permit to the administrative office. A compulsory provision should be set up to have a fire-resistant performance to movable furniture. The classification index designating the fire hazard of interior material by flame spread rate and smoke toxicity and its test method should be established.

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A Study of MSDS Reliability Evaluation in Chemicals including Formaldehyde (포름알데히드 함유 화학제품의 MSDS 신뢰성 평가 연구)

  • Hong, Mun Ki;Song, Se Wook;Lee, Kwon Seob;Choi, Sung Bong;Lee, Jong Han
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.3
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    • pp.287-298
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    • 2013
  • Objectives: Workers who use chemicals are exposed to safety accidents and occupational diseases. Employers are required to provide workers with Material Safety Data Sheets (MSDSs) in order to prevent accidents and diseases related to chemicals. Thus, it is very important to offer reliable MSDSs. In this paper, we assessed the reliability of MSDSs for chemicals including formaldehyde. Methods: To evaluate MSDS reliability, we collected 14 MSDSs and bulk samples from the chemical industry. MSDS reliability was evaluated by the completeness of details. In order to evaluate the adequacy of the formaldehyde contents in a mixture, bulk samples were collected and analyzed by HPLC. The result of Globally Harmonized System (GHS) classification was confirmed by identifying physical chemical properties, toxicology information and ecological information. Results: The result of the evaluation of 14 MSDSs showed 76.29% average reliability on each item, especially 53.9% average appropriate rate on hazard risk classification. No chemicals failed to match between the content (%) in MSDSs and the result of analysis. Conclusions: To elevate MSDSs reliability, the certified education of MSDS drafters and reorganization of the MSDS circulation system is required.

Temperature effect on seismic performance of CBFs equipped with SMA braces

  • Qiu, Canxing;Zhao, Xingnan
    • Smart Structures and Systems
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    • v.22 no.5
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    • pp.495-508
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    • 2018
  • Shape memory alloys (SMAs) exhibit superelasticity given the ambient temperature is above the austenite finish temperature threshold, the magnitude of which significantly depends on the metal ingredients though. For the monocrystalline CuAlBe SMAs, their superelasticity was found being maintained even when the ambient temperature is down to $-40^{\circ}C$. Thus this makes such SMAs particularly favorable for outdoor seismic applications, such as the framed structures located in cold regions with substantial temperature oscillation. Due to the thermo-mechanical coupling mechanism, the hysteretic properties of SMAs vary with temperature change, primarily including altered material strength and different damping. Thus, this study adopted the monocrystalline CuAlBe SMAs as the kernel component of the SMA braces. To quantify the seismic response characteristics at various temperatures, a wide temperature range from -40 to $40^{\circ}C$ are considered. The middle temperature, $0^{\circ}C$, is artificially selected to be the reference temperature in the performance comparisons, as well the corresponding material properties are used in the seismic design procedure. Both single-degree-of-freedom systems and a six-story braced frame were numerically analyzed by subjecting them to a suite of earthquake ground motions corresponding to the design basis hazard level. To the frame structures, the analytical results show that temperature variation generates minor influence on deformation and energy demands, whereas low temperatures help to reduce acceleration demands. Further, attributed to the excellent superelasticity of the monocrystalline CuAlBe SMAs, the frames successfully maintain recentering capability without leaving residual deformation upon considered earthquakes, even when the temperature is down to $-40^{\circ}C$.

Releasing of asbestos fibers from the weathered asbestos cement slate roofing (슬레이트 지붕 노후화에 따른 석면 섬유 방출량)

  • Kim, Hyun-Wook;Park, Gye-Young;Han, Jin-Gu;Han, Young-Sun;Hwang, Bum-Gu;Lee, Jun-Hyuk
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.20 no.2
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    • pp.88-93
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    • 2010
  • To confirm and quantify asbestos fibers released from the asbestos-cement slate roofs due to weathering, three houses, selected based on the year of built - 60's, 70, and 80's, were investigated. All of them were located in the downtown of Seoul. Rain or snow-melt water was collected from the roof in a 3.5 liter plastic bottle. A known amount of collected water was filtered on the 37 mm membrane filter, ashed in a muffle furnace, and subsequently treated with HCl to remove organic material. The treated remaining was refiltered on a 25mm membrane filter for PLM and PCM analyses. The NIOSH 7400 method was utilized for PCM counting. In addition, SEM/EDX was used to confirm the asbestos types. The results of this study showed that chrysotile fibers were confirmed by PLM in all samples analyzed. A significant amount of asbestos fibers were found in the water samples. The ranges of asbestos fibers counted from the samples collected in the 60's, 70's, and 80's were; 10,406.3~55,575.6 f/L, 5,218.8~38,126.2 f/L, and 2,906.3~7,798.6 f/L, respectively. As anticipated, concentrations of asbestos fibers increased with time of installment of the roofing material. We conclude that weathering can be a significant factor on the release of asbestos fibers from the asbestos cement products. Since asbestos fibers released into environment can be a source of significant health hazard, countermeasures, such as replacement, removal, and encapsulation of weathered asbestos slate, should be initiated immediately.

Hazard Evaluation of Runaway Reaction in Deboronation Process Using H2O2 in DIET Synthesis of Pharmaceutical Raw Material (의약품 원료 DIET 합성 중 H2O2를 이용한 붕소제거 반응공정에서의 폭주반응 위험성 평가)

  • Kim, Won Sung;Lee, Keun Won
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.49-54
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    • 2018
  • In the Active Pharmaceutical Ingredient(API) manufacturing company, since the product is produced by the chemical reaction, fire and explosion are frequently occurred in the process of inputting the raw powder as the chemical reaction stage. There are not many studies on safety measures through analysis of cause of accident in the actual chemical reaction stage. In this study, we investigated the heat flow in the boron removal reaction process to investigate the risk in the chemical reaction stage. The study reaction process was performed by using the reaction calorimeter for the products synthesized at the actual raw material in pharmaceutical factory. The risk was estimated by comparing the maximum temperature of the synthesis reaction, which can generate heat due to the failure of cooling in the actual manufacturing process, and the technical temperature. These results are applied to commercial manufacturing sites and safety measures to control the risk of runaway reaction due to reaction heat are suggested.

A Study on Combustion Experiments of Color Nonwoven (칼라 부직포의 연소실험에 관한 연구)

  • Min, Se-Hong;Im, Sang-Bum
    • Fire Science and Engineering
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    • v.25 no.3
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    • pp.99-106
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    • 2011
  • Experiments of Cone calorimeter test and Lift spread flame apparatus test are carried out in order to appraise fire hazard in color nonwoven used mostly on the spot in construction works. As the result, in color nonwoven combustibility is discovered not firing flame in surface, but firing under state of combustible gas occuring in the state of melting. In the case of Lift spread flame apparatus test, color nonwoven is very brittle which almost no flame spread owing to contracting and break by firing strength. The following data are agree with basis: total heat release is 2.66 MJ/$m^2$, limited combustible material (10 min) of incombustible rating appraisal in interior material of building, and incombustible materials (5 min) 8 MJ/$m^2$ in spite of the above data mentioned, those data are only as basis of interior finish, and so I cannot judge color nonwoven have incombustible rating retain through the above data. Accordingly, the basis of incombustible rating and experiment method about exterior finish must be arranged also.

An Experimental Study on the Development of Fire-retardant Treated Wood for Construction (건축용 난연 목재 개발에 대한 실험 연구)

  • Seo, Hyun Jeong;Kim, Nam Kyun;Jo, Jeong Min;Lee, Min Chul
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.149-156
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    • 2017
  • This study investigates fire-retardant performances and combustion/thermal characteristics of fire-retardant treated wood by comparing them with those of fire-retardant untreated wood from the expreimental resutls of cone calorimeter and thermo-gravimetric(TG) analyzer. Hazardousness of combustion product gases for fire-retardant treated wood and untreasted wood were also observed from the results of internal finish material incombustibility test according to the Korea standard code of KS F 2271. In this study, we also tried to improve the fire retardant performance of wood by applying fire-retardant chemical composites, and to secure the fire safety performance in buildings. Red pine (Pinus densiflora) was selected as a test specimen because it is mostly used as a building material in Korea. Fire retardant chemical composites (FRCs) were prepared by mixing boron, phosphorous, and nitrogen species and treated by press-impregnation method. Water-based FRCs were composed of 3% boric acid($H_3BO_3$), 3% borax decahydrate($Na_2B_4O_7$), 8% ammonium carbonate($(NH_4)_2CO_3$), diammonium phosphate ($(NH_4)_2HPO_4$) varied from 10-30% and potassium carbonate($K_2CO_3$) varied from 10-30%. From the test results of cone calorimeter, TG analysis and gas hazard assessments, newly proposed were the optimal composition and production methods of FRCs which can sufficiently meet fire-retardant level 3 based on Korea law of construction. Thus, the FRCs, developed in this study, are anticipated to contribute to the improvement of fire safety and widespread of usage in wood as building materials.