• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.21 no.2
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• pp.103-109
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• 2011

Object: we investigated some factors which can affect workers' comprehension of chemical hazard information and their actions to protect themselves from the hazard. Method: Comprehension score of chemical hazard information and the rate of wearing personal protective equipment (PPE) was surveyed for the 109 workers from 15 factories who were exposed to N, N-dimethylformamide. Difference of the worker's comprehension score of hazard information was analyzed by education interval, work duration and the way of occupational safety and health management between self-managed or sub-contracted. Result: Mean comprehension score of N, N-dimethylformamide hazard, which was given as a short quiz composed of 10 "true" or "false" problems, was 65%. Mean percentage of wearing PPE was improved as the education program was done within a month but decreased after 6 months. Eighty seven % of workers got the chemical hazard information from the material safety data sheet placed at workplace. Conclusion: Education interval and comprehension score affected the rate of wearing PPE. The way of occupational safety and health management self-managed or sub-contracted did not affect the workers' comprehension score on hazard information nor the rate of wearing PPE.

• Journal of Applied Biological Chemistry
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• v.49 no.3
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• pp.101-105
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• 2006

Degradation of the herbicide butachlor was investigated using laboratory-synthesized zerovalent iron ($Fe^0$). The synthesized zerovalent iron was determined to be nanoscale powder by scanning electron microscopic analysis. To investigate degradation of butachlor using the synthesized nanoscale zerovalent iron, time-course batch experiments were conducted by treating the solution of butachlor formulation with the iron. More than 90% degradation of butachlor was observed by iron treatment within 24 h. The synthesized nanoscale zerovalent iron showed an increase in particle aggregation in the batch tests. Green rust formation and a pH drop in solutions were observed, suggesting that the oxidation of the iron occurred. When the iron was extracted with dichloromethane, a negligible concentration was found in the extract, suggesting that butachlor did not bind to the iron particles. GC/MS analysis detected the dechlorinated product as a major degradation product of butachlor in the solutions. The data indicate that laboratory-synthesized zerovalent iron functioned as a reductant to remove electron-withdrawing chlorine, giving the dechlorinated product.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.25 no.4
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• pp.506-515
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• 2015

Objectives: This study was conducted to evaluate the status of hazard communication regarding dental materials among dental hygienists in the Daegu Metropolitan City and the North Gyeongsang-do Province area. Materials: A total of 310 dental hygienists were surveyed using self-administered questionnaires to investigate the status of hazard communication on dental materials and information needs. We collected instructions for use and material safety data sheets(MSDSs) for 67 dental materials frequently used at dental hospitals located in the Daegu Metropolitan City and the North Gyeongsang-do Province area. Results: The questionnaire surveys showed that only 11% of the 310 dental hygienists had knowledge of MSDS and 46.8% of respondents never read instructions for use before using materials. Just 7.4% of dental hygienists have undergone training on hazard information for dental materials. In particular, dental hygienists working at dental clinics had significantly lower response rates on knowledge of MSDS(p<0.001), reading of instructions for use(p=0.042) and training on the hazard information of dental materials(p=0.004) than those in dental hospitals or general hospitals. The essential information most desired by dental hygienists was hazard identification(82.3%) followed by first-aid measures(53.9%), handling and storage(51%), disposal considerations (49%) and toxicological information(47.1%). All dental materials were on foreign products which came from Japan(59.7%), the USA(26.9%) and Liechtenstein(13.7%). In terms of usage, 56.7% of dental materials were prosthetic, followed by conservation(31.3%), orthodontics(9%), and prevention(3%). We found that dental hygienists had accessed MSDSs for only five dental products among the 67 dental materials. The instructions for the use of the 67 dental materials provided hazard identification(64.2%), first-aid measures(83.6%), handling and storage(97%), disposal considerations(20.9%) and toxicological information(26.9%). Conclusions: Based on the results of this study, the hazard communication system for dental hygienists working at dental clinics should be improved.

• Journal of Korean Society for Quality Management
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• v.31 no.4
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• pp.226-238
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• 2003

Recently, The problems with which our country's company is confronted for business of manufacturing goods. This study set the hypothesis to develop the method that was analysis and application of A reliability evaluation method of environmental material for circuit components in Computer, Color TV, Monitor, Microwave oven, Electric Refrigerator, Automobile parts, other goods. Especially, this study emphasis on regulate export of the EU and North America that it's a environmental material's hazards problem. In this process, this study set the pattern of practical application. Therefore, this study emphasis on the application of A reliability evaluation method of environmental material and the use of other parameters by environmental reliability test data. The result of this study is as follows. 1) There is relationship between regulate material and technical protecting system. 2) Characteristics of hazard materials is operating a healthcare damage factor as well as regulate environmental factors.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.384-391
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• 1997

The hazard assessment in which the potential hazard factors In the buildings are investigated and the scale of the hazard is analyzed should be performed first in order to prevent personal and material damages due to building fire. In this study, the building fire hazard are assessed using 822-item checklist, for the qualitative evaluation of which the main factors are classified into 10 items, yielding 100 scale points with some weighting. It is shown that present model is applicable for the assessment of all general buildings through the examination of the suitability of assessment model by actual assessment of existing building. Also, the checklist is prepared in itemized questionnaire form for easy assessment of building fire hazard. Therefore, the present model will be helpful for those working in fire prevention, who are suffering from the lack of manifest evaluation model for the fire prevention assessment so far in Korea.

• International conference on construction engineering and project management
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• 2005.10a
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• pp.1048-1052
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• 2005

In Korean cases, the occupation of building construction is below 10% of the total industry workers but from a accident rate point of view, it is a risk serious industry and it's hazard is very considerable which accident rate is up to 30% of the total industry workers. The reason of high accident rate of the building construction is its own characteristic, hazard of the work in which is implicated and the shortage of safety counter plan and information, so it is most required to the building construction that educating, training, short and long period approaching to prevent the hazard. The safety information of building construction which is related to safety accident is divided into human and material such as hazard, work situation, cause and counter plan. The existing hazard cases imply all of the information about the work type and work progress of the building construction, so if the research of the every fact is well accomplished, we can obtain the useful information and prevent the hazard of building construction. From this point of view, the emphasis of this study is based on analyzing the cause of hazard first, suggesting the safety information each part of work type and work progress second, and finally making the all existing hazard cases to the Data Base and developing the safety information system.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.30 no.3
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• pp.280-291
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• 2020

Objectives: Hazard classification is a controversial issue in the new MSDS system in which chemical companies have to prepare and submit MSDS for chemicals that they manufacture or import to the competent authorities according to the amended Occupational Safety and Health Act. The aim of this study is to suggest how to apply and manage harmonized hazard classification criteria and results by investigating current hazard classification systems and trends. Methods: The domestic issues about different hazard classification criteria and results were investigated by reviewing the literature and business outcomes regarding KOSHA. We also checked official and unofficial reports from the UN to understand international discussion about the topic. Chemical hazard classification results from agencies providing chemical information were analyzed to compare a harmonized rate between classifications. Furthermore, a field survey of a few chemical companies was conducted. Results: Under the related competent authorities, an integrated standard proposal was developed to harmonize the domestic hazard classification criteria. Although harmonized chemical information is strongly needed, we recognized the uncertainty and difficulty of harmonized hazard classification from the UN global list project review. In practice the harmonization rate of the classification was generally low between the classification in KOSHA, MoE, and EU CLP. Among hazard classes, health hazards largely led the disharmony. The field survey revealed a change of perception that the main body of chemical information production is manufacturers. Approaches and solutions about hazard classification issues differed depending on business size, types of chemical handling, and other factors. Conclusions: We proposed reasonable ways by time and step to apply hazard classification in the new MSDS system. Chemical manufacturers should make and offer chemical information including responsible hazard classifications. The government should primarily accept these classifications, evaluate them by priority, and support or supervise workplaces in order to communicate reliable chemical information.

• 제어로봇시스템학회:학술대회논문집
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• 1992.10b
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• pp.430-435
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• 1992

Hazard identification is one of the most important task in process design and operation. This work has focused on the development of a knowledge-based expert system for HAZOP (Hazard and Operability) studies which are regarded as one of the most systematic and logical qualitative hazard identification methodologies but which require a multidisciplinary team and demand much time-consuming, repetitious work. The developed system enables design engineers to implement existing checklists and past experiences for safe design. It will increase efficiency of hazard identification and be suitable for educational purposes. This system has a frame-based knowledge structure for equipment failures/process material properties and rule networks for consequence reasoning which uses both forward and backward chaining. To include wide process knowledge, it is open-ended and modular for future expansion. An application to LPG storage and fractionation system shows the efficiency and reliability of the developed system.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.252-259
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• 1997

A method to automate hazard analysis of chemical plants is proposed in this paper. The proposed system is composed of three knowledge bases - unit knowledge base, organizational knowledge base and material knowledge base, and three hazard analysis algorithms - deviation, malfunction and accident analysis algorithm. Hazard analysis inference procedure is developed based on the actual hazard analysis procedures and accident development sequence. The proposed algorithm can perform hazard analysis in two methods and represent all conceivable types of accidents using accident analysis algorithm. In addition, it provides intermediate steps in the accident propagation, and enables the analysis result to give a useful information to hazard assessment. The proposed method is successfully demonstrated by being applied to diammonium phosphate manufacturing process. A system to automate hazard analysis is developed by using the suggested method. The developed system is expected to be useful in finding the propagation path of a fault or the cause of a malfunction as it is capable to approach causes of faults and malfunctions simultaneously.

• Journal of the Korean Society of Hazard Mitigation
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• v.4 no.2 s.13
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• pp.35-45
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• 2004

Recently, the composite material becomes more popular and its usage is kept expanding from aerospace to civil structures such as bridge decks and irrigation and drainage pipes. The major cause for the popularity can be found in its high strength, light, and excellent anticorrosive properties. Nevertheless the methods to accurately predict and analyze its structural behavior are extremely limited. This has been the major reason circumventing more prevalent use of the composite materials in civil structures. This study is a pre-study to develop the analyzing models for accurate prediction of the composite material structures. Thus, various tests were performed for GFRP pipes to estimate material characteristics of GFRP in this study. And stress-strain relation of GFRP was suggested as a bilinear relation.