• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1443-1454
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• 2011

Methods to prepare novel second-order nonlinear optical (2O-NLO) materials composed of all-silica zeolite (silicalite-1) and a series of 2O-NLO molecules having high second order hyperpolarizability constants (${\beta}$ values) are reviewed. These methods include the development of novel methods to incorporate a series of hemicyanine (HC) molecules into the channels of silicaite-1 films in uniform orientations. The first method is to incorporate HC molecules tethered with long alkyl chains (octadecyl or longer) into the silicalite-1 channels with the long alkyl chain side first through the hydrophobic-hydrophobic interaction between the long alky chains and the silicalite-1 channels. The second method is to incorporate the HC molecule tethered with a medium length alkyl chain (nonyl) into the silicalite-1 channels with the medium length alkyl chain side first through hydrophobic-hydrophobic interaction between the medium length alky chain in the photoexcited state and the silicalite-1 channels. The third method is to incorporate the HC molecule tethered with propionic acid into the silicalite-1 channels with the propionic acid side last mediated by a tetrabultylammonium cation ion-paired to the propionate unit. A method to prepare a novel third-order nonlinear optical (3O-NLO) material composed of zeolite-Y and PbS or PbSe quantum dots is also reviewed. This Account thus describes a promising new direction to which the search for highly sensitive 2O-NLO and 3O-NLO materials has to be conducted and a new direction to which zeolite research and applications have to be expanded.

• Journal of the Institute of Electronics and Information Engineers
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• v.53 no.7
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• pp.121-127
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• 2016

We propose a algorithm to calculate power factor of fundamental waveform in an environment where the voltage and current have been distorted by harmonics. In the proposed power factor computation algorithm, voltage and current are converted to rotating DQ reference frame, and power factor is calculated from active power and reactive power. We compare the proposed method with the conventional power factor measurement method as mathematically. In a condition that voltage and current are distorted by harmonics, the proposed method accurately measure the power factor of fundamental wave, and it is confirmed by simulation using MATLAB. If the proposed power factor measurement method is applied to an automatic power factor control system, a power factor compensation performance can be maximized in harmonic distortion environment. As a result, it is possible to reduce electricity prices, reduce line loss, increase load capacity, ensure the transmission margin capacity, and reduce the amount of power generation.

• Journal of the Korean Ceramic Society
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• v.45 no.9
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• pp.524-530
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• 2008

Anti-Reflective (AR) thin film coatings of $SiO_2$ (n= 1.48) and $TiO_2$ (n=2.17) were deposited by ion-beam assisted deposition (IBAD) with End-Hall ion source and conventional electron beam (e-beam) evaporation to investigate the effect of deposition method on the refractive indicies (n) of the fIlms. Green-light generation using a GaAs laser diode was achieved via excitation of the second harmonic. The latter resulted from the transmission of the fundamental guided-mode wave of 1064 nm through periodically poled $LiNbO_3$. Large differences in the refractive indicies of each of the layers in the multilayer coating may improve AR performance. IBAD of $SiO_2$ reduced its refractive index from 1.45 to 1.34 at 1064 nm. Conversely, e-beam evaporation of $TiO_2$ increased its refractive index from 1.80 to 2.11. In addition, no fluctuations in absorption at the wavelength of 1064 nm were found. The results suggest that films prepared by different deposition methods can increase the effectiveness of multilayer AR coatings.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.5
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• pp.214-217
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• 2011

A fresnoite glass-ceramics has been investigating considerably because of the second order nonlinearity as well as its permanent optical nonlinearity. However, the chemical compositions of transparent glass-ceramics examined in the previous studies have been limited to adjust the composition close to fresnoite stoichiometrically. In this study, to investigate the effect of strontium ions in glass-ceramics on second order nonlinearity, $K_2O-TiO_2-SiO_2$ (KTS) glasses soaked in molten $Sr(NO_3)_2$ were prepared. Crystalline phases of the soaked glasses were measured by X-ray diffraction (XRD) as soaking times and additional heat treatment. The exchange of strontium ions into the glass was verified by Field Emission Scanning Electron Microscope (FE-SEM). And the phenomena of second order harmonic generation (SHG) was observed using Nd-YAG laser.

• Smart Structures and Systems
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• v.19 no.6
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• pp.665-678
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• 2017

In this paper the tuned mass-damper-inerter (TMDI) is considered for passive vibration control and energy harvesting in harmonically excited structures. The TMDI couples the classical tuned mass-damper (TMD) with a grounded inerter: a two-terminal linear device resisting the relative acceleration of its terminals by a constant of proportionality termed inertance. In this manner, the TMD is endowed with additional inertia, beyond the one offered by the attached mass, without any substantial increase to the overall weight. Closed-form analytical expressions for optimal TMDI parameters, stiffness and damping, given attached mass and inertance are derived by application of Den Hartog's tuning approach to suppress the response amplitude of force and base-acceleration excited single-degree-of-freedom structures. It is analytically shown that the TMDI is more effective from a same mass/weight TMD to suppress vibrations close to the natural frequency of the uncontrolled structure, while it is more robust to detuning effects. Moreover, it is shown that the mass amplification effect of the inerter achieves significant weight reduction for a target/predefined level of vibration suppression in a performance-based oriented design approach compared to the classical TMD. Lastly, the potential of using the TMDI for energy harvesting is explored by substituting the dissipative damper with an electromagnetic motor and assuming that the inertance can vary through the use of a flywheel-based inerter device. It is analytically shown that by reducing the inertance, treated as a mass/inertia-related design parameter not considered in conventional TMD-based energy harvesters, the available power for electric generation increases for fixed attached mass/weight, electromechanical damping, and stiffness properties.

• Magazine of the Korean Society of Agricultural Engineers
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• v.35 no.3
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• pp.100-116
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• 1993

It is experienced fact that unreasonable design criterion and unsitable operation management for the agricultural structures including reservoirs based on short terms data of monthly flows have been brought about not only loss of lives, but also enormous property damage. For the solution of this point at issue, this study was conducted to simulate long series of synthetic monthly flows by multi-season first order Markov model with selection of best fitting frequency distribution and to make a comparison of statistical parameters between observed and synthetic flows of six watersheds in Yeong San and Seom Jin river systems. The results obtained through this study can be summarized as follows. 1.Both Gamma and two parameter lognormal distribution were found to be suitable ones for monthly flows in all watersheds by Kolmogorov-Smirnov test while those distributions were judged to be unfitness in Nam Pyeong of Yeong San and Song Jeong and Ab Rog watersheds of Seom Jin river systems in the $\chi$$^2$ goodness of fit test. 2.Most of the arithmetic mean values for synthetic monthly flows simulated by Gamma distribution are much closer to the results of the observed data than those of two parameter lognomal distribution in the applied watersheds. 3.Fluctuation for the coefficient of variation derived by Gamma distribution was shown in general as better agreement with the results of the observed data than that of two parameter lognormal distribution in the applied watersheds both in Yeong San and Seom Jin river systems. Especially, coefficients of variation calculated by Gamma distribution are seemed to be much closer to those of the observed data during July and August. 4.It can be concluded that synthetic monthly flows simulated by Gamma distribution are seemed to be much closer to the observed data than those by two parameter lognormal distribution in the applied watersheds. 5.It is to be desired that multi-season first order Markov model based on Gamma distribution which is confirmed as a good fitting one in this study would be compared with Harmonic synthetic model as a continuation follows.

• The Transactions of the Korean Institute of Power Electronics
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• v.8 no.2
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• pp.99-106
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• 2003

This paper presents a novel multilevel PWM inverter employing series-connected transformers in order to improve the waveshape of output voltage and to reduce its harmonics. The proposed 11-level inverter consists of three full-bridge inverter modules and their corresponding transformers. Among their inverter modules, one is used as PWM operation and the others as level generation. From a suitable selection of turns ratio of transformer, continuous output voltage levels were generated appearing an integral ratio to input DC source. Because of their series connection of transformers, output filter inductor is not necessary. The operational principles and analysis are explained, and it is compared with a conventional multilevel PWM inverter. The validity of the proposed system Is verified through the experimental results using a prototype.

• Polymer(Korea)
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• v.25 no.6
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• pp.803-810
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• 2001

A nonlinear optical hyperbranched polyester (PE-Azo/Hyper) was synthesized from 4-[N,N-bis(hydroxyethyl)amino-4'-formyl] azobenzene and cyanoacetic acid by a Knoevenagel polycondensation using 4-(dimethylamino) pyridine as a base. The resulting polymer was soluble in polar aprotic solvents such as N,N-dimethylformamide and 1-methyl-2-pyrrolidinone and could be processed into optical quality films by spin coating. The molecular weight was determined to be $M_w$=61,800 ($M_W/M_n{=1.86}$) by gel permeation chromatography using polystyrene as a standard. No melting point was detected by differential scanning Calorimeter, indicating that this polymer presents an amorphous state. It shows a glass transition temperature of $121^{\circ}C$. The second-order nonlinear optical coefficient $d_{33}$ of the poled polymer determined by the second harmonic generation at 1064 nm was 25.4 pm/V.

• Journal of IKEEE
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• v.21 no.2
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• pp.105-114
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• 2017

This paper proposes a design method of an LCL-filter for grid-tied three-level inverter systems. The demand for three-phase PWM inverters in applications such as wind or solar power generation systems has been increase in recent years. To reduce harmonic components caused by switching operation, such inverters are connected to the grid via an LCL filter. Although there are research results for designing LCL-filter, the modulation method should be fully considered to make the filter perform desired cancellation ability with minimized size. This paper presents the design methodology for an LCL-filter that is optimized for SVM switching operations. The simulation and experimental results verify the validity of the LCL-filter designed with proposed method in this paper.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2241-2247
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• 2007

A new series of chiral bent-shaped liquid crystals with an asymmetric central core based on 1,6- dihydroxynaphthalene and chiral terminal chain prepared from (S)-(?)-2-methyl-1-butanol, 1,6-naphthalene bis[4-(4-alkoxyphenyliminomethyl)]benzoates [N(1,6)-n-O-PIMB(n-2)*-(n-4)O (n = 8-11)] were synthesized. Their mesomorphic properties and phase structures were investigated by means of electro-optical, polarization reversal current, and second harmonic generation measurements in order to confirm the relationship between the molecular structure and phase structure. All odd n (n = 9 and 11) compounds, N(1,6)-9-O-PIMB7*-5O and N(1,6)-11-O-PIMB9*-7O exhibit antiferroelectric phase, whereas even n (n = 8 and 10) compounds was flexible, N(1,6)-10-O-PIMB8*-6O exhibits the ferroelectric phase but N(1,6)-8-O-PIMB6*-4O exhibits the antiferroelectric phase. These results come from the decrease of the closed packing efficiency within a layer and the lack of uniform interlayer interaction between adjacent layers, which were caused by the asymmetrical naphthalene central core. Thus, we concluded that the structure of central core as well as the terminal chain plays an important role for the emergence of particular polar ordering in phase structures.