• 제목/요약/키워드: Hap

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Amonia-Borane에서의 이종상 촉매인 Ru-HAP, Co-HAP를 이용한 수소 발생

  • 김영용;권기영
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.194-194
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    • 2011
  • 지구상에서 화석 연료에 기초한 에너지가 고갈되어 가고 있는 지금, 여러 가지 대체 에너지들이 주목 받고 있는데 그 중에서도 수소는 친환경적 에너지원으로서 최근 많은 연구가 진행중이다. 여러 가지 저 분자 중에서 보레인은 수소 질량비가 큰 물질 중의 하나로서 이를 이용하면 적은 무게에 비하여 다른 유사한 질량의 분자들 보다 많은 수소를 발생할 수 있다. 그래서 우리는 이에 착안하여 촉매를 이용한 수소 발생 실험을 구상하게 되었다. Ru과 Co를 수산화인회석에 도입하여 우리는 이종상 촉매인 Ru-HAP와 Co-HAP를 만들었다. 이를 TEM을 이용하여 시료상의 이온교환 전후의 상을 관찰 하였고 SEM을 이용하여 촉매 표면 상의 붕소유리를 관찰 하였다. 높은 온도와 압력일수록 HAP에 더 많이 표면에 Ru과 Co가 흡착됨을 ICP를 통해서 알 수 있었다.

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PMMA를 결합제로 한 수산화아파타이트 성형체의 제조 (Fabrication of Hydroxyapatite Compacts with Polymethyl Methacrylate)

  • 류수착;윤수종
    • 한국재료학회지
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    • 제16권4호
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    • pp.272-275
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    • 2006
  • In order to evaluate the possibility of Polymethyl methacrylate (PMMA) as a binder on hydroxyapatite (HAp) which has good biocompatibility, the properties of HAp compacts with PMMA were examined. When adding 50 wt% of PMMA on HAp and pressed, the compression strength and the hardness of the compacting body were 168MPa and 55 Hv, respectively, and the strength of compacts was higher than that of cortical bone and the hardness was similar to the value of molar. We demonstrated that HAp ceramics can be obtained without additional heat treatment and machining of the ceramic was feasible. Therefore, the HAp compacts have potential to apply to implant or artificial bone after the clinical trials guarantees biocompatibility of it.

생체활성 유리 골 시멘트의 응결 및 수산화 아파타이트 형성 (Setting and Hydroxyapatite Formation of Bioactive Glass Bone Cement)

  • 임형봉;김철영
    • 한국세라믹학회지
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    • 제42권11호
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    • pp.770-776
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    • 2005
  • Hardening and hydroxyapatite(HAp) formation behavior of the bioactive cements in the system of $CaO-SiO_{2}-P_{2}O_{5}$ glasses and the corresponding glass-ceramics were studied. DCPD (Dicalcium Phosphate Dihydrate: $CaHPO_4{\cdot}2H_2O$) and DCPA (Dicalcium Phosphate Anhydrous: $CaHPO_4$) were developed when the prepared glass and glass-ceramic powders were mixed with three different solutions. The DCPD and DCPA transformed to HAp when the cement was soaked in Simulated Body Fluid (SBF), and this HAp formation strongly depended on the releasing capacity of $Ca^{2+}$ ions from the cements. The glass-ceramic containing apatite showed fast setting, but no HAp formation was observed because no $Ca^{2+}$ ions were released from this glass-ceramics. The compressive strength of the cements increased with reaction time in SBF until all DCPD and DCPA transformed to HAp.

High-frequency Induction Heating Sintering of Hydroxyapatite-($ZrO_2+3%Mol\;Y_2O_3$) Bioceramics

  • Khalil, Khalil Abdel-razek;Kim, Sug-Won
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.924-925
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    • 2006
  • In this study, hydroxyapatite (HAp) and hydroxyapatite-yttria stabilized zirconia (HAp-3YSZ) with 20 vol.%-($ZrO_2+3%mol\;Y_2O_3$) nanopowders were consolidated very rapidly to full density by High-frequency induction heat sintering (HFIHS). Effects of temperature and the addition of 3YSZ on the toughness, hardness and microstructure properties have been studied. 3YSZ second phase toughening HAp composites with higher toughness were successfully developed at relatively low temperatures through this technique. Compared with hardness and toughness obtained for pure HAp, the hardness and toughness for HAp-20vol. % 3YSZ were much higher.

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Morphology Changes of E. coli in Ag-HAp Observed by TEM

  • Kim, T.N.;Feng, Q.L.;Kim, Y.J.;Yim, H.J.;Lim, D.Y.;Hwang, D.S.;Kim, J.W.;Cui, F.Z.
    • 한국진공학회지
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    • 제7권s1호
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    • pp.44-49
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    • 1998
  • The antimicrobial effects of HAp and Ag-HAp was observed using periprosthetic infection bacteria such as Pseudomonas Aeruginosa, Staphylococcus Epidermidis, Escherichia coli (DH5$\alpha$). Ag-HAp showed good antimicrobial effects. TEM study of E. coli with and without Ag treatment in HAp was experimented in order to find the mechanism of Ag in antimicrobial effects. It was observed that the shape of Ag-treated E. coli was changed, the cells walls became inhomogeneous. The vaculoes at cytoplasm formed into E. coli and finally it was discovered by EDAX that there were many dark granules which contain the Ag element inside the cells.

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수산화인회석이 충전된 고분자 복합체의 치과적 물성 (Dental Properties of Hydroxyapatite Filled Polymer Composite)

  • 서기택;윤진구;김주환;김오영
    • 응용화학
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    • 제9권2호
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    • pp.25-28
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    • 2005
  • To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

Hydroxyapatite-Zirconia Composite Thin Films Showing Improved Mechanical Properties and Bioactivity

  • Kim, Min-Seok;Ryu, Jae-Jun;Sung, Yun-Mo
    • 한국재료학회지
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    • 제19권2호
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    • pp.85-89
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    • 2009
  • Nano-crystalline hydroxyapatite (HAp) films were formed at the Ti surface by a single-step microarc oxidation (MAO), and HAp-zirconia composite (HZC) films were obtained by subsequent chemical vapor deposition (CVD) of zirconia onto the HAp. Through the CVD process, zero- and one-dimensional zirconia nanostructures having tetragonal crystallinity (t-ZrO2) were uniformly distributed and well incorporated into the HAp crystal matrix to form nanoscale composites. In particular, (t-$ZrO_2$) was synthesized at a very low temperature. The HZC films did not show secondary phases such as tricalcium phosphate (TCP) and tetracalcium phosphate (TTCP) at relatively high temperatures. The most likely mechanism for the formation of the t-$ZrO_2$ and the pure HAp at the low processing temperature was proposed to be the diffusion of $Ca^{2+}$ ions. The HZC films showed increasing micro-Vickers hardness values with increases in the t-$ZrO_2$ content. The morphological features and phase compositions of the HZC films showed strong dependence on the time and temperature of the CVD process. Furthermore, they showed enhanced cell proliferation compared to the $TiO_2$ and HAp films most likely due to the surface structure change.

HAP 네트워크에서 BIRCH 클러스터링 알고리즘을 이용한 이동 기지국의 배치 (Mobile Base Station Placement with BIRCH Clustering Algorithm for HAP Network)

  • 채준병;송하윤
    • 한국정보과학회논문지:컴퓨팅의 실제 및 레터
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    • 제15권10호
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    • pp.761-765
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    • 2009
  • 본 연구는 HAP(High Altitude Platform) 기반 네트워크 구성에서 최적의 이동 기지국의 위치와 적용범위를 찾는 것을 목적으로 한다. 이를 위하여 지상 노드들을 BIRCH(Balanced Iterative Reducing and Clustering Using Hierarchies) 알고리즘을 응용하여 클러스터링(Clustering) 하였다. BIRCH 알고리즘의 특징인 계층적 구조를 통해 CF(Clustering-Feature) 트리를 만들어 모바일 노드들을 관리하였고, 최대 반경과 노드 수 제약조건으로 분할과 합병 과정을 수행하도록 하였다. 제주도를 기반으로 한 모빌리티 모델을 만들어 시뮬레이션 작업을 수행하였으며, 제약 조건에 만족하는 이동 기지국의 최적위치와 적용범위를 확인했다.

Effect of Ti Intermediate Layer on Properties of HAp Plasma Sprayed Biocompatible Coatings

  • Take, Seisho;Otabe, Tusyoshi;Ohgake, Wataru;Atsumi, Taro
    • Corrosion Science and Technology
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    • 제19권2호
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    • pp.51-56
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    • 2020
  • The objective of this study was to improve properties of plasma sprayed HAp layer to titanium substrate by introducing an intermediate layer with two different methods. Before applying Zn doped HAp coating on titanium substrate, an intermediate layer was introduced by titanium plasma spray or titanium anodization. Heat treatments were conducted for some samples after titanium intermediate layer was formed. Zn doped HAp top layer was applied by plasma spraying. Three-point bending test and pull-off adhesion test were performed to determine the adhesion of Zn doped HAp coatings to substrates. Long-term credibility of Zn doped HAp plasma sprayed coatings on titanium was assessed by electrochemical impedance measurements in Hanks' solution. It was found that both titanium plasma sprayed and titanium anodized intermediate layer had excellent credibility. Strong adhesion to the titanium substrate was confirmed after 12 weeks of immersion for coating samples with titanium plasma sprayed intermediate layer. Samples with titanium anodized intermediate layer showed good bending strength. However, they showed relatively poor resistance against pulling off. The thickness of titanium anodized intermediate layer can be controlled much more precisely than that of plasma sprayed one, which is important for practical application.

방약합편과 한의학 임상표현 (Clinical presentation with 『PangYakHapPyon(方藥合編)』 in Korean medicine)

  • 주다현;김병수
    • 대한한의학회지
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    • 제40권1호
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    • pp.1-11
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    • 2019
  • Objectives: The aim of this study is to introduce the Clinical presentation and announce the importance of developing Clinical presentation of Korean medicine and suggest about development direction of Clinical presentation of Korean medicine. Methods: To Investigate the Clinical presentation used in western medicine. I think that Clinical presentation of Korean medicine is a systematic list of Korean medicine symptoms and a standard syndrome differentiation and treatment(辨證論治). So I would like to offer "PangYakHapPyon(方藥合編)" as a basis for developing Clinical presentation of Korean medicine. Results: The clinical presentation term has become widespread in use at Calgary Medical college. Calgary Medical college created a list of 120 clinical presentations In 1991. In Korea, 101 clinical presentations were made in 2016. "PangYakHapPyon(方藥合編)" has been used effectively for over 130 years and widely used in the public. In addition, "PangYakHapPyon(方藥合編)" is summarized in the symptoms and prescriptions that occur frequently in Korea. Conclusions: For the globalization and standardization of Korean medicine, Clinical presentation of Korean medicine should be developed. The overall form of Clinical presentation of Korean medicine uses the form of Clinical presentation of Canada and a standard syndrome differentiation and treatment(辨證論治) for diagnosis and treatment is based "PangYakHapPyon(方藥合編)".