• Fire Science and Engineering
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• v.10 no.3
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• pp.29-40
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• 1996

The AFFF(Aqueous Film Forming Foam : 3M Company's Light Water) agent are synthetic compounds that foams which are similar to those produced by protein based materials. The foam extinguishing agent was used In the extinguisher was the AFFF agent. We sought, however, to make other foams by using halon 1301 (CF$_3$Br) and halon alternatives, such as HCFC Blend A($CHCIF_2$ 82%, $CF_3$CHCIF 9.5%m $C_{10}$$H_{16}$ 3.75%), HFC-227ea ($CF_3$ $CHFCF_3$) We selected these alternatives instead of air in order to raise the expansion ratio of the AFFF agent. By these means we discovered that it is possible to increase the expansion ratio of the AFFF agent up to 44:1 and up to 24:1 when HFC-227ea was used as a halon alternatives. Therefore our new foam extinguishing agents can be used in a portable extinguish agents can be used in a portable extinguishers.

• Fire Science and Engineering
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• v.18 no.1
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• pp.7-12
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• 2004

For CFCs and Halons regulated by Montreal Protocol and their alternatives of HFC-23, HFC-125 HFC-227ea, HFC-236fa and the mixtures of inert gases of $Ar, N_2 and CO_2$, the thermodynamic properties of saturated pressure, density, enthalpy and viscosity were compared. In this study, the data from literature were expressed as a function of temperature. Thermodynamic properties of HFC compounds were similar to those of Halon-1301. Inert gas was mainly used as a mixture, but the physical properties of the inert gas does not have the favorable advantages over those of Halon-1301.

• Fire Science and Engineering
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• v.16 no.2
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• pp.51-58
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• 2002

For Halon-1301 regulated by Montreal Protocol and $CO_2$as its alternatives, the empirical equations of density, viscosity, and enthalpy were correlated in terms of temperature. They were obtained by regression analysis from the experimental data in the literature. The empirical equation of density was expressed as compressibility factor by the second- order function of temperature. The empirical equation of viscosity was formulated as a power function, and a correction factor was considered to cover the wider range of temperature. Finally, heat capacity as well as enthalpy were well fitted by empirical form of the second-order temperature. The correlation coefficients of the empirical equations in this work were more than 0.99.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.542-549
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• 1997

HFC-227ea and HCFC Blend A were evaluated using full-scale fire tests to obtain information on their fire suppression performance, drop-in capability, thermal decomposition products and physical behaviour of the agent such as its flow characteristics in the piping system. Also, full-scale tests were conducted with Halon 1301 to provide a basis for comparison. Halon 1301, at concentrations of 5% to 7.5%, showed effective total-flooding fire- extinguishing performance for all test scenarios. HFC-227ea, at a design concentration of 7.6% or higher, and HCFC Blend A, at a design concentration of 12%, extinguished all fires in the test facility, however, these agents produced higher concentrations of acid gases than Halon 1301. The quantity of the acid gases generated during fire suppression was dependent on agent concentration, agent discharge time, fire type and size as well as extinguishment time.

• Fire Science and Engineering
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• v.16 no.3
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• pp.26-31
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• 2002

Bromotrifluoromethane(halon-1301) and bromochlorodifluoromethane(halon-1211) have been widely used as a clean fire extinguishing agents due to their outstanding properties. However, production and use of halon are currently being phased out under an international agreements Montreal Protocol because of global environmental concerns and HFCs have been considered as promising alter-natives for the replacement of halon since their ozone depletion potentials are low. The vapor-liquid equilibrium data are required as important basic information in evaluating the solubility of clean fire extinguishing agents and determining their optimal compositions. In this work, we chose HFCs such as HFC-22 HFC-125, and HFC-l34a for gaseous fire extinguishing agents and nitrogen as a pressurization gas for a proper jet velocity of these agents. Phase equilibria for binary mixtures of nitrogen/HFC-22, nitrogen/HFC-125, and nitrogen/HFC-l34a were measured in the temperature range from 283.15K to 303.15K. For equilibrium measurement, we used a circulation type apparatus in which both vapor and liquid phases were continuously recirculated. The experimental data were relatively well correlated with the Peng-Robinson equation of state with Wong-Sandier mixing rules.

• Fire Science and Engineering
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• v.21 no.4
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• pp.1-11
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• 2007

This study aims to investigate, review, and summarize the definition, development, and applications of "percent agent in pipe", "percent of agent in pipe" which is used as a key factor in testing and evaluating the performance of gaseous fire extinguishing agents, including Halon 1301 and $CO_2$. This study also analyzes and compares the local and international standards on testing and evaluating the performance of gaseous fire extinguishing systems, as well as the results of system performance tests conducted as a part of performance evaluation and approval programs for gaseous fire extinguishing systems, especially, Korean Gaseous Fire Extinguishing System Performance Approval Program called KFI Approval. Percent agent in pipe was defined first in NFPA 12A, Standard on Halon 1301 Fire Extinguishing Systems, dating back to the 1970's. After the phaseout of Halon 1301 systems in 1994 in the developed countries, the percent agent in pipe has been widely used in Halon 1301 alternative clean agent fire extinguishing systems, both halocarbon clean agent systems and inert gas clean agent systems, as an essential criterion to assure the system design accuracy, determine the limitations and performance of a system, and to predict the system performance results accurately, especially, in association with their system flow calculations. Underwriters Laboratories has their own standards such as UL 2127 and 2166 applying percent agent in pipe in testing and evaluating the performance of clean agent fire extinguishing systems. As a part of a system performance test and approval program called KFI Approval System, Korea also has started to apply the percent agent in pipe as a key factor to test, evaluate, and approve the performance of gaseous fire extinguishing systems, including both high and low pressure $CO_2$ systems, from the early 2000's. This study outlines and summarizes the relevant UL and KFI standards and also describes the actual test resultant data, including the maximum percents of agent in pipe for gaseous fire extinguishing systems. As evidenced in lots of tests conducted as a part of the system performance test and approval programs like KFI Approval System, it has been proven that the percent agent in pipe may work as a key factor in testing, evaluating, and determining the limitations and performance of gaseous fire extinguishing systems, especially compared with the hydraulic flow calculations of computer design programs of gaseous fire extinguishing systems, and will remain as such in the future. As one thing to note, however, there are some difficulties in using the unified percent agent in pipe to determine the maximum lengths of pipe networks for gaseous fire extinguishing systems, because the varying definitions used by some of the flow calculations (not in accordance with NFPA 12A definition) make it impossible to do any direct comparison of pipe lengths based on percent agent in pipe.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.550-557
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• 1997

Production of so-called Halon fire extinguishing agents has been prohibited since January 1994 because of their ozone depletion potential, To replace them, several hydrofluorocarbons and fluorocarbons have been developed and utilized. A number of studies on flame extinguishing concentrations and flammability peak concentrations of them have been done. Although there was enough information for practical purpose, more knowledge on fire extinguishing characteristics of them should be attained for efficient use of them. In this study, peak concentrations of methane/air mixtures with gaseous halogenated hydrocarbons were measured at elevated temperature, because the former studies were done at room temperature and temperature of a fire room can be higher than usual. Measurement was done at $200^{\circ}C$, because measuring system could not endure higher temperature. This study revealed that peak concentrations of halogenated hydrocarbons differed little at elevated temperature. The halogenated hydrocarbons have almost the same fire extinguishing ability as Halon 1301.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.598-605
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• 1997

In recent years, the number of vehicle fires, as well as the number of motor vehicles, has been increasing rapidly. Therefore, several types of automatic fire suppression systems for the engine compartment of automobiles have been developed to extinguish automobile fires, and most of these systems use halon 1301 as a fire extinguishing agent. Due to environmental concerns, the phase-out of halons has been announced, so now there is a need to replace halon 1301. For this, a 1,1,1,2,3,3,3-heptaflouropropane (HFC-227ea, FM-$200^{TM}$) gas-filled Aqueous Film- Forming foam (known as AFFF) extinguisher was devised even though air foam extinguishers could be used. This is because the air in the foam bubbles is a source of oxygen required for the combustion reaction. It can be surmised that it is possible to increase the fire extinguishing efficiency of AFFF by filling in foam bubbles with a gaseous extinguishing agent. The best choice is the FM-$200^{TM}$ gas-filled AFFF, Which has the maximum expansion ratio of 62:1. This makes it possible for the expanded foam to rapidly fill the engine compartment.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.534-541
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• 1997

Isothermal solubilities of nitrogen in clean fire extinguishing agents, such as bromotrifluoromethane (Halon-1301), bromochlorodifluoromethane (Halon-121 t), 1,1,1,2,3,3,3- heptafluoropropane (HFC-227ea), and trifluoroiodomethane (FIC-13I1) were measured in a circulation-type equilibrium apparatus. The temperature range was (293.2 to 313.2) K and the pressure range was (30 to 100) bar. The experimental data were well correlated with the Peng- Robinson equation of state using the Wong and Sandier mixing rules, and the relevant parameters are presented.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1996.11a
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• pp.57-61
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• 1996

Our goal was to make a cost-effective automatic fire extinguishing system for the engine compartment use of automobiles. We designed this system for the engine compartment. This system consists of 1)foam extinguisher, 2)four nozzles, 3)a pipe arrangement, and 4)an extinguishing device which is equipped with a glass bulb as detector. First and foremost, the extinguishing device was carefully designed to keep the system cost to a minimum. Second, a AFFF foam extinguisher was used because no other fire-fighting agents proved effective against fire in the engine compartment. The AFFF(Aqueous Film Forming Foam) agent which was used in the extinguisher is the 3M company's Light Water. We sought, however, to make other foams by using Halon 1301 and Halon alternatives such as HCFC Blend A, HFC-227ea. We selected these alternatives instead of air in order to raise the expansion ratio of the AFFF agent. By these means we discovered that it is possible to increase the expansion ration of the AFFF agent up to 44:1. We then demonstrated that our automatic fire extinguishing system is the most effective and lowest cost-system yet devised for passenger cars.