• Title/Summary/Keyword: Halide

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Growth and changes in the biochemical composition of Isochrysis galbana under different light-emitting diode conditions

  • BAE, Jae-Hyun;AN, Heui-Chun;PARK, Heum-Gi;PARK, Jin-Chul;PARK, Jong-Myung;LEE, Kyoung-Hoon;HONG, Sung-Eic
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.51 no.4
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    • pp.475-483
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    • 2015
  • The marine microalgae Isochrysis galbana was cultured under various light-emitting diode (LED) light conditions with different wavelengths to examine changes in growth and in amino acid and fatty acid profiles. The culture conditions for the microalgae were Conway medium, salinity of 33 psu, temperature of $24^{\circ}C$, and a 16/8 h light/dark photoperiod. Six light sources, including 5 units of 180W LED lamps (peak wavelength: blue [LB] 470 nm; green [LG] 525 nm; yellow [LY] 595 nm; red [LR] 636 nm; white [LW] 442 nm) and 1 unit of a 175W metal halide (MH) lamp, were used for the experiment. The dry cell weights ($gL^{-1}$) of I. galbana under different light conditions were in the order of LW>LB${\geq}$MH>LR>LG>LY. Levels of essential amino acids were revealed to be significantly higher under LW, LG, and MH than under the other wavelengths (P<0.05). The fatty acid, unsaturated fatty acid, and DHA contents of I. galbana were higher under MH, LW, and LG. In addition, the carotenoid content was higher under MH, LW, and LG than under the other wavelengths (P<0.05). The fucoxanthin content was highest under MH (0.28%) and lowest under LY (0.2%), and it was 0.26% under LW and LG. The results indicate that the combined use of LW and LG is effective when using LED lamps for I. galbana cultivation.

Development of the silver-white decoy for squid automatic jigging machine and fishing performance (오징어채낚기용 은백색 유인체 개발과 어획성능)

  • An, Young-Il;Jang, Ung-Jeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.49 no.3
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    • pp.208-217
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    • 2013
  • Decoys for automatic jigging machines, the body part of a squid hook, have been developed in small and existing sizes in consideration of squid food, color blindness, and retinomotor responses and in utilization of pearl pigment, PP of high transparency, and combined mixture. In comparison of the developed silver-white decoy and existing decoys, the optical characteristics were examined, and the fishing performance of small size silver-white squid hooks was assessed in application of 4 fishing boats with the squid automatic jigging machine and metal halide fishing lamp in July, 2012. The luminances of the three squid hook colors-green, dark green and silver-white-increased as the intensity of illumination increased. Among these, the increase of silver-white was particularly distinguished. As to the average contrast of squid hooks, that of silver-white was 10.33, which was the highest, and then green 1.86 and dark green -0.10 in the order. As to the fishing performance of the silver-white hook, that of the 202 Geumyeong-ho and 101Yongjin-ho which caught squids were similar to that of the existing green hook and was relatively low in the case of the Dongbu-ho. However, that of the Haengbok-ho which caught relatively small squids whose average length was 19.9cm and installed silver-white hook in all automatic jigging machines was significantly excellent. In order to enhance the fishing performance of small size silver-white hooks, therefore, it would be effective to install in every automatic jigging machines of fishing boat and to start fishing before July by which small squids are caught.

Upconversion Mechanisms in $Tm^{3+}$-doped Glasses under 800 nm Excitation (800nm 파장 여기관에 의한 $Tm^{3+}$첨가 유리내 상향 전이 현상 기구)

  • Jeong, Hoon;Chung, Woon-Jin;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.111-116
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    • 2000
  • 700nm red emission(3F3longrightarrow3H6) in Tm3+ ion with 800 nm(3H6longrightarrow3H4) excitation via upconversion process has been reported only in host materials which have low phonon energies such as halide crystals. However, we observed 700nm and 480nm(1G4longrightarrow3H6) upconverted emission with 800nm excitation in several oxide glasses which has never reported. With spectroscopic analyses and lifetime measurements of each nergy level of Tm3+ ion doped in various oxide glasses, following mechanisms are suggested. For red upconversion, upconversion mechanism changed with Tm3+ concentration. While direct excitation up to 3F3 level via anti-Stokes excitation was dominated at low concentration, two-step excitation via 3H6longrightarrow3H4 and 3F4longrightarrow3F3 transitions was dominated at high concentration. For blue upconversion, two step excitation mechanism up to 1G4 level was suggested as follows : electrons are exciated up to 3H5 with direct excitation with pumping light up to 3H4 followed by multiphonon relaxation, and then additional reabsorption of pumping light excites electrons up to 1G4.

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Dimming Control of A Automotive HID Lamp Ballast Using Digital Control Method (디지털제어방식을 이용한 자동차용 고압방전등 안정기의 조광제어)

  • Lee, Jae-Hak;Kim, Yoon-Ho
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.1
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    • pp.24-33
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    • 2005
  • This paper presents dimming control system for automotive 35[W] metal halide discharge(MHD) lamp electronic ballast using digital control method. HID system has been becoming increasingly popular due to its superior performance(high luminous efficacy, good color rendering and long life etc.)over the conventional halogen system. However, this lamp demands a highly efficient ballast and very complex control circuitry that can control complex transient state in applying to automotive. Therefore, in this paper, digital control method for the HID lamp ballast is presented for optimal control that can adapt complex transient state, steady state and various environments. In developed dimming system, the system is designed to control the lamp output voltage step by step using microcontroller according to cds sensor. Therefore the designed dimming control system give good driving condition to diver and realize the power control effectively. The results of the proposed system is verified through various simulation results and the experiment results.

Effect of Artificial Light Sources on the Growth of Crisphead Lettuce in Plant Factory (식물공장에서 인공광원이 결구상추의 생육에 미치는 영향)

  • 조영렬;한동욱;이용범
    • Journal of Bio-Environment Control
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    • v.7 no.1
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    • pp.35-41
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    • 1998
  • This experiment was conducted to find out the effect of artificial light sources(high-pressure sodium lamp, metal halide lamp and fluorescent lamp) on growth of crisphead lettuce(Lactuca sativa L.) in a plant factory. No significant differences in leaf fresh and dry weight were presented among them. Lettuce plants grown under fluorescent lamp showed the lowest growth. Considering the growth of lettuce and efficiency of lamps, it is worth using HPS(high-pressure sodium) lamp in plant factories. The leaves of lettuce plants grown under artificial light sources showed tipburn symptoms at 14th day after transplanting. The beginning of tipburn symptom have been seen on the ninth to tenth leaves from the cotyledons. It is estimated that the occurrence of tipburn was related to rapid growth and K uptake of the lettuce Plants. The Ca, Mg. Cu and Zn elements tended to be accumulated in the nutrient solutions but the T-N, P, Fe and Mn elements keep in balance in them.

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Kinetics of Ethyl Phenylcarbamate Synthesis by the Oxidative Carbonylation of Aniline (아닐린의 산화적 카르보닐화에 의한 에틸페닐카바메이트의 합성의 속도론적 고찰)

  • Park, Nae-Joung;Park, Jae-Keun
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.710-716
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    • 1992
  • Ethylphenyl carbarmate(EPC) was synthesized by oxidative CO carbonylation of aniline in the presence of transition metal catalysts and alkali metal halide cocatalysts at $120^{\circ}C$ under the pressure of 79atm. Oxygen gas was used for oxidizing agent. Kinetics of the reaction was studied and activation energies with different catalysts were estimated. About 100% conversion to EPC and 95% selectivity was obtained in 5 hour reaction. 5% Pd/C was more effective than 5% Rh/C. Effectiveness of cocatalysts was in the order of KI>KBr>KCl. As the temperature increased from $75^{\circ}C$ to $120^{\circ}C$, the conversion rate increased. The reaction was apparent first order and the activation energies with 5% Pd/C and 5% Rh/C were 5.647 and 5.780 kcal/mol, respectively.

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Distribution patterns of the Japanese common squid, Todarodes pacificus attracted around the luring lamp on the jigging boat (채낚기 집어등 어선 주변에 유집된 살오징어, Todarodes pacificus의 분포 패턴)

  • BAE, Jae-Hyun;LEE, Kyounghoon;JO, Hyeon-Jeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.52 no.3
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    • pp.276-280
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    • 2016
  • This study investigated luring distributions by water layer of common squid which were targeted by angling fishing vessels equipped with LED and metal-halide lamps using a scientific echosounder with a 120 kHz frequency in order to develop energy-effective underwater fish aggregation devices. In the analysis, angles of a transducer were changed from $0^{\circ}$ to $45^{\circ}$ and were rotated every $10^{\circ}$ horizontally. It was shown that common squid were densely distributed from the surface to 40 m and they were also distributed in directions of $10^{\circ}{\sim}+30^{\circ}$, $-30^{\circ}{\sim}-60^{\circ}$, and $-120^{\circ}{\sim}-130^{\circ}$with the head of vessel as the center. Comparative results of angles of transducer on acoustical densities of common squid distributing in 21~40 m water depth showed an average $101.8m^2/nm^2$ in vertical direction of $0^{\circ}$, $12.3m^2/nm^2$ in angle of $30^{\circ}$, and $42.4m^2/nm^2$ in angle of $45^{\circ}$, respectively. It implied that more considerations on acoustic scattering strength by incidence angle direction of the transducer and swimming oriental angle direction of common squid would be required.

Studies on the Pulp Bleaching for Reducing AOX(I) - The Pulp Bleaching Method Using A and $D_{(H/L)}$ Treatment - (AOX 감소를 위한 새로운 표백법 (제1보) - A처리 및 $D_{(H/L)}$ 처리를 이용한 표백법 -)

  • 윤병호;김기선;이선호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.1
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    • pp.52-61
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    • 1997
  • This study was aimed to decrease AOX(Adsorbed Organic Halide Compounds) by applying bleaching methods of A(HNO$_3$ + NaNO$_2$) and $D^{(H/L)}$(dual pH chlorine dioxide bleaching) to conventional OCEDED bleaching stages. And so we investigate the effects of NSA treatment and the influence of production rate of ion species in chlorine dioxide and pulp mixtures according to various pH as well as dual pH on pulp bleaching. Finally the effects of AOC_DED^{(H/L)}ED^{(H/L)}$ bleaching stage were investigated by measuring AOX, brightness, kappa number and viscosity of pulps. A stage was treated by using 4% $HNO_3$ and 0.05~2.0% $NaNO_2$ on pulp and $D^{(H/L)}$ stage was like that pulp mixed with chlorine dioxide solution was adjusted at pH 7.0 and reacted in pulp cosistency 3%, S~20min, $70^{\circ}C$, and then successively for 160~175min at pH 4.0. It was found that suitable $NaNO_2$ addition rate was at 0.6% where the brigtness of pulp was most higher and pulp viscosity was not decreased much. Chlorate ($CIO_3$) was decreased according to pH increase but chlorite($CIO_2$) was highly decreased according to pH increase. And chloride was slightly increased with pH increase. The applying of A and D^{(H/L)}$ bleaching stages to some various multiple bleaching stages ($AOC_DED^{(H/L)}/EopD^{(H/L)} etc.$) had good results that brightness was increased more 2~3% ISO than conventional method(OCEDEopD), but viscosity was dropped by only 1~2cps.

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Size Tailored Nanoparticles of ZrN Prepared by Single-Step Exothermic Chemical Route

  • Lee, Sang-Ki;Park, Kyung-Tae;Ryu, Hong-Youl;Nersisyan, Hayk H.;Lee, Kap-Ho;Lee, Jong-Hyeon
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.243-248
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    • 2012
  • ZrN nanoparticles were prepared by an exothermic reduction of $ZrCl_4$ with $NaN_3$ in the presence of NaCl flux in a nitrogen atmosphere. Using a solid-state combustion approach, we have demonstrated that the zirconium nitride nanoparticles synthesis process can be completed in only several minutes compared with a few hours for previous synthesis approaches. The chemistry of the combustion process is not complex and is based on a metathesis reaction between $ZrCl_4$ and $NaN_3$. Because of the low melting and boiling points of the raw materials it was possible to synthesize the ZrN phase at low combustion temperatures. It was shown that the combustion temperature and the size of the particles can be readily controlled by tuning the concentration of the NaCl flux. The results show that an increase in the NaCl concentration (from 2 to 13 M) results in a temperature decrease from 1280 to $750^{\circ}C$. ZrN nanoparticles have a high surface area (50-70 $m^2/g$), narrow pore size distribution, and nano-particle size between 10 and 30 nm. The activation energy, which can be extracted from the experimental combustion temperature data, is: E = 20 kcal/mol. The method reported here is self-sustaining, rapid, and can be scaled up for a large scale production of a transition metal nitride nanoparticle system (TiN, TaN, HfN, etc.) with suitable halide salts and alkali metal azide.

Effect of Injection Conditions on the Spray Behaviors of the Multi-hole GDI Injector (분사 조건이 다공형 GDI 인젝터의 분무 거동에 미치는 영향)

  • Park, Jeong-Hwan;Park, Su-Han;Lee, Chang-Sik;Park, Sung-Wook
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.2
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    • pp.116-122
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    • 2012
  • The purpose of this study is to investigate the overall spray behavior characteristics for various injection conditions in a gasoline direct injection(GDI) injector with multi-hole. The spray characteristics, such as the spray penetration, the spray angle, and the injection quantity, were studied through the change of the injection pressure, the ambient pressure, and the energizing duration in a high-pressure chamber with a constant volume. The n-heptane with 99.5% purity was used as the test fuel. In a constant volume chamber, the injected spray was visualized by the spray visualization system, which consisted of the high-speed camera, the metal-halide lamp, the injector control device, and the image analysis system with the image processing program. It was revealed that the injection quantity was mainly affected by the difference between the injection pressure and the ambient pressure. For low injection pressure conditions, the injection quantity was decreased by the increase of the ambient pressure, while it nearly maintained regardless of the ambient pressure at high injection pressure. According to the increase of the ambient pressure in the constant volume chamber, the spray development became slow, consequently, the spray tip penetration decreased, and the spray area increased. In additions, the circular cone area decreased, and the vortex area increased.