• Journal of the Korean Chemical Society
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• v.66 no.6
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• pp.433-435
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• 2022

• Journal of Biomedical Engineering Research
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• v.27 no.6
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• pp.337-342
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• 2006

We have developed a noncontact temperature sensor using a silver halide optical fiber. The infrared collimator and focus head are connected both ends of a silver halide optical fiber with SMA connectors and used to collimate radiations of a heat source and to focus them to infrared sensors such as a pyroelectric sensor and a thermopile sensor, respectively. The relation ships between the temperatures of a heat source and the output signals of the infrared sensors are determined to measure the surface temperature of a heat source. The measurable temperature range is from 25 to $60^{\circ}C$. It is expected that a noncontact temperature sensor using a silver halide optical fiber can be developed for medical usages such as temperature monitoring during hyperthermia, cryosurgery, laser surgery and diagnostic procedure based on the results of this study.

• Journal of the Korean Chemical Society
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• v.32 no.2
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• pp.122-129
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• 1988

The rates of aquation of sparteine cobalt(II) halide and sparteine copper(II) halide were investigated in the citrate buffer solutions. The aquation of cobalt(II) complexes proceeds via D-mechanism and the catalytic effect of halide ions is not observed. The aquation of copper(II) complexes proceeds via $I_d$-mechanism and is catalyzed by the presence of cyanide and halide ions, and the aquation rate is pH dependent. The different mechanistic behavior of cobalt(II) complexes from corresponding copper(II) complexes seems to be attributed to the weakness of Co-N bond in the coordination sphere.

• Journal of the Korean Chemical Society
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• v.29 no.1
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• pp.45-51
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• 1985

Rate constants and activation parameters for the methanolysis of t-butyl halide (t-BuCl, t-BuBr, t-BuI) in various MeOH-DMSO mixtures were measured by conductometric method. Taft's solvatochromic parameters, such as polarity-polarizability(SPP's), ${\pi}^{\ast}$, hydrogen bond donor (HBD) acidity, ${\alpha}$, and hydrogen bond acceptor (HBA) basicity, ${\beta}$ of the solvents, were determined by the so called solvatochromic method using five indicators. The variation of methanolysis rate with the solvent composition was discussed on the basis of the activation parameters and the correlation of the rates with the solvatochromic parameters. It is concluded that the polarity-polarizability, HBD acidity and HBA basicity of the mixtures had an effect on the ionization of t-butyl halide cooperatively, also that the specific interaction between the leaving groups and the solvents, such as ion-dipole and hydrogen bond acceptor-donor interaction, is the most important factor of solvent effects on the stabilization of transition states.

• Journal of the Korean institute of surface engineering
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• v.51 no.5
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• pp.257-262
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• 2018

Cesium lead halide perovskite quantum dots (QDs) have recently emerged as highly promising opto-electronic materials. Despite the relative facile anion exchange reactions in cesium lead halide perovskite QDs, in depth study of the anion exchange reactions such as reaction kinetics are required that can provide insight into the crystal transformation in the cesium lead halide perovskite QDs. Herein, we investigated the anion exchange reaction from $CsPbI_3$ QDs to $CsPbBr_3$ QDs with varying the particle size of the starting $CsPbI_3$ QDs. By characterizing the PL spectra in the anion exchange reaction process, we observed that discontinuous PL peak shifts during I-to-Br anion exchange reaction in starting $CsPbI_3$ QDs over a critical size. Origin of the discontinuous I-to-Br anion exchange kinetics are mainly due to thermodynamically unstable nature of the $CsPb(Br/I)_3$ alloy QDs.

• Horticultural Science & Technology
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• v.32 no.6
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• pp.794-802
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• 2014

The aim of this study was to determine the effect of day-length extension treatment using LED lighting (blue, green, red, or 3 mixed) on vegetative growth and flowering of freesia 'Yvonne', in comparison to that using glow lamps and metal halide lamps. Lighting treatments were imposed from 5 PM to 8 PM for 150 days from after flower bud differentiation to flowering end. For the period from leaf emergence to floral bud formation, no light source affected plant height but the number of leaves was decreased by the metal halide lamp. The highest SPAD value in the flower bud developing period occurred in the metal halide lamp treatment. The time of flowering was advanced by blue or green LED treatment compared to the no lighting control. The green LED lighting advanced flowering by 6 and 8 days compared to no lighting and metal halide lamp treatment, respectively. The blooming period tended to be shortened by the red LED treatment. As for the flower characteristics of 'Yvonne', floret length and width, and the weight of cut flowers were highest in the metal halide lamp treatment. Red LED decreased corm width and weight of 'Yvonne' while glow lamp decreased height and weight. Starch contents in corm were not influenced by the lighting source. Our results indicate that the green LED lighting advanced the time of flowering and the metal halide lamp was good for cut-flower quality.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.23 no.12
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• pp.996-1001
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• 2010

Recently, the demand of ceramic metal halide lamp has been expanded. Therefore, the lamp with high efficiency and long lifetime are increasing and the evaluation of reliability is needed. In this paper, the degradation phenomena of ceramic metal halide lamp was studied. The lamp was tested for 3000 on/off cycles with each cycle having a duration of 20 minutes on and 20 minutes off based on the accelerated aging experiment based on "Reliability Standards RS C 0085". As result, the corrosion of arc tube and leak was appeared from reaction between inner wall of PCA and chemical elements, and distortion of electrode was resulted from difference of thermal expansion between arc tube of PCA and electrode. Also, the efficiency of lamp was decreased by the change of inner pressure, operation temperature, and driving voltage from wall blackening.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.42 no.4
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• pp.228-233
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• 2006

The transmittance properties of fishing lamp of the squid jigging vessel was investigated during nighttime operations in the Northwest Pacific on 21 and 29 September 2005. The metal halide lamps of white color($2.0kW{\times}168$) in the air and metal halide lamp of white color($10.0kW{\times}1$) in the underwater were used as a fishing lamp for gathering squids. The relative irradiance of metal halide lamp in the air showed peak in 850nm of wave length. The relationship between underwater illuminance(Y) and water depth(X) of metal halide lamp light in the observation areas is represented, $Y=84.137e^{-0.1105X},\;R^2=0.9974$. The distribution of underwater illuminance of measure points St. 1-5 showed low value of 0.11x in 80m depth.

• Journal of the Korean Chemical Society
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• v.25 no.4
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• pp.253-262
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• 1981

The AgI/ PV${\cdot}$THF membrane electrode could be used as an indicator electrode in the potentiometric titration of single halide and mixture halide solutions with the standard solution of silver nitrate. The errors in the stepwise titrations of mixture halide solutions were considerably large, but by addition of flocculating agent, such as $NaNO_3$ or $Ba(NO_3)_2$, in the sample solution, the errors were greatly reduced. Also, the effects of gelatin, filter paper and temperature on the titration errors were examined.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.48 no.4
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• pp.346-351
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• 2012

The fuel cost of fishing lights for squid jigging fishing vessels takes about 30% of total fishing costs and over 65% of total fuel costs, which indicates the necessity of development of cost-reducing and high efficient fishing light system. This study aimed to analyze the economic effectiveness of LED fishing light systems in combination with metal halide lamp for the squid jigging fishery. Analytical results showed that the level of fishing profits of vessels using LED lights could be different with those of vessels using metal halide lights. That is, when a fuel cost could be reduced by 30%, fishing profits of vessels using LED lights might be the same as those of vessels using metal halide lights, and fishing profits of vessels using LED lights could be higher than those of vessels using metal halide lights when a fuel cost could be reduced by 50%.