• 제목/요약/키워드: Half integer peak

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Elucidation of Central Line Refocusing in Quadrupolar Echo Formation

  • Han, Duk-Young
    • 한국자기공명학회논문지
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    • 제3권1호
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    • pp.27-35
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    • 1999
  • Quadrupolar interaction is a strong line broadening agent for nuclei of half-integer spin except the central line. The two-pulse quadrupolar echo technique is widely used, which refocuses the quadrupolar broadening. Echo formation is due to the cancellation of quadrupolar broadening effect by the applied two pulses. Since the central line is not quadrupolar broadened, it should not be involved in the echo formation. However, the central line peak always appears in experiments. This is explained qualitatively here by close examination on the time development of individual coherence. This explanation is used to predict the number of echoes that will be formed with 2 pulse sequence for nuclei of I=3/2, 5/2, 7/2, 9/2 with ease.

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Temperature Dependent Octahedral Tilting Behaviors of Monoclinic and Tetragonal SrRuO3 Thin Films

  • Lee, Sung Su;Seo, Okkyun;Kim, Jaemyung;Song, Chulho;Hiroi, Satoshi;Chen, Yanna;Katsuya, Yoshio;Sakata, Osami
    • Journal of the Korean Physical Society
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    • 제73권10호
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    • pp.1529-1534
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    • 2018
  • We used in-situ synchrotron X-ray scattering to investigate phase transformations of octahedral tilted monoclinic $SrRuO_3$ (MSRO) and tetragonal SRO (TSRO) thin films on $SrTiO_3$ (STO) substrates. The octahedral tilted MSRO thin films were highly crystalline and the monoclinic distortion angle was $0.45^{\circ}$. The phase transition temperature from the MSRO to TSRO phase occurred at approximately $200^{\circ}C$ as a second order transition. Conversely, no phase transformations of the TSRO thin film occurred within the range from RT to $250^{\circ}C$. The octahedral $RuO_6$ rotation was strongly affected by the phase transformation in the SRO thin films.