• 제목/요약/키워드: Half cell test

검색결과 117건 처리시간 0.027초

Half-cell 기반 multi-wires 접합 공정에서 접합 특성에 영향을 주는 요인과 효율의 상관관계 연구 (A Study on the Relationship between Factors Affecting Soldering Characteristics and Efficiency of Half-cell Soldering Process with Multi-wires)

  • 김재훈;손형진;김성현
    • Current Photovoltaic Research
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    • 제7권3호
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    • pp.65-70
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    • 2019
  • As a demand of higher power photovoltaic modules, shingled, multi-busbar, half-cell, and bifacial techniques are developed. Multi-busbar module has advantage for large amount of light havesting. And, half-cell is high power module for reducing resistive losses and higher shade tolerance. Recently, researches on multi-busbar is focused on reliability according to adhesion and intermetallic compound between Sn-Pb solder and Ag electrode. And half-cell module is researched to comparing with full-sized cell module for structure difference. In this study, we investigated the factors affecting to efficiency and adhesion of multi-wires half-cell module according to wire thickness, solder thickness, and flux. The results of solar simulator and peel test was that peel strength and efficiency of soldered cell is not related. But samples with flux including high solid material showed high efficiency. The results of FE-SEM and EDX line scan on cross-section between wire and Ag electrode for different flux showed thickness of solder joint between wire and Ag electrode is increasing through solid material increasing. Flux including high solid material would affect to solder behavior on Ag electrode. Higher solid material occurred lower growth of IMC layer because solder permeate to sider of wire ribbon than Ag electrode. And it increased fill factor for high efficiency. In soldering process, amount of solid material in flux and solder thickness are the factor related with characteristic of soldered photovoltaic cell.

반전지-전위 측정방법을 활용한 슬래그 콘크리트의 철근 부식 저항성능 평가 (Evaluation of Steel Corrosion of Slag Concrete by Half-cell Potential Method)

  • 이보경;김규용;김래환;윤민호;이영욱;최경철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 추계 학술논문 발표대회
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    • pp.3-4
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    • 2014
  • There is high probability of steel corrosion on the reinforced concrete exposed to marine environment by penetration of chloride ion. When making concrete structure with slag as admixture in marine environment, salt damage can be prevented. Therefore, this paper presents experimental results of steel corrosion resistance of slag concrete considering marine environment through half-cell potential method which is one of the nondestructive test. As a result of half-cell potential experiment, it was assumed that every specimen exposed to marine environment was not corroded, and as a result of destroying specimens, it was confirmed that there was no corrosion in specimens.

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부식촉진시험에 의한 콘크리트 내의 철근의 부식 모니터링에 관한 실험적 연구 (An Experimental Study on the Corrosion Monitoring of Reinforcing Steel in Concrete by the Accelerated Corrosion Test)

  • 배수호;정영수;김진영
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.543-548
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    • 2001
  • The corrosion monitoring methods of reinforcing steel in concrete are the various methods such as half cell potential method, galvanic current method, resistivity method, polarization resistance method, AC impedance method and etc. In this study, the corrosion monitoring methods of reinforcing steel in concrete were investigated for the test specimens using corrosion inhibitors, zinc-mortar, zinc-plate, respectively. For this purpose, the accelerated corrosion tests for reinforcing steel were conducted according to the periodic cycles(140 days) of wetting($65^{\circ}C$, 90% R.H.) and drying period(15$^{\circ}C$ , 65% R.H.) for the test specimens. As a result, it can be concluded from the test that half cell potential and galvanic current method as monitoring techniques for corrosion were found to be relatively reliable and easily usable method in the field.

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콘크리트구조물 중의 철근 부식 저감을 위한 FRP Hybrid Bar의 적용성 연구 (A Study on the Application of FRP Hybrid Bar to Prevent Corrosion of Reinforcing Bar in Concrete Structure)

  • 이승태;박광필;박기태;유영준;서동우
    • 한국산학기술학회논문지
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    • 제20권5호
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    • pp.559-568
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    • 2019
  • 최근 해양환경의 대형 SOC구조물 증가에 따른 구조물 내구성 증진에 관심이 증가되고 있다. 내구성 증진을 위해 개발된 FRP Hybrid Bar의 구조적 성능은 검증 되었으나 부식에 대한 저항성을 평가한 연구는 미흡하여 본 연구를 수행 하였다. 본 연구에서는 콘크리트 중의 철근 종류에 따른 철근부식 저항성을 평가하였다. 평가를 위하여 철근은 일반철근과 FRP hybrid Bar을 사용하였다. 시험방법은 갈바닉전류(Galvanic)와 반전지법(Half-Cell)을 사용하였으며, 철근부식 촉진을 위하여 콘크리트 내부에 염분을 0%, 1.5%, 3%, 6% 첨가하였다. 그 결과 갈바닉전류측정에서 FRP Hybrid Bar는 부식전류가 측정되지 않았다. 반면 일반철근에서는 시험 직후 부식이 발생하는 결과를 나타내었다. Half-Cell측정 결과에서도 4단계의 염분 함유량의 차이와 광물질혼화재료를 사용한 콘크리트와 일반콘크리트에 관계없이 FRP Hybrid Bar의 부식 저항성이 우수하게 나타났다. 따라서 FRP Hybrid Bar는 해양환경 및 철근부식이 예측되는 구조물용 대체 철근으로 사용이 가능하나 부착성능, 탄성계수, 절곡부의 강선 노출에 대한 처리 방법 등이 개선되면 염해로부터 철근부식 저항성 확보를 요구하는 구조물에 사용 할 수 있는 우수한 소재로 판단된다.

고로슬래그 미분말을 사용한 콘크리트 내의 철근부식에 관한 실험적 연구 (An Experimental Study on the Reinforcement Corrosion in Concrete Using Granulated Blast Furnace Slag)

  • 이동혁;김은겸;김영웅;김영철
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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    • pp.761-766
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    • 2002
  • This paper was peformed to verify the effect that granulated blast furnace slag gets in reinforcement corrosion resistance about chloride ion that invade from outside. An experiment accelerated for the reinforcement corrosion through repeat of brine digestion and dry. Reinforcement corrosion investigated half cell potential method of measurement by ASTM C876 and corrosion area ratio. If granulated blast furnace slag metathesis ratio is high generally that looked the corrosion of reinforcement decreasing as a result that evaluate reinforcement corrosion by ASTM C876 canon in this research. It showed high resistance about reinforcement corrosion that use normal portland cement and increase the metathesis rate of granulated blast furnace slag, as a result that evaluate metathesis rate effect of granulated blast furnace slag according to cement kind. when the test piece split destroying, area rate of reinforcement corrosion showed about result of half cell potential measurement.

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Corrosion of rebar in carbon fiber reinforced polymer bonded reinforced concrete

  • Bahekar, Prasad V.;Gadve, Sangeeta S.
    • Advances in concrete construction
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    • 제8권4호
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    • pp.247-255
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    • 2019
  • Several reinforced concrete structures that get deteriorated by rebar corrosion are retrofitted using Carbon Fiber Reinforced Polymer (CFRP). When rebar comes in direct contact with CFRP, rebar may corrode, as iron is more active than carbon. Progression of corrosion of rebar in strengthened RC structures has been carried out when rebar comes in direct contact with CFRP. The experimentation is carried out in two phases. In phase I, corrosion of bare steel bar is monitored by making its contact with CFRP. In phase II, concrete specimens with surface bonded CFRP were casted and subjected to the realistic exposure conditions keeping direct contact between rebar and CFRP. Progression of corrosion has been monitored by various parameters: Half-cell potential, Tafel extrapolation and Linear Polarisation Resistance. On termination of exposure, to find residual bond stress between rebar and concrete, pull-out test was performed. Rebar in contact with CFRP has shown substantially higher corrosion. The level of corrosion will be more with more area of contact.

The Initial Irreversible Capacity of the Lithium Ion Battery System Using by the Gradual Control of State of Charge

  • Doh, Chil-Hoon;Choi, Sang-Jin;Jin, Bong-Soo;Moon, Seong-In;Yun, Mun-Soo
    • 전기화학회지
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    • 제5권4호
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    • pp.173-177
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    • 2002
  • Electrochemical characteristics of a graphite/lithium and a $LiCoO_2/lithium$ half cell and a $graphite/LiCoO_2$ full cell were analyzed using a GCSOC (gradual control test of the state of charge) technique. The IIE (initial intercalation coulombic efficiency), which represents lithium intercalation property of the electrode material, and the $lIC_s$ (initial irreversible capacity by the surface), which represents irreversible reaction between the electrode surface and the electrolyte were obtained from the GCSOC analysis. Linear-fittable capacity ranges of IIE of graphite and $LiCoO_2$ electrodes were 370 and 150 mAh/g, respectively, based on material weight. The value of lIE for graphite and $LiCoO_2$ electrodes were $93-94\%$ and $94-95\%$, respectively. The value of IICs for graphite and $LiCoO_2$ electrodes were 15-17 mAh/g and 0.3-1.7 mAh/g, respectively. The value of IIE for $graphite/LiCoO_2$ full cell, used GX25 and DJG311 as a graphite, was $89-90\%$ that lower than that for the half cells. Parameters of IIE and IICs can also be used to represent not only half cell but also full cell.

염화칼슘이 함유된 제설제로 인한 콘크리트 바닥판 단부의 염해에 관한 사례 연구 (A Case Study on Chloride Corrosion for the End Zone of Concrete Deck Subjected to De-icing Salts Added Calcium Chloride)

  • 정지승;김보헌;김일순
    • 한국안전학회지
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    • 제29권6호
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    • pp.87-93
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    • 2014
  • In this study, the reinforced concrete rahmen bridge damaged by the chloride attack was investigated. According to the investigation, the degraded concretes on cantilever kerb and end part were intensively observed. Thus, the chloride content test and half-cell method were performed to evaluate the degraded parts. As a result, the contents of chloride on degraded parts were C and D grade. On the other hand, the half-cell potential values of rebar in degraded concrete were measured with the minor corrosion. This rebar corrosion is expected to progressing. Chloride content D grade is due to expansion pressure by corrosion of rebar and freeze-thaw by permeate water, could see progresses rapidly degradation. In order to prevent chloride attack to concrete deck caused by deicing salts, corresponding to the chloride critical concentration must maintain grade b or at least grade c. Chloride condition evaluation standard apply to evaluation of marine structure chloride attack with chloride attack by deicing salts.

솔-젤 합성에 의한 직접 메탄올 연료전지용 고분산 Pt-Ru/C 음극 촉매의 제조 (A Study on Sol-gel Preparation of Pt-Ru/C Anode Catalysts for Direct Methanol Fuel Cells)

  • 이강희;김일곤;박태진;서동진
    • 전기화학회지
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    • 제6권1호
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    • pp.13-17
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    • 2003
  • 직접 메탄을 연료전지의 음극 촉매로 사용되는 Pt-Ru/C를 솔-젤법을 이용하여 크라이오젤 및 에어로젤 형태로 제조하였다. 탄소의 원료가 되는 유기물의 종류에 따라 B종의 촉매를 제조하였으며 XRD분석에 의해 금속이 탄소담체 위에 고분산되어 있음을 확인하였다. 초임계건조, 탄화. 환원 공정을 거쳐 완성된 에어로젤 촉매의 전극 활성은 Cyclic voltametry를 이용한 half cell test를 통하여 평가하였다. 그 중 Phloroglucinol-Formaldehyde(PF) 형의 촉매가 가장 우수한 활성을 보였으며 내구성 또한 양호하였다.