• Journal of the Korean Ceramic Society
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• v.52 no.6
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• pp.429-434
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• 2015

This study investigates the macroscopic wear behaviors of C/C and C/C-SiC composites coated with hafnium carbide (HfC). To improve the wear resistance of C/C composites, low-pressure chemical vapor deposition (LPCVD) was used to obtain HfC coating. The CVD coatings were deposited at various deposition temperatures of 1300, 1400, and $1500^{\circ}C$. The effect of the substrate material (the C/C substrate, the C/C-CVR substrate, or the C/C-SiC substrate deposited by LSI) was also studied to improve the wear resistance. The experiment used the ball-on-disk method, with a tungsten carbide (WC) ball utilized as an indenter to evaluate the wear behavior. The HfC coatings were found to effectively improve the wear resistance of C/C and C/C-SiC composites, compared with the case of a non-coated C/C composite. The former showed lower friction coefficients and almost no wear loss during the wear test because of the presence of hard coatings. The wear scar width was relatively narrower for the C/C and C/C-SiC composites with hafnium coatings. Wear behavior was found to critically depend on the deposition temperature and the material. Thus, the HfC-coated C/C-SiC composites fabricated at deposition temperatures of $1500^{\circ}C$ showed the best wear resistance, a lower friction coefficient, and almost no loss during the wear test.

• Korean Journal of Materials Research
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• v.3 no.2
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• pp.111-120
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• 1993

Abstract In this study, the Mo-Hf-O ingots containing 0.31-1.14at % Hf and 0.08-1.00at % 0 were prepared by plasma arc melting. The change of microstructure depending on the condition of heat treatmen~ was analysed by optical microscophy, auger electron microscophy, and transmission electron microscophy. Molybdenum powder with the oxygen content of 830ppm was compacted, and then melted. The oxygen content of molybdenum ingots was detected to be 40 -130ppm. As the contents of Hf and 0 increased, the grain size of ingots decreased. When molybdenum igot containing l.14at % Hf and 1.00at % C was heat treated, p-molybdenum carbide in grains was transformed into ${\alpha}$-molybdenum carbide at 130$0^{\circ}C$. Between 140$0^{\circ}C$ and 150$0^{\circ}C$, the precipitation of hafnium carbide was due to the reaction of solute Hf and C, and the hafnium carbide was saturated at grain boundaries at 150$0^{\circ}C$. When the sample was heat treated from 150$0^{\circ}C$ to 170$0^{\circ}C$, Hafnium oxide more stable thermodynamically precipitated both at grain boundaries and in grains after hafnium carbide had been dissolved at grain boundaries.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.237.2-237.2
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• 2016

A pure hafnium-carbide (HfC) coating layer was deposited onto carbon/carbon (C.C) composites using a vacuum plasma spray system. By adopting a SiC buffer layer, we successfully integrated C.C composites with a $100-{\mu}m-thick$ protective coating layer of HfC. Compared to the conventional chemical vapor deposition process, the HfC coating process by VPS showed increased growth rate, thickness, and hardness. The growth behavior and morphology of HfC coatings were investigated by FE-SEM, EDX, and XRD. From these results, it was shown that the addition of a SiC intermediate layer provided optimal surface conditions during the VPS procedure to enhance adhesion between C.C and HfC (without delamination). The thermal ablation test results shows that the HfC coating layer perfectly protected inner C.C layer from thermal ablation and oxidation. Consequently, we expect that this ultra-high temperature ceramic coating method, and the subsequent microstructure that it creates, can be widely applied to improve the thermal shock and oxidation resistance of materials under ultra-high temperature environments.

• Composites Research
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• v.31 no.5
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• pp.260-266
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• 2018

This study investigates thermal and mechanical characterization of Hafnium carbide coating on the $C_f-C$ composites. The hafnium carbide coatings by vacuum plasma spray on the C/C-SiC composites are prepared to evaluate oxidation and wear resistance. We perform the thermal durability tests by thermal cycling at $1200^{\circ}C$ for 10cycles in air and investigates the weight change of each cycle. We also evaluate the wear and indentation behavior using tungsten carbide ball indenter as a mechanical evaluation. As a result, the HfC coating is beneficial to reduce of weight loss during thermal cycling test and improve the elastic property of C/C-SiC composite. Especially, the HfC coating improves the wear resistance of C/C-SiC composite.

• Journal of the Korean Ceramic Society
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• v.47 no.6
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• pp.534-539
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• 2010

$HfB_2$-HfC composites were prepared by reactive hot pressing using Hf and $B_4C$ at temperatures of 1800 and $1900^{\circ}C$ for 60 min under 32 MPa in an Ar atmosphere. The reaction sequences of the $HfB_2$-HfC composite were studied through series of pressureless heat treatments ranging from 800 to $1600^{\circ}C$. The effect of size reduction of the starting powders on densification was investigated by vibration milling. Fully dense $HfB_2$-HfC composites were obtained by size reduction of the starting powders via vibration milling. The oxidation behaviour of the $HfB_2$-HfC composites at $1500^{\circ}C$ in air showed formation of a non-protective $HfO_2$ scale with linear mass gain. Examination of the mechanical properties showed that particle size reduction via vibration milling also led to improved flexural strength, hardness and fracture toughness.

• Archives of Metallurgy and Materials
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• v.66 no.4
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• pp.997-1000
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• 2021

In this study, a novel composite was fabricated by adding the Hafnium diboride (HfB₂) to conventional WC-Co cemented carbides to enhance the high-temperature properties while retaining the intrinsic high hardness. Using spark plasma sintering, high density (up to 99.4%) WC-6Co-(1, 2.5, 4, and 5.5 wt. %) HfB₂ composites were consolidated at 1300℃ (100℃/min) under 60 MPa pressure. The microstructural evolution, oxidation layer, and phase constitution of WC-Co-HfB₂ were investigated in the distribution of WC grain and solid solution phases by X-ray diffraction and FE-SEM. The WC-Co-HfB₂ composite exhibited improved mechanical properties (approximately 2,180.7 kg/mm²) than those of conventional WC-Co cemented carbides. The high strength of the fabricated composites was caused by the fine-grade HfB₂ precipitate and the solid solution, which enabled the tailoring of mechanical properties.

• Composites Research
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• v.28 no.6
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• pp.366-371
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• 2015

In order to improve the mechanical properties of tungsten at room and elevated temperature, hafnium carbide (HfC) reinforced tungsten matrix composites were prepared using the spark plasma sintering technique. The effect of HfC content on the compressive strength and flexural strength of the tungsten composites was investigated. Mechanical properties of the composites were also measured at elevated temperatures and their trends, with varying reinforcement volume fraction, were studied. The effect of reinforcement fraction on the thermal properties of the composites was investigated. The thermal conductivity and diffusivity of the composites decreased with increasing temperature and reinforcement volume fraction. An inherently low thermal conductivity of the reinforcement as well as interfacial losses was responsible for lower values of thermal conductivity of the composites. Values of coefficient of thermal expansion of the composites were observed to increase with HfC volume fraction.