• 제목/요약/키워드: HST

검색결과 197건 처리시간 0.032초

AKD 사이즈 처리한 종이의 저장중 가열처리에 의한 AKD의 거동 (Behavior of AKD in AKD-sized Paper by Heating Treatment During Ageing)

  • 신영두;서원성;조남석
    • 펄프종이기술
    • /
    • 제39권1호
    • /
    • pp.16-24
    • /
    • 2007

  • This study was performed to investigate the reaction between alkylketene dimer(AKD) and cellulose molecules in AKD-sized paper sheet. AKD was added to highly beaten($80{\pm}3^{\circ}SR$) SwBKP(ca. 0.8% on pulp) in order to have much AKD retention in the paper sheet. This AKD-sized paper sheet was aged at different temperatures, $60^{\circ}C,\;80^{\circ}C,\;105^{\circ}C\;and\;125^{\circ}C$. Changes in FT-IR spectra of AKD in paper sheet during the ageing were measured. In addition, sizing degrees of the AKD-sized paper sheet pretreated for 30 sec. at $105^{\circ}C$ were measured by HST size tester during the storage at different temperature. IR spectra of AKD-sized paper sheet preheated at $105^{\circ}C$ for 30 sec. showed unchanged spectra two absorption bands at $1849cm^{-1}\;and\;1722cm^{-1}$ which refer to the typical AKD IR bands. However, these typical AKD bands were gradually reduced with increasing ageing, completely disappeared after 6 hrs. and formed new absorption band at $1706cm^{-1}$, which refers to carbonyl stretching vibration of dialkylktone. Eventually the AKD molecule was hydrolyzed to diakylketone without formation of ${\beta}$-ketoester with cellulose in paper sheet. After 6 days ageing, a little amount of ${\beta}$-ketoester bands was identified in 6 or 7 days ageing, because of the absence of water due to long-term heating. The same tendency was observed at different ageing conditions. At the practical papermaking process, AKD reacts prevailing with water, and mostly seems to be hydrolyzed to dialkylketene. Concerned to the sizing development, AKD-sized paper sheet was shown no sizing development at the initial stage of ageing at $60^{\circ}C$ after heating treatment at $105^{\circ}C$ for 30 sec., and gradually increased the sizing degree with increasing ageing, such as Hercules Sizing Tester (HST) 130 see for 12 hr, HST 300 sec. for 3 days and HST 400 sec. for 5 days. It was concluded that hydrolyzed AKD could contributed to the sizing development of the paper sheet.

  • PDF KSCI

INTERIM REPORT ON THE HST KEY PROJECT TO MEASURE $H_0$

  • MOULD JEREMY
    • 천문학회지
    • /
    • 제29권spc1호
    • /
    • pp.7-10
    • /
    • 1996

  • With an interim calibration based upon half the Key Project's galaxies, the Tully-Fisher relation, the (Dn, $\sigma$) relation and type II supernovae yield $H_0$= 73$\pm$10 km/sec/Mpc.

  • PDF