• 제목/요약/키워드: HNS(hexanitrostilbene)

검색결과 4건 처리시간 0.018초

Mass Spectrometric Analysis of Eight Common Chemical Explosives Using Ion Trap Mass Spectrometer

  • Park, Sehwan;Lee, Jihyeon;Cho, Soo Gyeong;Goh, Eun Mee;Lee, Sungman;Koh, Sung-Suk;Kim, Jeongkwon
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3659-3664
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    • 2013
  • Eight representative explosives (ammonium perchlorate (AP), ammonium nitrate (AN), trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), cyclonite (RDX), cyclotetramethylenetetranitramine (HMX), pentaerythritol tetranitrate (PETN), and hexanitrostilbene (HNS)) were comprehensively analyzed with an ion trap mass spectrometer in negative ion mode using direct infusion electrospray ionization. MS/MS experiments were performed to generate fragment ions from the major parent ion of each explosive. Explosives in salt forms such as AP or AN provided cluster parent ions with their own anions. Explosives with an aromatic ring were observed as either $[M-H]^-$ for TNT and DNT or $[M]^{{\cdot}-}$ for HNS, while explosives without an aromatic ring such as RDX, HMX, and PETN were detected as an adduct ion with a formate anion, i.e., $[M+HCOO]^-$. These findings provide a guideline for the rapid and accurate detection of explosives once portable MS instruments become more readily available.

탄두 충돌 시 기폭관 컵의 변형 해석 (Deformation of STS Cup for EFI Detonator in High Velocity Impact)

  • 김석봉;유요한
    • 한국군사과학기술학회지
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    • 제16권4호
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    • pp.430-434
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    • 2013
  • In this paper, we have investigated deformation of cup for EFI detonator in high velocity impact test. The experimental result shows that STS cup deformed 0.170 mm with the bulged shape. The numerical simulation result with static/dynamic material properties of SUS304 shows 0.166 mm of deformation. The main parameters to decrease the deformation of cup are stength, thickness and density of cup. The initial condition of SUS304 cup was strength of 215 MPa and thickness of 0.12 mm. As strength increases to 500 MPa, deformation of cup converges to 0 mm, and as thickness increases to 0.18 mm, deformation of cup converges to 0 mm. If the density of cup decreases from 8 to 2.7 g/cc, the deformation of cup decreases to 0.141 mm.

VISAR를 활용한 초소형 EFI 기폭 장치의 성능 특성 연구 (An Experimental Study on Performance of a Miniaturized Exploding Foil Initiator using VISAR)

  • 유현주;장승교;김규형;여재익
    • 한국추진공학회지
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    • 제21권5호
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    • pp.80-87
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    • 2017
  • 격벽으로 분리된 여폭약과 수폭약의 쌍으로 이루어진 파이로테크닉 장치의 성능은 격벽 내에서의 충격파 감쇠 및 폭약의 충격 감도에 의해 결정된다. 따라서 초소형 Kapton 비행편의 고속 충돌 실험을 통한 대상 HNS의 충격 점화 및 감도 분석을 목표로 EFI 기폭 장치를 고안하였다. 폭약에 전해지는 충격파의 강도 및 지속 시간의 측정을 위해 VISAR 속도 간섭계를 활용한 속도 측정 및 임피던스 정합 기법을 적용하였다. 본 연구는 비행편의 속도 및 충돌 시 발생되는 충격파의 강도와 지속 시간을 결정함으로써 소형 파이로테크닉 장치의 성능 및 기폭을 위한 비행편의 임계 속도의 예측 가능성을 확인하였다.