• Title/Summary/Keyword: HLW disposal

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Assessment of Potential Natural Attenuation of Arsenic by Geological Media During Managed Aquifer Recharge (대수층 함양관리에 있어서 지질매질에 의한 비소 자연저감 가능성 평가)

  • Park, Dasomi;Hyun, Sung Pil;Ha, Kyoochul;Moon, Hee Sun
    • Journal of Soil and Groundwater Environment
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    • v.25 no.3
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    • pp.12-22
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    • 2020
  • Managed aquifer recharge (MAR) is a promising water management strategy for securing stable water resources to overcome water shortage and water quality deterioration caused by global environmental changes. A MAR demonstration site was selected at Imgok-ri, Sangju-si, Korea, based on screening for the frequency of drought events and local water supply situations. The abundant groundwater discharging from a nearby abandoned coal mine is one of the potential recharge water sources for the MAR implementation. However, it has elevated levels of arsenic (~12 ㎍/L). In this study, the potential of the natural attenuation of arsenic by the field geological media was investigated using batch and column experiments. The adsorption and desorption parameters were obtained for two drill core samples (GM1; 21.8~22.8 m and GM2; 26.0~27.8 m depth) recovered from the potentially water-conducting fracture-zones in the injection well. The effluent arsenic concentrations were monitored during the continuous flow of the mine drainage water through the columns packed with the core samples. GM2 removed about 60% of arsenic in the influent (0.1 mg-As/L) while GM1 removed about 20%. The results suggest that natural attenuation is an acitive process occurring during the MAR operation, potentially lowering the arsenic level in the mine drainage water below the regulatory standard for drinking water. This study hence demonstrates that using the mine drainage water as the recharge water source is a viable option at the MAR demonstration site.

Blasting Impact by the Construction of an Underground Research Tunnel in KAERI (한국원자력연구소내 지하처분연구시설 건설에 따른 발파 영향)

  • Kwon Sang-Ki;Cho Won-Jin;Kim Deug-Su
    • Explosives and Blasting
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    • v.23 no.4
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    • pp.1-18
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    • 2005
  • The underground research tunnel, which is under construction in KAERI for the validation of HLW disposal system, is excavated in a granite rock by drill&blasting. In order not to disturb the operation at the research facilities including Hanara reactor by the blasting for the excavation of $6m{\times}6m$ tunnel, a test blasting at the site was performed. Using the vibration equation derived from the test blasting, it was possible to predict the vibration at different locations at KAERI and to conclude that the blasting design would meet the design criteria at the major facilities in KAERI. The noise and vibration generated by the main blasting were continuously measured. In the case of vibration, the measured values were lower than the predicted one from the vibration equation. It is, therefore, concluded that the influence of blasting work for the construction of 280m long research tunnel on the major facilities in KAERIl would be insignificant.

Thermal-Hydro-Mechanical Behaviors in the Engineered Barrier of a HLW Repository: Engineering-scale Validation Test (고준위폐기물처분장 공학적방벽의 열-수리-역학적 거동 연구: 엔지니어링 규모의 실증실험)

  • Lee, Jae-Owan;Cho, Won-Jin
    • Tunnel and Underground Space
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    • v.17 no.6
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    • pp.464-474
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    • 2007
  • An enhancement in the performance and safety of a high-level waste repository requires a validation of its engineered barrier. An engineering-scale test (named "KENTEX") has been conducted to investigate the thermal-hydro-mechanical behaviors in the engineered barrier of the Korean reference disposal system The validation test started on May 31, 2005 and is still under operation. The experimental data obtained allowed a preliminary and qualitative interpretation of the thermal-hydro-mechanical behaviors in the bentonite blocks. The temperature was higher as it became closer to the heater, while it became lower as it was farther away from the heater. The water content had a higher value in the part close to the hydration surface than that in the heater part. The relative humidity data suggested that a hydration of the bentonite blocks might occur by different drying-wetting processes, depending on their position. The total pressure was continuously increased by the evolution of the saturation front in the bentonite blocks and thereby the swelling pressure. Near the heater region, there was also a significant contribution of the thermal expansion of bentonite and the vapor pressure in the pores of the bentonite blocks.

Speciation and Solubility of Major Actinides Under the Deep Groundwater Conditions of Korea

  • Dong-Kwon Keum;Min-Hoon Baik;Pil-Soo Hahn
    • Nuclear Engineering and Technology
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    • v.34 no.5
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    • pp.517-531
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    • 2002
  • The speciation and solubility of Am, Np, Pu and U have been analyzed by means of the geochemical code MUGREM, under the chemical conditions of domestic deep groundwater, in order to support the preliminary safety assessment for a Korean HLW disposal concept. Under the conditions of groundwaters studied, the stable solid phase is AmOHC $O_3$(s) or Am(OH)$_3$(s), soddyite((U $O_2$)$_2$ $SiO_2$.2$H_2O$) or N $a_2$ $U_2$ $O_{7}$ (c), Np(OH)$_4$(am), and Pu(OH)$_4$(am) for Am, U, Np, and Pu, respectively. The dominating aqueous species are as follows: the complexes of Am(III), Am(OH)$_2$$^{+}$ and Am(C $O_3$)$_2$$^{[-10]}$ , the complexes of U(VI), U $O_2$(OH)$_3$$^{[-10]}$ and U $O_2$(C $O_3$)$_3$$^{4-}$, the complexes of Np(IV), Np(OH)$_4$(aq) and Np(OH)$_3$C $O_3$, and the complexes of Pu(IV), Pu(OH)$_4$(aq) and Pu(OH)$_3$C $O_3$$^{[-10]}$ . The calculated solubilities exist between 1.9E-10 and 1.3E-9 mol/L for Am, between 5.6E-6 and 1.2E-4 mol/L for U, between 3.1E-9 and 1.3E-8 mol/L for Np, and between 6.6E-10 and 2.4E-10 mol/L for Pu, depending on groundwater conditions. The present solubilities of each actinide agree well with the results of other studies obtained under similar conditions.s.

Petrographic Study(ASTM C 295) on the KEDO Concrete Aggregates (콘크리트용 KEDO 골재의 암석기재시험 (ASTM C295))

  • Jeong, Ji-Gon;Kim, Kyung-Su;Lee, Chol-Woo
    • The Journal of Engineering Geology
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    • v.17 no.4
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    • pp.589-599
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    • 2007
  • For the preliminary judgement on the chemical stability of concrete aggregates mixed with cement paste, ASTM C 295 method can be applied prior to the long-term chemical test methods. By using this standard test method, the petrographic study on the appropriateness of natural KEDO aggregates for concrete was carried out. With the natural gravel and sand aggregates, the polarized microscope, stereoscopic microscope, and X-ray diffractometer were used for examination. The result shows the 23% of gravel aggregates and 5.1% of sand aggregates are chemically unstable. To select the favorable KEDO concrete aggregates, it is required to exclude the highly metamorphosed rocks, acidic volcanic rocks, highly foliated rocks, and expansive rocks identified from mortar-bar test. Further chemical test and mortar-bar test method integrated with this study is recommended for the suitability assessment of natural KEDO concrete aggregates.

Characteristic analysis of a thermochromic material based fiber-optic temperature sensor for measuring temperature of subsurface water (열변성 물질을 이용한 지하수 온도 측정용 광섬유 온도센서의 특성분석)

  • Seo, Jeong-Ki;Yoo, Wook-Jae;Cho, Dong-Hyun;Jang, Kyoung-Won;Heo, Ji-Yeon;Lee, Bong-Soo;Koh, Yong-Kwon
    • Journal of Sensor Science and Technology
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    • v.18 no.6
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    • pp.467-474
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    • 2009
  • In this study, we describe the feasibility of developing a fiber-optic temperature sensor using a thermochromic material such as 2,4,5-triphenylimidazole or also called Lophine. A sensor-tip is fabricated by mixing of a Lophine powder, which has a non-toxic and hydrophobic characteristics, and an epoxy resin. The temperature change in the sensor-tip gives rise to a change in the optical absorbance of the Lophine, and the transmittance of a light through the Lophine is also changed. We have measured the intensities of modulated lights due to the change of optical absorbance of the Lophine by using of a photo-multiplier tube(PMT). The relationships between the temperatures and the output voltages of PMT are determined to measure the temperature of water. The measurable temperature range of the fiber-optic sensor is from 5 to $30^{\circ}C$.

Impact of Residual Hydrofluoric Acid on Leaching of Minerals and Arsenic from Different Types of Geological Media (잔류 불산에 의한 모델 지질토양시료의 광물 용해 및 비소 용출 특성)

  • Jeon, Pilyong;Moon, Hee Sun;Shin, Doyun;Hyun, Sung Pil
    • Journal of Soil and Groundwater Environment
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    • v.23 no.2
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    • pp.23-29
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    • 2018
  • This study explored secondary effects of the residual hydrofluoric acid (HF) after a hypothetical acid spill accident by investigating the long-term dissolution of minerals and leaching of pre-existing arsenic (As) from two soil samples (i.e., KBS and KBM) through batch and column experiments. An increase in the HF concentration in both soil samples resulted in a dramatic increase in the release of major cations, especially Si. However, the amounts of mineral dissolved were dependent on the soil type and mineral characteristics. Compared to the KBM soil, relatively more Ca, Mg and Si were dissolved from the KBS soil. The column experiment showed that the long-term dissolution rates of the minerals are closely associated with the acid buffering capacity of the two soils. The KBM soil had relatively higher effluent pH values compared to the KBS soil. Also, more As was leached from the KBM soil, with a more amorphous hydrous oxide-bound As fraction. These results suggest that the potential of heavy metal leaching by the residual acid after an acid spill will be influenced by heavy metal speciation and mineral structure in the affected soil.

Overseas Review on the In-situ Demonstration of EBS for IN-DEBS Development (공학적방벽 현장실증 시스템 (IN-DEBS) 개발을 위한 해외 실증연구 현황 분석)

  • Lee, Minsoo;Choi, Heui-Joo;Lee, Jong-Youl;Lee, Changsoo;Lee, Jae-Owan;Kim, Inyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.2
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    • pp.107-119
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    • 2014
  • The worldwide Status-of-Art survey for the in-situ experiments of the engineered barrier system for HLW underground disposal was performed as a preliminary action for the design of the in-situ demonstration at KURT. Some nations, which have executed or is ongoing the in-situ experiments at their underground research facilities, were summarized in this review. The demonstration projects reviewed were TBT/Sweden-France, LOT/Sweden, HE-E/Switzerland, PRACLAY/Belgium, FEBEX/Spain, HORONOBE/Japan, and BCE/Canada. The investigated items for the projects were mainly their purposes, constitutional structures, test conditions, monitoring parameters and the measuring tools, and test results. In this review, the hardware design and the assembling of the test system were more concentrated rather than their experimental results, because the purpose of this review is to achieve the necessary information for the practical design of the in-situ experiment to be installed at KURT. A mid scale in-situ demonstration of EBS at KURT, that is called IN-DBES, will be launched right after the completion the expanding project of KURT in 2015. It is hoped that the structural design, installing methods, hardware equipments required in the establishment of IN-DEBS will be referred on this review.

Experimental Study on Frictional Healing Behavior of Rock Joints in the Natural Barriers under Hydro-Mechanical Conditions (천연방벽 내 암반 절리의 수리-역학적 조건에서의 마찰회복 거동에 대한 실험적 연구)

  • Yong-Ki Lee;Seungbeom Choi;Kyung-Woo Park;Jin-Seop Kim;Taehyun Kim
    • Tunnel and Underground Space
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    • v.33 no.1
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    • pp.42-56
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    • 2023
  • In deep geological disposal of high-level radioactive waste (HLW), the natural barrier must physically support the disposal facility and delay the movement of radionuclides for at least hundreds of thousands of years. To evaluate the long-term geological evolution of the natural barriers, it is essential to analyze the long-term behavior of rock joints, including the frictional healing behavior. This study aimed to experimentally analyze the frictional healing behavior of rock joints under hydro-mechanical (H-M) conditions through the slide-hold-slide (SHS) test. The SHS tests were performed under mechanical and H-M conditions for joint specimens of different roughness. In the H-M conditions, the frictional healing rate tended to increase, which was more evident in the specimens with large roughness. In addition, it was confirmed that the effect of the hydro-mechanical conditions was more significant when the effective normal stress acting on the joint surface was small. These results are expected to be used as fundamental data to understand the frictional healing behavior of rock joints in the natural barriers.

R&D Review on the Gap Fill of an Engineered Barrier for an HLW Repository (고준위폐기물처분장 공학적방벽의 갭채움재 기술현황)

  • Lee, Jae Owan;Choi, Young-Chul;Kim, Jin-Seop;Choi, Heui-Joo
    • Tunnel and Underground Space
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    • v.24 no.6
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    • pp.405-417
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    • 2014
  • In a high-level waste repository, the gap fill of the engineered barrier is an important component that influences the performance of the buffer and backfill. This paper reviewed the overseas status of R&D on the gap fill used engineered barriers, through which the concept of the gap fill, manufacturing techniques, pellet-molding characteristics, and emplacement techniques were summarized. The concept of a gap fill differs for each country depending on its disposal type and concept. Bentonite has been considered a major material of a gap fill, and clay as an inert filler. Gap fill was used in the form of pellets, granules, or a pellet-granule blend. Pellets are manufactured through one of the following techniques: static compaction, roller compression, or extrusion-cutting. Among these techniques, countries have focused on developing advanced technologies of roller compression and extrusion-cutting techniques for industrial pellet production. The dry density and integrity of the pellet are sensitive to water content, constituent material, manufacturing technique, and pellet size, and are less sensitive to the pressure applied during the manufacturing. For the emplacement of the gap fill, pouring, pouring and tamping, and pouring with vibration techniques were used in the buffer gap of the vertical deposition hole; blowing through the use of shotcrete technology and auger placement and compaction techniques have been used in the gap of horizontal deposition hole and tunnel. However, these emplacement techniques are still technically at the beginning stage, and thus additional research and development are expected to be needed.