• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.644-646
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• 2014

• 보존과학연구
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• 통권34호
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• pp.20-29
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• 2013

지류, 섬유, 목재와 같은 유기질 문화재는 주요 화학성분으로서 셀룰로오스로 구성되어 있다. 셀룰로오스는 글루코오스가 분자내 또는 분자간 수소결합으로 고분자 결정성 구조를 이루고 있다. 특히 셀룰로오스의 중합도는 종이나 섬유의 강도와 밀접한 관련이 있으며, 종이나 섬유에 있어서 열화의 진행정도나 보존성을 나타내는 지표로써 사용된다. 일반적으로 이러한 셀룰로오스의 분자량을 측정하는 방법으로 TAPPI 표준방법인 CED (cupriethylene diamine)용액을 이용한 점도측정법을 많이 사용하고 있다. 목재 섬유로 제조된 종이의 경우 TAPPI 표준 방법 T230법에 의거하여 셀룰로오스 점도를 측정한다. 그러나 우리나라 종이나 섬유의 주요 원료인 닥나무 인피섬유, 저마, 면 등은 목재 셀룰로오스 섬유에 비해 분자량이 크고 중합도가 높아 현재까지 주로 사용되던 T230법으로는 정확한 점도 측정이 어렵다. 따라서 본 연구에서는 고점도 측정방법인 TAPPI 표준 방법 T254법에 의거하여 저농도 CED 용액으로 섬유 깊숙이 용액을 침투시켜 해리시킨 뒤 고농도의 CED 용액으로 완전히 용해시키는 방법을 이용하여 한지의 점도를 측정하였고, 열화시편에 적용하여 종이와 섬유의 열화에 의한 손상정도를 측정하였다.

• Tribology and Lubricants
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• 제24권1호
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• pp.1-6
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• 2008

An experimental study was conducted to evaluate the viscosity characteristics of multi-grade engine oils in which contain diesel fuels. Unused engine oils of SAE 5W40, 10W40 and 15W40 were blended with a diesel fuel ratio of 5%, 10%, and 15%. The viscosity of a diluted engine oil was measured with temperature variation ranging from $-20^{\circ}C$ to $120^{\circ}C$ using a rotary viscometer. The diluted engine oil in which is blended to a diesel fuel plays an important role for decreasing an engine oil viscosity, which may decrease the oil film thickness and a load-carrying capacity. Test results show that the viscosity tends to fall for the increased temperature when engine oil is mixed with a diesel fuel. Especially, the viscosity at a low temperature zone is radically decreased compared with a high temperature zone. Based on the experimental results, the empirical equation that can predict the viscosity of diluted engine oil is expressed in the exponential function with the variation of the temperature and a fuel ratio of diluted engine oil. This equation may be possible to predict the limitation of the oil-fuel dilution rate at the concept design stage of the CDPF system, which doesn't affect the influence of the tribological components.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.230-233
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• 2008

The vanadium rich ash of petroleum coke can give a slagging problem during because of the high melting point of $V_2O_3$. For continuous removal of the slag, petroleum coke is often mixed with coal, and the viscosity of the mixed slag is an important property, determining the gasification temperature. The viscosities of the mixed slag from various mixing ratios of petroleum coke and a bituminous coal were investigated. When mixed with a crystalline coal slag, $T_{cv}$ was increased at a higher the coke content in the mixed feed. When the $V_2O_3$ concentration was greater than 4.5%, it was difficult to get accurate measurements of $T_{cv}$. The SEM/EDX analyses of the cooled slag revealed that the major crystalline phase was anorthite, and $T_{cv}$ should be related to the formation temperature of anorthite. The SEM/EDX analyses also showed that, at low concentrations of vanadium, part vanadium formed a crystalline phase with Al-Si-Ca-Fe, and the rest remained in the glassy phase, suggesting that vanadium existed as a slag component at the low viscosity region. At a high concentration, vanadium forms a phase with Ca, and the Ca-V phase was separated from the slag phase, and formed a layer above the slag. FeO in petroleum coke also played an important role determining viscosity: at high temperatures, increased FeO lowered the viscosity, but as it formed a spinel phase, the depletion of FeO in the slag resulted in a higher viscosity.

• 한국염색가공학회지
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• 제29권3호
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• pp.122-130
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• 2017

In the direct digital textile printing process, the pre-treatment process is an essential condition for products by forming a clear pattern by sticking and penetration of DTP dye without spreading on the fabric. Recently, pre-treatment agent is changing from high viscosity to low viscosity in order to reduce defects of fabric during pre-treatment process. In this study, pre-treatment agent of acrylic polymer with low viscosity(less than 50cps) was prepared according to the solid content of the polymer, pre-treated on the cotton fabric, and direct DTP printing was performed to compare the color and sharpness. As a result, it showed high color at a viscosity of 50cps or less. When the solid content of the polyacrylic acid having a high molecular weight(A1) was 2.5wt%, when the solid content of the polyacrylic acid having a low molecular weight(A2) was 1 - 1.5wt%, the color was the best. And when the solid content of A1 and A2 was 1.5wt%, the degree of spreading was small and A1 was superior to A2 at the sharpness.

• Tribology and Lubricants
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• 제3권2호
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• pp.34-43
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• 1987

탈납공정에 있어서 중요인자인 용제혼합비, 용제희석비 및 냉각온도에 대해 연구하였다. 용제로서 MEK와 toluene을 사용한 결과 혼합용제비로서는 저점도유 48:52, 고점도유 45:55가 이상적이었고, 용제희석비는 저점도유의 경우 1:2.8배로서 5회분할, 고점도유의 경우 1:3.5로 2회분할 첨가함이 가장 좋았으며 냉각온도는 영하 26$\circ$C로 탈납에 요구되는 시간은 오일의 종류비 따라 차이가 있음을 알았다.

• 한국자동차공학회논문집
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• 제15권3호
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• pp.141-146
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• 2007

In this study, the effects of change in ambient gas viscosity on spray structure have been investigated in the high temperature and pressure field. To analyze the structure of evaporative diesel spray is important in speculation of mixture formation process. Emissions of diesel engines can be reduced by the control of the mixture formation process. Therefore, this study examines the evaporating spray structure in the constant volume chamber. The viscosity of ambient gas was selected as the experimental parameter, is changed from 21.7 mPa s to 32.1 mPa s by changing in ambient gas temperature. In order to obtain images of the liquid and vapor-phase of injected spray, exciplex fluorescence method was used in this study. The liquid and vapor-phase images were taken with 35mm still camera and CCD camera, respectively. Consequentially, it could be confirmed that the distribution of vapor concentration is more uniform in the case of the ambient gas with high viscosity than in that of the ambient gas with low viscosity.

• Bulletin of the Korean Chemical Society
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• 제32권11호
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• pp.3909-3913
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• 2011

In this paper we have carried out molecular dynamics simulations (MD) for model systems of liquid n-alkane oligomers ($C_{12}{\sim}C_{80}$) at high temperatures (~2300 K) in a canonical ensemble to calculate viscosity ${\eta}$, self-diffusion constants D, and monomeric friction constant ${\zeta}$. We found that the long chains of these n-alkanes at high temperatures show an abnormality in density and in monomeric friction constant. The behavior of both activation energies, $E_{\eta}$ and $E_D$, and the mass and temperature dependence of ${\eta}$, D, and ${\zeta}$ are discussed.

• 소음진동
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• 제5권4호
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• pp.483-492
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• 1995

For evaluation of rotational accuracy performance of high speed machine tool spindle system, the characteristics of main spindle and tool motion behavior are presented by means of three point accuracy testing method. The results of experiments and analyses are as follows: (1) The high speed spindle rotational accuracy can be evaluated by the combination of the spindle and tool motion behavior. (2) The spindle motion behavior increases up to more that 4 times the tool motion behavior. (3) For the influence of oil viscosity on spindle and tool taper application, 32 cSt of oil viscosity showed the most satisfactory result for rotational accuracy. (4) In order to improve the rotational accuracy of high speed machine tool spindle system, it is needed to reduce the combination error. This can be achieved by improving the working accuracy and supplying the proper lubrication with contact area at the spindle and tool.

• Tribology and Lubricants
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• 제9권1호
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• pp.55-61
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• 1993

Recently, due to the erosion damage that were generated increasingly at alloy metals of slide bearing by cavity of lubricating oil with tendency of high speed and high output of reciprocating engine, there is a need to study the process on the formation of cavitation erosion, and the characteristic of cavitation erosion at lubricating oil environments under various condition for marine ship. Therefore, the apparatus of cavitation erosion experiment used 20 KHz, $24 \mu m$ piezoelectric vibrator. The main results obtained through this test method are as follows: 1. The max. erosion rate at lubricating oil environments was related to the change of space, oil film thickness, and shown to tendency of gear oil>system oil>turbine oil>mixed oil environments with different viscosity. 2. The pitted hole by cavitation erosion at high viscosity oil environments became small and deep, and in addition to, they appeared to be wide and shallow at low viscosity.