• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.704-710
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• 2017

Although the desalination technique using gas hydrate formation is at a development stage compared to the commercially well-established reverse osmosis (RO), it still draws attention because of its simplicity and moderate operational conditions especially when using refrigerants for guest gases. In this study, DFT (density functional theory)-based molecular modeling was employed to explain the energetics of the gas hydrate formation using HFC (hydrofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants. For guest gases, R-134a, R-227ea, R-236fa, and R-141b were selected and three cavity structures ($5^{12}$, $5^{12}6^2$, and $5^{12}6^4$) composed of water molecules were constructed. The geometries of guest gas, cavity, and cavity encapsulating guest gas were optimized by molecular modeling respectively and their located energies were then used for the calculation of binding energy between the guest gas and cavity. Finally, the comparison of binding energies was used to propose which refrigerant is more favorable for the gas hydrate formation energetically. In conclusion, R-236fa was the best choice in terms of thermodynamic spontaneity, less toxicity, and low solubility in water.

• The KSFM Journal of Fluid Machinery
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• v.7 no.2 s.23
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• pp.14-20
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• 2004

In this study, the overall performance and the local flow field of the centrifugal compressor with the refrigerant HFC-l34a were numerically studied using CFX-TASCflow. The thermodynamic and transport properties of the refrigerant gas were modeled by REFPROP which is NIST refrigerant properties database. The impacts of a grid qualify, discretization scheme, turbulent model and interaction between a impeller and a cascade diffuser were analyzed comparatively. The results were compared with experimental data and 1-D design results using COMPAL and agreed well with others. The numerical method and data obtained in this study can be applied to the design and modification of centrifugal compressors with real gases

• The KSFM Journal of Fluid Machinery
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• v.10 no.4
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• pp.29-38
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• 2007

In this study, flow structure in a two-stage centrifugal compressor for a turbo-chiller with the refrigerant, R134a, was numerically investigated at the design point of the compressor using a commercial code. Flow characteristics in the passages of impeller, diffuser and return channel were analyzed in detail including velocity vector, secondary flow, Mach number and pressure contours in blade spanwise and meridional plane for each stage. The estimation on the one-dimensional output from the preliminary design and three-dimensional shape of the impeller blade and the meridional shape of the return channel were performed through the flow analysis, while some numerical schemes and techniques including Multiple Frames of Reference technique, real gas property data and inlet boundary condition changes, which were used in CFD, were compared with their features. The results will be used as reference data for a new design of 3-D impeller shape to improve R134a compressor performance.

• International Journal of Air-Conditioning and Refrigeration
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• v.12 no.4
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• pp.176-183
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• 2004

Systematic methods to calculate thermodynamic properties of carbon dioxide, HFC-134a and HCFC-22 are presented. First, application of a basic method to identify the saturation state with given temperature or pressure is attempted and the feasibility of auxil­iary equations is tested. Next, detailed procedures are suggested to tell a phase when tem­perature/pressure and another property are specified. Finally the Newton-Raphson method is applied to calculate unknown thermodynamic properties fixing the state with the two inde­pendent properties specified. The procedures described here are utilized to develop a computer program, which is used to find the relation between temperature and pressure with maximum isobaric heat capacity for super-critical carbon dioxide.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.1
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• pp.140-150
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• 1996

CFC-12, which has been used most widely in automobile air conditioners and household refrigerators is scheduled to be phased out soon because of its high ozone depletion potential. Now HFC-134a is suggested as an alternative refrigerant for CFC-12. In this Study, we intended to investigate how PAG oil influence evaporation heat transfer and flow pattern, using R-134a and PAG oil influences evaporation heat transfer and flow pattern, using R-134a and PAG oil in the horizontal miro-fin evaporation tube. Experiments were conducted under the flowing est conditions : mass velocity 86-250kg/$m^2$s, heat flux 5-30 ㎾/$m^2$, oil concentration 0-21 wt.% and saturation temperature 5$^{\circ}C$. Local evaporation heat transfer coefficients were found to be higher at the top, side and bottom of the tube in this order. Average heat transfer coefficients turned out to increase with oil concentration increment up to 3 wt.% oil concentration, whereas heat transfer coefficients gradually decreased over 3 wt.% oil concentration, because of oil-rich liquid film was formed on the heat transfer surface. Flow patterns were rapidly transitioned to annular regimes up to 3 wt.% oil concentration. In case of pure refrigerant, measured heat transfer coefficients in the experiments were similar to those of Kandlikar＇s correlation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.177-186
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• 1996

The characteristics of the flow of pure HFC refrigerants(R32, R125, and R134a) and their mixtures through capillary tubes were investigated experimentally. Two capillary tubes with 1.2mm and 1.6mm inner diameter and 1.5m length were adopted as test sections. Mass flow rates and temperatures and pressures were measured for several condensing temperatures and degrees of subcooling at capillary tube inlet. The effects of the condensing temperature, inner diameter of capillary tube, and subcooling on the mass flow rate of refrigerants were discussed, and the mass flow rates of HFC refrigerants were compared with that of R22. The pressure and temperature distributions along the capillary tube compared with that of R22. The pressure and temperature distributions along the capillary tube show that there is a metastable equilibrium state in the flow through the tube. Underpressure for vaporization increases as refrigerant mass flux increases and inlet subcooling decreases. Empirical correlation was suggested to predict underpressure for vaporization of the HFC refrigerants.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.3
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• pp.381-388
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• 2003

An experimental study was carried out to measure the heat transfer coefficient in flow boiling to mixtures of HFC-l34a and HCFC-123 in a uniformly heated horizontal tube. Tests were run at a pressure of 0.6 MPa and in the ranges of heat flux 1-50 kw/$m^2$, vapor quality 0-100 % and mass velocity 150-600 kg/$m^2$s. Heat transfer coefficients of mixture were less than the interpolated values between pure fluids both in the low quality region where the nucleate boiling is dominant and in the high quality region where the convective evaporation is dominant. Measured data of heat transfer are compared to a few available correlations proposed for mixtures. The correlation of Jung et. al. satisfactorily predicted the present data, but the data in lower quality was overpredicted and underpredicted the high quality data. The correlation of Kandlikar considerably underpredicted most of the data. and showed the mean deviation of 35.1%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.3
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• pp.258-266
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• 2000

Experimental investigation and cycle simulation of a capacity modulation of a heat pump system using a hydrofluorocarbon (HFC) refrigerant mixture, R32/134a as an alternative to R22, have been done. In the cycle simulation, the refrigeration system was operated by assigning the temperatures of the external heat transfer fluids with the heat exchangers generalized by an average effective temperature difference. Heating capacity, cooling capacity, and coefficient of performance (COP) of the system were investigated at several operating conditions. Experimental apparatus which had a refrigeration part and a composition changing part was built, and the performance of the heat pump system filled with R32/134a mixture was investigated. A gas-liquid separator was used in the experiment to change the composition by collecting the vapor and the liquid Phase separately, The mass fraction of the charged refrigerant in the heat pump system was 40/60 and 70/30 by weight percentage. The composition of the refrigerant with initial composition of 40/60 varied from 29/71 to 41/59 in the refrigeration cycle. For the refrigerant with initial composition of 70/30, the composition varied from 65/35 to 75/25.

• Solar Energy
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• v.18 no.2
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• pp.91-104
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• 1998

This study carried out a numerical analysis on a heat pump assisted dryer using HFC134a. Under the constant degree of superheat and that of subcooling, we analyzed the performance of heat pump assisted dryer with varying an air mass velocity, bypass air ratio, compressor speed and an inlet bulb temperature of dryer. Simulation results were compared with experimental results, so they were maximally agreed in the range of 10%. There was the proper bypass air ratio with varying an air mass velocity. As for the effect of SMER having the inlet temperature $35^{\circ}C$ and compressor speed 1360rpm, bypass air ratio was 30% at the front velocity 0.5kg/s, 40% at the front velocity 0.7kg/s and 50% at the front velocity 0.9kg/s and 1.1kg/s. As the compressor speed was increased, SMER decreased and COP increased. As the inlet bulb temperature was increased, SMER and COP decreased.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.3
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• pp.315-324
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• 2000

R-410A, R-407C, and four refrigerant mixtures composed of R-32, R-l34a, R-l43a, R-l52a, R-600(butane), and R-600a(isobutane) were tested in an attempt to replace R-22 used in most of the residential air conditioners. The performance evaluation was carried out in a psychrometric calorimeter test facility using a residential spilt type air conditioner under the KS rating conditions. Except for the lubricant and hand-operated expansion valve, the other parts of the air conditioner were the same with the commercial system. Performance characteristics were measured; COP, capacity, compressor power, and VCR. R-410A was shown to have 5.5% higher COP and 3.5% lower capacity than R-22. R-32/134a/600a (42.8/ 46.0/11.2 wt%) mixture have the best performance among the four refrigerant mixtures composed of hydrofluorocarbon and hydrocarbon. This inixture have 3.0% lower COP and 1.6% lower capacity than R-22.