• Smart Structures and Systems
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• v.12 no.1
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• pp.73-95
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• 2013

Nine deoxyribonucleic acid (DNA) sequences were used to functionalize single-walled carbon nanotube (SWNT) sensors to detect the trace amount of methanol, acetone, and HCl in vapor. DNA 24 Ma (24 randomly arranged nitrogenous bases with one amine at each end of it) decorated SWNT sensor and DNA 24 A (only adenine (A) base with a length of 24) decorated SWNT sensor have demonstrated the largest sensing responses towards acetone and HCl, respectively. On the other hand, for the DNA GT decorated SWNT sensors with different sequence lengths, the optimum DNA sequence length for acetone and HCl sensing is 32 and 8, separately. The detection of methanol, acetone, and HCl have identified that DNA functionalized SWNT sensors exhibit great selectivity, sensitivity, and repeatability with an accuracy of more than 90%. Further, a sensor array composed of SWNT functionalized with various DNA sequences was utilized to identify acetone and HCl through pattern recognition. The sensor array is a combination of four different DNA functionalized SWNT sensors and two bare SWNT sensors (work as reference). This wireless sensing system has enabled real-time gas monitoring and air quality assurance for safety and security.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.3
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• pp.245-252
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• 2010

For the purpose of evaluating to remove elemental mercury using SCR (Selective Catalytic Reduction) catalysts, the result of the concentration variation of elemental mercury in lab experiment and field measurement was compared. The effect of the elemental mercury oxidation on commercial catalysts was studied in simulated gas. Three species of SCR catalyst, $V_2O_5-TiO_2$ type, were selected. The elemental mercury reduced 30% without HCl gas in SCR operating condition. But the width of reduction increased 60% at 20 ppm HCl gas. According to the result of field measurement, reduction rate of elemental mercury at SCR outlet showed 60%. The total mercury concentration decreased about 20%. The results were similar to the lab test. The results of chemical analysis of test sample showed increase of mercury concentration but surface change was not observed.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.609-617
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• 2000

This study is aimed at investigating an effect of HCl gas on selective reduction of NOx over a CuHM and $V_2O_5-WO_3/TiO_2$ catalyst. SCR process is the most effective method to remove NOx, but catalyst can be deactivated by the acidic gas such as HCl gas which is also included in flue gas from the incinerator. In dry condition of flue gas, the CuHM catalyst treated by HCl gas has shown higher NO removal activity than the fresh catalyst. The activity of the catalyst can be restored by treating at $500^{\circ}C$. On the contrary. $V_2O_5-WO_3/TiO_2$ catalyst is obviously deactivated by HCl and the deactivation increases in proportion to the concentration of HCl gas. The deactivated catalyst is not restored to it's original activity by heat treatment for regeneration. In wet flue gas stream, the CuHM catalyst has shown lower activity than fresh catalyst and $V_2O_5-WO_3/TiO_2$ catalyst was severely deactivated by HCl treatment. The activity loss of catalysts are mainly due to the decrease of Br$\ddot{o}$nsted acid site on the catalyst surface by $NH_3$ TPD. The change of BET surface area of CuHM catalyst after the reaction isn't observed but $V_2O_5-WO_3/TiO_2$ catalyst is observed. The amount of $Cu^{{+}{+}}$ and $V_2O_5$ is decreased after the reaction. From these results, it is expected that CuHM catalyst should be better than $V_2O_5-WO_3/TiO_2$ catalyst for its application to the incineration of flue gas.

• Journal of the Korean Institute of Gas
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• v.16 no.4
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• pp.38-43
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• 2012

The purpose of this study is to carry out the consequence analysis of an accident related to the release of Hydrogen chloride occurred in a petrochemical company in Korea and suggest the measures to prevent similar accidents from happening again. The total amount released through the safety valve of HCl Column was calculated based on the rated capacity of the safety valve, the ideal gas equation and mechanical energy balance, respectively. As a result of the calculation, we found that the amount of HCl released through the safety valve was at least 76.8 kg. Also, we predicted the dispersion concentration at the position of the injured workers(more than 350 m away from the accident location) using simulation programs such as PHAST. The results of ALOHA and K-CARM are 304 ppm and 1,700 ppm respectively. However, PHAST calculation indicated that the concentration is less than l ppm. From these results, we can understand that workers were injured by HCl gas released from the safe valve and the concentration of gas might be less than 1 ppm. Also, it is important for toxic gases such as HCl to be vented safely to the atmosphere after scrubbing.

• Fire Science and Engineering
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• v.32 no.5
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• pp.52-56
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• 2018

The damage caused by fires is fatal as opposed to the damage caused by heat, and toxic gas generated by fires can be protected against by using a wet towel. In this study, we quantified the filtration effect of gas generated by an actual fire using a wet towel. In order to confirm the filtration effect of the wet towel on three harmful gases ($CO_2$, HCl, HCN), gases passed through a filter using FT-IR were analyzed in realtime. HCl and HCN, which are gases, were filtered by a wet towel, and the detection time of each gas was delayed. Therefore, it was confirmed that evacuation time can be secured by using a wet towel in the case of toxic gas, especially water-soluble gases in an actual fire.

• Carbon letters
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• v.5 no.4
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• pp.186-190
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• 2004

In this work, a nickel metal (Ni) electroplating on the activated carbon fiber (Ni/ACFs) surfaces was carried out to remove the toxic hydrogen chloride (HCl) gas. The surface properties of the treated ACFs were determined by using nitrogen adsorption isotherms at 77 K, SEM, and X-ray diffraction (XRD) measurements. HCl removal efficiency was confirmed by a gas-detecting tube technique. As a result, the nickel metal contents on the ACF surfaces were increased with increasing the plating time. And, it was found that the specific surface area or the micropore volume of the ACFs studied was slightly decreased as increasing the plating time. Whereas, it was revealed that the HCl removal efficiency containing nickel metal showed higher efficiency values than that of untreated ACFs. These results indicated that the presence of nickel metal on the ACF surfaces played an important role in improving the HCl removal over the Ni/ACFs, due to the catalytic reactions between nickel and chlorine.

• Journal of Wetlands Research
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• v.17 no.1
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• pp.75-79
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• 2015

DIWS system was introduced to treat HCl gas from the scrubber of iron and steel industry according as the regulation of air quality is expected to be changed to 2ppm. pH of condensed water at stack was increased to 6.0. While 13.3ppm of inflow HCl was introduced to DIWS system, the average exhaust gas was 0.43ppm with 96.9% of removal efficiency. Compared with HCl data of TMS, the stable removal efficiency was shown in DIWS system, but the phenomenon of data hunting was also observed with different types of TMS apparatus.

• Journal of Wetlands Research
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• v.17 no.2
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• pp.118-123
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• 2015

This work has performed to examine the operation status of regeneration and scrubber system of cold rolling mill plant and established the DIWS(Dip Injection Wet Scrubber) system for the removal of hydrochloric acid with micro bubble. When the initial 22.3 ppm of HCl gas was injected into the system, the average exhaust HCl gas was 0.59 ppm with the removal efficiency of 97.3%. Hydrochloric acid was effectively removed by DIWS system. In the long term monitoring for 10 hours by 5 minutes through TMS(Tele Monitoring System), the average exhaust HCl gas was stably kept 0.69 ppm, which was also verified by manual measurement.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.2180-2185
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• 2003

Numerical simulations of freely propagating flames burning $H_2/HCl/Air$ mixtures are performed at atmospheric pressure in order to understand the effect of HCl on the NOx reduction. A chemical kinetic mechanism is developed, which involves 26 gas-phase species and 99 reactions. Under several equivalence ratios the flame speeds are calculated and compared with those obtained from the experiments, the results of which is in good agreement. As HCl is added into $H_2/Air$ flame as additive, its chemical effect causes the reduction of radicals (H, OH, and O), and then the decrease of the net rate of NO production. It is found that the chemical effect of additive has much more influence on the reduction of EINO than its physical effect.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.2
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• pp.103-108
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• 2014

Using dried sludge as a secondary fuel of a coal-fired power plant is proposed as an alternative option for sludge disposal. Because elemental contents of sludge are different from those of coal, different levels of acidic gas emissions are expected from the co-combustion of sludge with coal. In this study, sludge samples were obtained from 7 sewage treatment plants in Korea. Each sludge sample was combusted together with coal in a lab-scale combustor, and the concentrations of nitrogen oxides ($NO_x$), sulfur dioxide ($SO_2$), hydrogen chloride (HCl), chlorine ($Cl_2$) in the flue gas were analyzed. Compared to the combustion of coal only, $NO_x$ concentration was slightly higher in the flue gas from the co-combustion of coal and sludge. $SO_2$ emission increased with the combustion of sludge due to the higher content of sulfur in sludge than in coal. For most of the tested samples, the concentrations of HCl and $Cl_2$ were varied depending on the chlorine content in the sludge sample.