• Title/Summary/Keyword: HAL

Search Result 266, Processing Time 0.022 seconds

Electrochemical Properties of LiMn2O4-LiNi1/3Mn1/3Co1/3O2 Cathode Materials in Lithium Secondary Batteries (리튬이차전지 양극활물질용 LiMn2O4-LiNi1/3Mn1/3Co1/3O2의 전기화학적 특성)

  • Kong, Ming Zhe;Nguyen, Van Hiep;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.29 no.5
    • /
    • pp.298-302
    • /
    • 2016
  • In this work, $LiMn_2O_4$ and $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ cathode materials are mixed by some specific ratios to enhance the practical capacity, energy density and cycle performance of battery. At present, the most used cathode material in lithium ion batteries for EVs is spinel structure-type $LiMn_2O_4$. $LiMn_2O_4$ has advantages of high average voltage, excellent safety, environmental friendliness, and low cost. However, due to the low rechargeable capacity (120 mAh/g), it can not meet the requirement of high energy density for the EVs, resulting in limiting its development. The battery of $LiMn_2O_4-LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (50:50 wt%) mixed cathode delivers a energy density of 483.5 mWh/g at a current rate of 1.0 C. The accumulated capacity from $1^{st}$ to 150th cycles was 18.1 Ah/g when the battery is cycled at a current rate of 1.0 C in voltage range of 3.2~4.3 V.

Study of the Characteristics of Low-Temperature Prepared TiO2 Paste for Dye-sensitized Solar Cells (저온소성 TiO2 페이스트를 이용한 염료감응 태양전지의 특성 연구)

  • Jung, You-Ra;Jin, En Mei;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.5
    • /
    • pp.380-384
    • /
    • 2013
  • In this paper, we have developed a low temperature process to make two type of paste by using $TiO_2$ nanoparticles(P25). The interconnections between substrate and $TiO_2$ films or link between particles of free-binder paste(FP1, FP2, FP3) is very poor. Therefore, the Titanium(IV) isopropoxide was added to the TP paste to improve the interconnection. Electron transport time (${\tau}_t$) and recombination time (${\tau}_r$) are analyzed by IMPS (intensity-modulated photocurrent spectroscopy) and IMVS(Intensity-modulated photovoltage spectroscopy). In the results, ${\tau}_t$ of TP paste based DSSCs (about $4.3{\times}10^{-3}$) is faster than other samples. ${\tau}_r$ is longer from $2.7{\times}10^{-2}$ s of FP2 to $3.0{\times}10^{-2}$ s of TP. A solar conversion efficiency (DSSCs) of TP is 3.54% for an incident solar energy of 100 mW $cm^{-2}$(meanwhile, 2.70% for DSSCs with FP2). The conversion efficiency is increased by 1.3 times.

Study on Application of Fructus Forsythiae Main Blended Prescription from Dongeuybogam (동의보감(東醫寶鑑) 중(中) 연교(連翹)가 주약(主藥)으로 배오(配伍)된 방제(方劑)의 활용(活用)에 대한 고찰(考察))

  • Rho Euy-Joon;Kim Chang-Min;Lee Boo-Kyun;Kang Sung-Hyun;Yun Young-Gab
    • Herbal Formula Science
    • /
    • v.12 no.1
    • /
    • pp.105-121
    • /
    • 2004
  • This report describes the studies as follows through the research into the data of Fructus Forsythiae main blended prescriptions from Dongeuybogam. Through investigation on prescriptions from Dongeuybogam with Fructus Forsythiae as an ingredient, the following conclusions were reached. 1. All kinds of infection in a boil and the malignant tumor recorded the largest number of clinical frequency of the prescriptions in therapeutic use when Fructus Forsythiae was taken as a principle medicine. 2. The prescriptions are compounded with Fructus Forsythiae as a principle medicine can apply to eye disease, nose and ear disease, throat disease, trauma, the malignant tumor, skin disease, dental disease and heat pathogenic disease. 3. Various pathogenic factors such as wind-heat, heat, fire, wind, qi, poison, cold are put to practical use. 4. The dosage of Fructus Forsythiae is 2bun(about 0.75 gram) to 3jeon(about 11.25 gram), however 1joen(about 3.75 gram) has been taken the most for clinical application. 5. With examination the formulae of presciptions containing Fructus Forsythiae, I found the basic prescriptions as well as the medicines are in conjunction with Fructus Forsythiae and the theoretic grounds of formula in combining Fructus Forsythiae as a group of medicine for prescription through this research.

  • PDF

A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior (리튬이온전지의 유기용매분해에 따른 SEI film 형성과 전기화학적 거동에 관한 연구)

  • Kim, Min-Seong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11b
    • /
    • pp.545-549
    • /
    • 2001
  • We have produced electrolyte solution out of 1.15M $LiPF_6$ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M $LiPF_6$ DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M $LiPF_6$ EC/DEC(1/2 by vol%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC,DMC and EMC brought the de-decomposition peak of salt anion of $PF_6$ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. $Li/Li^+$). In addition, a kinetics current peak, in which intercalation of Lt is proceeded at 750mV, 450mV(vs. $Li/Li^+$), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance($R_{ct}$) according to the electric potential of $Li^+$ intercalation at 750mV(vs. $Li/Li^+$), which was the same as the resistance ($R_f$) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance($R_p$) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

  • PDF

The Electro-optical Propeties of Multilayer EL devices by blending TPD with P3TH as Emitting layer (TPD와 P3HT의 블렌드한 다층막 EL 소자의 전기-광학적 특성)

  • Kim, Dae-Jung;Gu, Hal-Bon;Kim, Hyung-Kon;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.11a
    • /
    • pp.542-545
    • /
    • 2002
  • High performance organic electroluminescnet(EL) devices which are composed of organic thin multilayer films are fabricated. The basic structure is ITO/Emitting layer/LiF/Al in which have a blended emitting layer. The emitting layer is consisted of a host material(N,N' diphenyl-N,N' (3-methyl phenyl)-l,l'-biphenyl-4,4'diamine)(TPD)) and a guest emitting material(poly(3-hexylthiophehe)(P3HT)). We think that the energy transfer in blending layer occurred from TPD to P3HT. Red emitting multilayer EL devices were fabricated using tris(8-hydroxyqunolinate) aluminum$(Alq_3)$ as electron transport material. The device structure of ITO/blending layer(TPD+P3HT)$/Alq_3$/LiF/Al was employed. In the Voltage-current-luminance characteristics of multilayer device, the device tum on at the 2V and the luminance of $10{\mu}W/cm^2$ obtain at l0V. Red emission peak at 640nm was observed with this device structure. We have presented evidence that the excitation energy migration between a polymeric host and guest has to be explained. And by using multilayer, the red light emitting EL device enhances not only Voltage-current-luminance characteristic but also stability of device.

  • PDF

A Study on the wiring Control Method of Hand & Auto Operation of an easy Elevator (간이 승강기 수.자동 배선제어방식에 관한 연구)

  • Wee, Sung-Dong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.11a
    • /
    • pp.596-602
    • /
    • 2002
  • An easy elevator for learning originated is opened to compare the existed learning equipment, and it had a high studying efficient that the sequence control circuit can opens and closes with the wire. The structure of equipment to be controlled from the first floor to the fifth floors is demonstrated a constructive apparatus by a lamp atc to express the function of the open-close of the door according to the cage moving with a mechanical actuation of the forward-reverse breaker and the motor of load and a mechanical actuation of hand-operation control components of push-button S/W and L/S and relay etc. These components let connects each other in order to control of the elevator function with the auto program and the designed sequence control circuit. Consequent1y the process of these functions of 1~5steps could operates the cage with an auto program of the elevator and the sequence control circuit. The sequence control circuit is controlled by the step of forward and reverse to follow as that the sensor function of the L/S1~L/S5 let posit with the control switchs of S/W1~S/W5 of PLC testing panel and switchs of S/W1~S/W5 installed on the transparent acryl plate of the frame. In here, improved apparatus is a hand-auto operation combined learning equipment to study the principle and a technique of the originated sequence control circuit and the auto program of PLC.

  • PDF

Electrochemical properties and Estimation of $LiMnO_{2}$ Active Material Synthesis for Secondary Batteries (2차 전지용 $LiMnO_{2}$ 활물질 합성의 전기화학적 특성과 평가)

  • Wee, Sung-Dong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.11a
    • /
    • pp.210-215
    • /
    • 2002
  • This thesis is contents on the crystal grown by the solide phase method at $925^{\circ}C$ with orthorhombic structure that $LiMnO_{2}$ active material synthesised with precurse $Mn_{2}O_{3}$ and $LiOH.H_{2}O$ material to get three voltage level. The porosity analysis of the grown crystal in secondary batteries $LiMnO_{2}$ thin film is $1.323E+02\AA$ of the average pore diameter of powder particles and its structure to be taken the pore diameter was prepared. Adding voltage area to get properties of charge and discharge of which experiment result of $LiMnO_{2}$ thin film area 2.2V~4.3V, current and scan speed were 0.1mAh/g and $0.2mV/cm^{2}$ respectively, and properties of the charge and discharge to be got optimum experiment condition parameter and density rate of Li for analyze that unit discharge capacity with metal properties is 87mAh/g was 96.9[ppm] at 670.784[nm] wavelength, and density rate of Mn analyzed 837[ppm] at 257.610[nm]. It can be estimated the quality of thin film that wrong cell reject from the bottle of electrolyte. The results of SEM and XRD were the same that of original researchers.

  • PDF

Extraction Efficiencies of Organochlorine Pesticides Spiked in Fish Tissues by Supercritical Carbon Dioxide (초임계이산화탄소에 의한 어류조직 중 유기염소계 농약의 추출수율)

  • Lim, Sang-Bin;Jwa, Mi-Kyung;Kang, Soon-Bae
    • Korean Journal of Food Science and Technology
    • /
    • v.28 no.3
    • /
    • pp.475-481
    • /
    • 1996
  • A simple, fast, inexpensive method hal been developed to extract organochlorine pesticide spiked in fish tissues by supercritical carbon dioxide. Following static supercritical fluid extraction (SFE), pesticides are collected by rapidly depressurizing the carbon dioxide effluent through a 0.79 mm i.d. metering valve into a capped screw-top tube. Percent recovers of standard organochlorine pesticides mixture (SOPM) increased with the decrease of the extraction temperature at 103 bar. Maximum average percent recovery of SOPM was 98% at $40^{\circ}C/172\;bar$ Average recoveries of SOPM spiked in Pacific cod, flatfish and common squid were 85,74,and 83% respectively at $40^{\circ}C/172\;bar$ Application of supercritical carbon dioxide ectraction offers and attractive alternative to the use of organic solvents for extraction of organochlorine pesticides from fish tissues.

  • PDF

The crystal growth and the electrochemical property of $LiZn_xMn{2-x}O_4(0\leqq x \leqq$ 0.15) cathode material ($LiZn_xMn{2-x}O_4(0\leqq x \leqq$ 0.15) 정극 활물질의 결정 성장 변화와 전기 화학적 특성)

  • Jeong, In-Seong;Gu, Hal-Bon;Lee, Jin;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.05a
    • /
    • pp.133-136
    • /
    • 1999
  • We report on the electrochemical properly of LiZ $n_{x}$Mn $_{2-x}$ $O_4$ for different degrees of Zn substitution(x) Though all cathode material showed spinel phase based on cubic phase in X-ray diffraction, other peaks(M $n_2$ $O_3$ or M $n_3$ $O_4$) gradually exhibited and became intense with the increase of x vague in LiZ $n_{x}$Mn $_{2-x}$ $O_4$. In addtion, TG-DTA analysis exhibited that both LiM $n_2$ $O_4$ and LiZ $n_{0.1}$ M $n_{1.9}$ $O_4$ occurred the weight loss(TG) and the endothermic and exothermic reaction(DTA) until 80$0^{\circ}C$ When x=0.1 in LiZ $n_{x}$Mn $_{2-x}$ $O_4$ cathode materials showed the charge and discharge capacity of about 100mAh/g at first cycle and about 70mAh/g after tooth cycle.cle.e.cle.e.e.e.

  • PDF

Quality improving effect of dries noodle according to treatment of pine needle seasoning oil (솔잎향미유 처리에 의한 건면의 품질개선 효과)

  • 손무호
    • Culinary science and hospitality research
    • /
    • v.7 no.2
    • /
    • pp.181-194
    • /
    • 2001
  • Dried noodles was manufactured by wheat flour and saline solution mixture. At this time, saline solution mixture was used for simple saline solution and mixture(blending ratio of PNSO and emulsifier=2:1, w/w) of both pine needle seasoning oil (PNSO) manufactured by autoclaving method and food emulsifier. Water absorption ratio, volume expansion ratio and water soluble solid matters content were decreased, but cooking time was prolonged, respectively. According to, suitable treating amount of PNSO was 2-3%(w/w) level. On organoleptic test, the peculiar green color was appeared in cooked noodles of PNSO treating groups. The surface was slickly, chewy rheology and texture were improved at PNSO treating cooked noodle. During 20-30 minutes after cooking, chewy characteristics was maintained the treating groups more than PNSO 2%(w/w). At the result, this PNSO treatin dried noodle samples were suitable at the institutional food service as well as dining hal1 for the case of large scale's kitchen work.

  • PDF