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Dye-sensitized solar cells using size dependent SBM binder

  • Park, Gyeong-Hui;Kim, Eun-Mi;Jo, Hong-Gwan;Wang, Gyo;Hong, Chang-Guk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.116-116
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    • 2009
  • $TiO_2$ pastes was synthesized to obtained of high efficiency dye-sensitized solar cells using size dependent co-polymer. SBM co-polymer binder is consist of styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The photoanodes were characterized by ATR-Fourier Transform spectrometer, X-ray diffraction (XRD) and morphology was investigated by field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density, AC impedance and monochromatic incident photon-to-current conversion efficiency (IPCE). DSSC based on the 100nm size co-polymer binder was obtained conversion efficiency of 8.1% under irradiation of AM 1.5(100 $mWcm^2$).

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Electrochemical properties of Graphene based $TiO_2$ photoelectrode for dye-sensitized solar cells (염료감응형 태양전지용 $TiO_2$ 광전극에 Graphene을 이용한 전기화학적 특성)

  • Wang, Jiao;Zhao, Xing Guan;Jin, En Mei;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bo-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.134-134
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    • 2009
  • We studied electrochemical properties of $TiO_2$ photoelectrode based graphene for dye-sensitized solar cells(DSSC). Gaphene has good electric conductivity and it is very good transparent when this is coated on monolayer. we prepared photoelectrode by squeeze methode and researched photoelectrical properties of $TiO_2$ electrode base gaphene. DSSC based on graphene was obtained conversion efficiency of 5.4% under irradiation of AM 1.5(100 $mWcm^2$).

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Enhancement of Emission Efficiency of Multilayer White Light Organic Electroluminescent Device (다층구조를 적용한 백색 전계발광소자의 발광효율 향상)

  • Kim, Ju-Seung;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05a
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    • pp.27-31
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    • 2001
  • We fabricated organic electroluminescent(EL) devices with mixed emitting layer of poly(N-vinylcarbazole)(PVK), 2,5-bis(5'-tert-butyl-2-benzoxazoly)thiophene(BBOT), N,N'-diphenyl-N,N'-(3-methyphenyl)-1,1'-biphenyl-4, 4'-diarnine(TPD) and poly(3-hexylthiophene)(P3HT). To improve the external quantum efficiency of EL devices, we added the functional layer to the devices such as LiF insulating layer, carrier confinement layer(BBOT) and hole injection layer(CuPc). In the ITO/emitting layer/Al device, the maximum quantum efficiency at 15V was $1.88{\times}10^{-5}%$. And then, it is increased by a factor of 27 to $5.2{\times}10^{-3}%$ in ITO/CuPc/emitting layer/BBOT/LiF/Al device at 15V.

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Electrochemical Characteristics of added $TiO_2$ Nanofiber for Dye-Sensitized Solar Cells ($TiO_2$ 나노파이퍼를 첨가한 염료감응형 태양전지의 전기화학적 특성)

  • Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.243-244
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    • 2009
  • The $TiO_2$ nanofiber doped $TiO_2$ electrode area applied to dye-sensitized solar cells(DSSCs). The mixtures of $TiO_2$ nanofiber to $TiO_2$ photoelectrode has larger surface area than $TiO_2$ photoelectrode. In this research added 2.5, 5 and 10wt% $TiO_2$ nanofibers and the optimum condition of 5 wt% $TiO_2$ nanofiber's high surface area contributing the improvement of short-circuit photocurrent. The open-circuit voltage was 0.7V and solar energy conversion efficiency was 5.4%.

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A Study on Transmittance Characteristic of ITO with Index Matching Film (Index Matching Film이 적용된 ITO 투과율 특성에 관한 연구)

  • Ki, Hyun-Chul;Kim, Sang-Gi;Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.307-308
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    • 2009
  • We have proposed an index matching film to improve the emitting efficiency of green OLED. Here, SiO2 and TiO2 were selected to coat the green OLED. The structures of index matching film were designed in G1ass/TiO2/SiO2/ITO and SiO2/TiO2/Glass/ITO. Then, these materials were deposited by ion-assisted deposition system. Transmittances of deposited devices were 86.14 and 85.07 %, respectively.

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Robot software component interface abstractions for distributed sensor and actuator (분산화된 센서와 엑츄에이터에 대한 로봇 소프트웨어 컴포넌트의 인터페이스 추상화)

  • Yang Kwang-Woong;Won Dae-Heui;Choi Moo-Sung;Kim Hong-Seok;Lee Ho-Gil;Park Joon-Woo
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1028-1033
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    • 2005
  • Robot is composed of various devices but, those are incompatible with each other and hardly developing reusable control software. We suggest standard abstract interface for robot software component to make portable device and reusable control software of robot. This assures uniform abstracted interface to the device driver software like sensor and actuator and, control program can be transparent operation over device. We can develop devices and control software separately and independently with this idea. This makes it possible to replace existing devices with new devices which have a improved performance.

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Emitting characteristics with alkyl side chain introduced at poly(3-alkylthiophene) electroluminescent devices (Poly(3-alkylthiophene) 전계발광소자에 도입된 alkyl side chain의 길이에 따른 발광특성)

  • Seo, Bu-Wan;Kim, Ju-Seung;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.143-146
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    • 2000
  • We studied effects of alkyl($C_nH_{2n+1}$) chain length on characteristics of poly(3-alkylthiophene) electroluminescent diodes. Among the poly(3-alkylthiophene), poly(3-hexylthiophene)(n=6) and poly(3- octyIthiophene)(n=8) were mainly used for the emitting layer of the diode. The result of experiment, the emission intensity of poly(3-alkylthiophene) electroluminescent diodes depends on the alkyl chain length. Strong emission is obtained from a poly(3-alkylthiophene) diodes of long alkyl side chain length. Emission intensities are enhanced by a confinement of carriers on a main chain with a long interchain distance caused by a long alkyl side chain.

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A Design of Half-wave length Resonant Dipole Antennas and Variations of Antenna Factors by the Antenna Dimensions (반파장 공진다이폴 안테나의 설계와 안테나 치수가 안테나 인자에 미치는 영향)

  • 김기채;정낙삼
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.16 no.8
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    • pp.785-792
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    • 1991
  • We designed the hal wavelength dipole antennal which can be used for he determination of the suitability of an antenna test site and considered the characteristic of antenna factors by using the moment methods. Antennal factors remain almost constant with negligible variations for the variations of $\pm$1 mm antenna dimention-radius and length. comparisons are mae between measured values and calculated results for the input impedance.

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Fabrication of TCO-less Dye-sensitized Solar Cells by Using Low Cost Ti Layer Deposited Glass Substrate (저가의 Ti 박막이 증착된 유리 기판을 사용한 TCO-less 염료감응형 태양전지의 응용)

  • Jung, Haeng-Yun;Ki, Hyun-Chul;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.11
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    • pp.725-729
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    • 2014
  • In this study, a transparent conductive oxide (TCO)-less dye-sensitized solar cells (DSSCs) was fabricated by using titanium (Ti) electrode to replace the Fluorine-doped tin oxide (FTO) for the reduction of manufacturing cost. Ti film was formed by electron beam evaporation method and the results showed the sheet resistance of Ti electrodes with a thikness of 500 nm similar to FTO. In case of power conversion efficiency (PCE), a DSSC with Ti electrodes showed a lower value than that with FTO by 0.38%. For the investigation of the difference, the DSSCs were measured and analyzed by using electrochemical impedance analyzer (EIS).

A Study on the Efficiency of Dye Sensitized Solar Cell Employing TiO2 Photoelectrode Synthesized Using Basic Catalyst (염기성 촉매제를 이용한 염료감응 태양전지의 효율에 관한 연구)

  • Ki, Hyun-Chul;Jung, Haeng-Yun;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.10
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    • pp.736-740
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    • 2013
  • In this study, the influence of electrochemical properties by mixing Tetrabutylammonium hydroxide (TBAOH) and ammonium hydroxide (NH4OH) electrode on the dssc. The titanias were prepared using a sol-gel method by mixing Tetrabutylammonium hydroxide and Ammonium hydroxide. The $TiO_2$ nanopowder prepared by sol-gel methode, and to improve the distributed properties of $TiO_2$ nanopowder, the TBAOH and NH4OH was added. The I-V values of cells show that the Tetrabutylammonium has 6.51% efficiency.