• Journal of the Korean Chemical Society
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• v.5 no.1
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• pp.1-6
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• 1961

It is important to study hydrazine because of the development of new uses for its derivatives. The Rasching method is the only satisfactory one for synthesizing hydrazine; it involves the oxidation of ammonia by sodium hypochlorite in the presence of some such catalyst as gelatin. Calcium hypochlorite was substituted for the sodium hypochlorite particularly in this work, applying agar-agar as catalyst. The results of the experiments are as follow: 1. The yield is proportional to the mole-ratio of ammonia to available chlorine in calcium hypochlorite and about 60% is obtained when the ratio is 20. 2. Agar-agar can be used as a catalyst and its proper concentration in the solution is 0.005%. 3. Proper concentration of available chlorine in the reaction solution is 0.23 mole/l. 4. The most effective condition for the reaction is a temperature of $60{\sim}65^{\circ}C.$ maintained for $20{\sim}25min$. 5. The reaction takes place equally well in either an open or closed container. 6. When calcium hypochlorite is applied in place of sodium hypochlorite, the yield of hydrazine is increased as much as 17%. 7. The yield of hydrazine is decreased by eliminating the suspension of $Ca(OH)_2$ which results from the use of calcium hypochlorite. 8. When $Ca(OH)_2$ is added to Rasching process, the yield of hydrazine is raised normally. 9. The fact that some metal ions, such as $Cu^{++},$ inhibit the formation of hydrazine was proved. 10. The suspension of $Ca(OH)_2$ acted as a remarkable adsorbent for $Cu^{++}$ like gelatin. The suspension of $Ca(OH)_2$ which results from the use of calcium hypochlorite acts as a catalyst, absorbing metal ions, to increase the yield of hydrazine. So I think that calcium hypochlorite is a more efficient oxidant than sodium hypochlorite in hydrazine syntheses.

• Korean Journal of Materials Research
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• v.11 no.3
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• pp.184-184
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• 2001

The effect of neutral ligand(L) on the precursor characteristics of (hfac)Cu(I)-L and on Cu MOCVD Process was studied. The neutral ligands of (hac)Cu(I)-L$_{x}$, such as ATMS(allytrimethylsilane), VTMS(vinyltrimethylsilane), VCH(vinylcyclohexane), MP(4-methyl-1-pentene), ACP(allylcyclopentane), and DMB(3,3-dimethyl-1-butene) were investigated. When the dissociation temperature of Cu(I)-L bond is low, low temperature deposition below $100^{\circ}C$ is possible and the resistivity of the film is low. But thermal stability of the precursor is low in this case. The resistivity is almost the same regardless of L at the deposition temperature range of $125~175^{\circ}C$. The resistivity is increased as the molecular weight of L becomes higher above $225^{\circ}C$ The vapor pressure of the precursor was closely related to the boiling point of L, the lower the boiling point of L, the higher the vapor pressurere.

• Korean Journal of Materials Research
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• v.11 no.3
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• pp.185-190
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• 2001

The effect of neutral ligand(L) on the precursor characteristics of (hfac)Cu(I)-L and on Cu MOCVD Process was studied. The neutral ligands of (hac)Cu(I)-L$_{x}$, such as ATMS(allytrimethylsilane), VTMS(vinyltrimethylsilane), VCH(vinylcyclohexane), MP(4-methyl-1-pentene), ACP(allylcyclopentane), and DMB(3,3-dimethyl-1-butene) were investigated. When the dissociation temperature of Cu(I)-L bond is low, low temperature deposition below $100^{\circ}C$ is possible and the resistivity of the film is low. But thermal stability of the precursor is low in this case. The resistivity is almost the same regardless of L at the deposition temperature range of $125~175^{\circ}C$. The resistivity is increased as the molecular weight of L becomes higher above $225^{\circ}C$ The vapor pressure of the precursor was closely related to the boiling point of L, the lower the boiling point of L, the higher the vapor pressurere.

• Korean Journal of Food Science and Technology
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• v.30 no.6
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• pp.1267-1272
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• 1998

The changes in physicochemical properties of gamma irradiated porks were investigated during storage at different temperature and periods. TBA values increased according to the increment of irradiation dose levels. TBA values of nonirradiated and irradiated samples drastically increased with storage period and temperatures at both $5^{\circ}C\;and\;-20^{\circ}C$. The acid value of porks stored at $5^{\circ}C$ was increased rapidly with the elapse of storage period in both nonirradiated and irradiated samples. However, the value decreased with increasing irradiation dose levels. VBN values increased more rapidly in nonirradiated samples than in irradiated samples with the storage period. Especially, VBN value of nonirradiated pork was four times higher than that of 3 kGy-irradiated one. No significant differences in the composition of fatty acids were observed in gamma irradiated samples. Free amino acids were changed with storage periods, but were not significantly affected by gamma irradiation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.1
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• pp.493-507
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• 2016

The aim of this study was to re-verify the importance of opportunity recognition as a mediating factor and add the entrepreneurial self-efficacy, which is recognized as another key factor that triggers start-up activities with the entrepreneurial intention, as a dependent variable. For this reason, in this study, 373 university students in Seoul, Gyeonggi-do Province, Inchon, were surveyed and analyzed empirically. The results of the study was as follows. First, the entrepreneurship partially affects the entrepreneurial self-efficacy and entrepreneurial intention. Second, the mediating effect of opportunity recognition between the entrepreneurship and entrepreneurial self-efficacy, and between entrepreneurship and entrepreneurial intention was verified.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.5
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• pp.364-371
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• 2016

We developed a prediction model of assistance force for the opening/closing of an automobile door depending on the condition of the parking ground. The candidates of the learning models for the operating assistance force were compared to determine the proper force according to the slope and user's force, etc. The reduced experimental model was developed to obtain learning data for the estimation model. The learning algorithm was composed to predict the assistance force to incorporate real assistance force data. Among these algorithms, an Artificial Neural Network (ANN) and Support Vector Machine(SVM) were applied and the adaptability was compared between these models. The SVM provided more adaptability for the learning process of the door assistance force prediction. This paper proposes a system for determining the assistance force to control a door motor to compensate for the deviation of required door force in the slope condition, as needed in the plane condition.

• The KIPS Transactions:PartB
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• v.13B no.2 s.105
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• pp.133-138
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• 2006

Learning with Attribute Value Taxonomies (AVT) has shown that it is possible to construct accurate, compact and robust classifiers from a partially missing dataset (dataset that contains attribute values specified with different level of precision). Yet, in many cases AVTs are generated from experts or people with specialized knowledge in their domain. Unfortunately these user-provided AVTs can be time-consuming to construct and misguided during the AVT building process. Moreover experts are occasionally unavailable to provide an AVT for a particular domain. Against these backgrounds, this paper introduces an AVT generating method called GA-AVT-Learner, which finds a near optimal AVT with a given training dataset using a genetic algorithm. This paper conducted experiments generating AVTs through GA-AVT-Learner with a variety of real world datasets. We compared these AVTs with other types of AVTs such as HAC-AVTs and user-provided AVTs. Through the experiments we have proved that GA-AVT-Learner provides AVTs that yield more accurate and compact classifiers and improve performance in learning missing data.

• Journal of the Korean Chemical Society
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• v.54 no.5
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• pp.556-566
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• 2010

A new kinetic spectrophotometric method is developed for the measurement of Mn(II) in natural water samples. The method is based on the catalytic effect of Mn(II) with the oxidation of Gallocyanin by $KIO_4$ using nitrilotriacetic acid (NTA) as an activation reagent at 620 nm. The optimum conditions obtained are $4.00{\times}1^{-5}\;M$ Gallocyanin, $KIO_4$, $1.00{\times}10^{-4}\;M$ NTA, 0.1 M HAc/NaAc buffer of pH = 3.50, the reaction time of 5 min and the temperature of $30^{\circ}C$. Under the optimum conditions, the proposed method allows the measurement of Mn(II) in a range of $0.1\;-\;4.0\;ng\;mL^{-1}$ and with a detection limit of down to $0.025\;ng\;mL^{-1}$. The recovery efficiency in measuring the standard Mn(II) solution is in a range of 98.5 - 102%, and the RSD is in a range of 0.76 - 1.25%. The newly developed kinetic method has been successfully applied to the measurement of Mn(II) in both some environmental water samples and certified standard reference river water sample, JAC-0031 with satisfying results. Moreover, few cations and anions interfere with the measurement of Mn(II). Compared with the other catalytic-kinetic methods and instrumental methods, the proposed kinetic method shows fairly good selectivity and sensitivity, low cost, cheapness, low detection limit and rapidity. It can easily and successfully be applied to the real water samples with relatively low salt content and complex matrices such as bottled drinking water, cold and hot spring waters, lake water, river water samples.

• Journal of the Korean GEO-environmental Society
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• v.8 no.2
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• pp.5-9
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• 2007

This study carried out to investigate the removal capacity of heavy metals such as Cu (II), Zn (II) and Cd (II) dissolved in aqueous solution in the soils collected from Hyeon-Dong (HD), San-seong (SS), Keum-chon (KC) and Keum-Hac (KH) located in the upper Banbyun stream. The pH of all the soils was weak alkali such as 8.8 9.2. According to the analysis of chemical composition of the soils, the amount of $SiO_2$, $AlO_2$ and CaO were similar in all tested soils. However, the amount of $K_2O$, $FeO_3$ and MgO were different from each soil. The XRD measurement with these soils showed that quartz and feldspar were presented in all tested soils, and the distribution of kaoline, illite, montmorillonite, vermiculite and calcite were different from each soil. The results of the removal capacity of heavy metals indicated that all the soils had more than 98% of the removal efficiency of Cu (II), Zn (II) and Cd (II), and among the heavy metals, Cu (II) was removed the most effectively. These results suggested that the soils collected from the upper Banbyun stream have the high removal capacity of heavy metals, and these soils could be used for the banking a river around the abandoned mine area, containing the higher concentrations of heavy metals than the usual stream.

• Korean Journal of Environmental Biology
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• v.29 no.4
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• pp.326-344
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• 2011

Although anthropogenic disturbance of 20 years duration affects benthic habitats, few studies have examined its effects on the macrobenthic communities of a bay. The aim of this study was to determine the influence of environmental variables on the macrobenthic communities after the construction of the Hwaong dike. Macrobenthos were collected at 22 sites using a Smith McIntyre grab (0.1 $m^2$) in August 2007 and February 2008. Total organic content was very low around the Hwaong dike. Sediment grain size increased from the Hwaong dike to the outer bay. In total, 317 species of macrobenthic fauna were collected and the mean density was 1,155 ind. $m^{-2}$, both of which were higher than the results of previous studies. The dominant species, $Hetermastus$ $filiformis$, known to be a potential pollution indicator, was more abundant near the Hwaong dike. Conversely, species sensitive to organic pollution, such as the polychaete $Ampharete$ $arctica$ and the ophiuroid $Amphioplus$ $squamata$, exhibited higher mean densities in areas distant from the dike. A cluster analysis indicated that the macrobenthic community was divided into two distinct groups: group I near the dike and group II in the outer bay, which were affected by sediment grain size and total organic content. This study suggests that variations in sediment grain size and organic content after dike construction are important factors controlling the macrobenthic community in Asan Bay.