• Title/Summary/Keyword: HA coating

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$MgF_2$ AR Coating 두께에 따른 CIGS Cell Performance 변화

  • Kim, Ju-Hui;Lee, Gyu-Seok;Jo, Dae-Hyeong;Choe, Hae-Won;Kim, Je-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.373-373
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    • 2011
  • $Cu(In,Ga)Se_2$(CIGS) 박막 태양전지는 Chalcopyrite계 박막 태양전지로 Cu, In, Ga, Se 각 원소의 조성을 적절히 조절하여 박막을 성장시킨다. 성장시킨 CIGS 박막은 광흡수계수가 105cm-1로 다른 물질 보다 뛰어나고 직접 천이형 반도체로서 얇은 두께로도 고효율의 박막 제작이 가능하다. 얇은 두께로도 충분히 빛의 흡수가 가능하지만, cell 표면 반사에 의한 광 손실은 cell 효율을 떨어뜨리게 된다. 본 연구에서는 CIGS 박막 태양전지의 광 흡수 향상을 위해 굴절률이 1.86인 ITO 위에 ITO보다 굴절률이 작은 $MgF_2$ (n=1.377) [1]를 80, 100, 120, 140 nm로 증착하여 $MgF_2$/Al/Ni/ITO/i-ZnO/CdS/CIGS/Mo/SLG 시료를 제작하고, optical reflectance, Quantum Efficiency를 이용하여 분석하였다. optical reflectance 분석 결과, $MgF_2$ AR coating을 한 경우, 두께가 두꺼워짐에 따라 광 반사도가 감소하는 경향을 보였다. 또한 AR coating 두께가 커짐에 따라 fluctuation이 점점 커지며, 파형이 장파장 쪽으로 shift하는 것을 관찰 할 수 있었다. Quantum efficiency (QE)를 분석한 결과 $MgF_2$ AR coating 할 경우, 측정된 대부분의 파장에서 QE가 향상되는 것을 확인할 수 있었다. 하지만 AR coating 두께에 따른 변화는 뚜렷한 차이를 보이지 않았다. AR coating 결과, JSC가 증가하여 efficiency가 향상되는 것을 확인 할 수 있다. 그러나 $MgF_2$ AR coating 80~140 nm 범위에서 cell 효율 변화의 뚜렷한 차이는 관찰할 수 없었다.

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Dip Coating of Amorphous Materials on Metal Surface (금속표면에 비정질의 피복)

  • Park, Byung-Ok;Yoon, Byung-Ha
    • Journal of the Korean institute of surface engineering
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    • v.20 no.2
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    • pp.49-59
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    • 1987
  • The properties of $Cr_2O_3-Al_2O_3-SiO_2$ composite oxide coatings on steel surface were investigated. The results obtained were as follows: The microhardness of oxide coating layer increased with increasing heat-treatment temperature and $Cr_2O_3$ content in coating layer. The hardness showed the highest value (850Hv) treated at 700$^{\circ}C$ for $SiO_2:Al_2O_3:Cr_2O_3$=1:1:4. Increasing heat-treatment temperature, corrosion current density became lower and coating layer became denser. The corrosion current density showed the lowest value $(6.5{\times}10^{-5}\;Acm^2)$ treated at 750$^{\circ}C\;for\;SiO_2:Al_2O_3:Cr_2O_3$=1:1:3. These results were explained by protective layer which was formed during heat-treatment. The bonding between matrix and coating layer is expected to be made mechanically and chemically by the inter diffusion of Ni and Fe. The composite oxide coating was formed by softening of the binder with increasing heat-treatment temperature. The strengthening of coating layer is to be resulted from the dispersion of major oxide particles.

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Microstructure and Biocompatibility of Ti-Nb-Si-HA Composites Fabricated by Rapid Sintering Using HEMM Powders

  • Woo, Kee-Do;Kim, Sang-Hyuk;Kang, Dong-Soo;Kim, Dong-Gun
    • Korean Journal of Materials Research
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    • v.23 no.7
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    • pp.353-358
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    • 2013
  • To improve coating ability and the life of the coating, Ti based composite materials with hydroxyapatite(HA) should be developed. The raw materials of Ti-26wt%, Nb-1wt%, and Si with 10wt% HA were mixed for 24 h by a mixing machine and milled for 1 h to 6 h by planetary mechanical ball milling. Ti-26%Nb-1%Si-(10%HA) composites, composed of nontoxic elements, were fabricated successfully by spark plasma sintering(SPS) at $1000^{\circ}C$ under 70MPa. The relative density of the sintered Ti-Nb-Si-HA composites using the 24 h mixed powder, and the 6 h milled powder, was 91% and 97 %, respectively. The effects of HA contents and milling time on microstructure and mechanical properties were investigated by SEM and hardness tester, respectively. The Vickers hardness of the composites increased with increasing milling time and higher HA content. The Young's modulus of the sintered Ti-26%Nb-1%Si-10%HA composite using the 6 h-milled powder was 55.6 GPa, as obtained by compression test. Corrosion resistance of the Ti-26wt%Nb-1wt%Si composite was increased by milling and by the addition of 10wt%HA. Wear resistance was improved with increasing milling time. Biocompatibility of the Ti-Nb-Si alloys was improved by the addition of HA.

Study on the Fouling Reduction of the RO Membrane by the Coating with an Anionic Polymer (역삼투막 표면에 음이온 고분자 코팅을 통한 파울링 현상 감소연구)

  • Cho, Eun Hye;Cheong, Seong Ihl;Rhim, Ji Won
    • Membrane Journal
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    • v.22 no.6
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    • pp.481-488
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    • 2012
  • The anionic exchange polymer, poly(vinyl amine)(PVAm), was coated onto polyamide (PA) reverse osmosis (RO) membranes by using 'salting-out' method. The effects of the fouling phenomena for these PVAm coated membranes were investigated using the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA). The surface coating and the fouling phenomena were observed by the scanning electron microscopy. And the flux was measured for each 100 ppm of above foulant aqueous solution at the operating pressure, 2, 4, 8 bar. The PVAm-coated PA membranes showed somewhat fouling improvements and the fouling reduction was shown in the order of HA > SA > BSA, particularly HA case was distinct.

Thickness evaluation of Cr coating fuel rod using encircling ECT sensor

  • Park, Jeong Won;Ha, Jong Moon;Seung, Hong Min;Jang, Hun;Choi, Wonjae
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3272-3282
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    • 2022
  • To improve the safety and life extension qualities of nuclear fuel rods which is currently made of zirconium (Zr) alloy, research on the application of chromium (Cr) coating was conducted. Cr coating has advantages such as increased corrosion resistance and reduced oxidation rate, but non-destructive thickness evaluation studies are needed to ensure the reliability of the steps taken to provide uniform coating thickness. Eddy current testing (ECT) is a representative non-destructive technique for such as thickness evaluation and surface defect inspection. To inspect changes in thickness at micron scale, the Swept Frequency Eddy Current Testing (SFECT) method was applied to select a frequency range sensitive to changes in thickness. The coating thickness was evaluated using changes in signals, such as that for impedance. In this study, basic research was performed to evaluate the thickness of the Cr coating on a rod using an encircling sensor and the SFECT technique. The sensor design parameters were determined through simulation, after which the new sensor was manufactured. A sensor capable of measuring the thickness of a non-uniformly Cr-coating rod was selected through an experiment evaluating the performance of the manufactured sensor. This was done using the impedance-difference of a Cr-coating rod and a Zr alloy rod. The possibility of evaluation of the Cr coating thickness was confirmed by comparing the experimental results with the selected sensor and the signals of the measured Cr-coating rod. All simulation results were verified experimentally.

Anti-Proliferative Effect of Tetraphenylporphine (TPP) as an Iron Chelator on Vascular Smooth Muscle Cells and its Release Profiles from Polymer Coating Layer (철 킬레이터로서의 tetraphenylporphine의 혈관평활근세포의 성장억제효과와 고분자 코팅막으로부터의 방출 특성)

  • Park, Min-Hee;Kang, Soo-Yong;Park, Hyun-Jeong;Seo, Jin-Seon;Park, Young-A;Kim, Ji-Eun;Kim, Yang-Geun;Whang, Bae-Geon;Munkhjargal, Odonchimeg;Shim, Young-Key;Kho, Weon-Gyu;Lee, Woo-Kyoung
    • Journal of Pharmaceutical Investigation
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    • v.38 no.2
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    • pp.93-98
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    • 2008
  • The drug-eluting stent (DES) implantation is a widely acceptable treatment for coronary heart disease. It was reported that iron chelator had anti-proliferative effect on human vascular smooth muscle cells (HA-VSMCs). In this study, tetraphenylporphine (TPP) was selected as an iron chelator and drug for DES. MTT assay showed that TPP had antiproliferative effect on HA-VSMCs. TPP and polycaprolactone (PCL) were coated onto stainless steel plate using a spraycoating method. From the surface morphology examination of the coated plate by SEM, smooth polymer coating layer could be observed. The thickness of coating layer could be controlled by changing repeating time of coating. From in vitro release test, sustained release of TPP was observed from plate during two weeks. Thus, TPP as iron chelator can be used as drug for stent coating because of its antiproliferative effect and sustain release profile.

Histomorphometric Analysis of Two Types of Coated Implants : a Preliminary Study Using the Rabbit Tibia Model

  • Yeo, In-Sung;Lee, Hyo-Jung
    • Journal of Korean Dental Science
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    • v.2 no.1
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    • pp.28-30
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    • 2009
  • Purpose : The purpose of this pilot experiment was to evaluate early bone response in two types of coated implants using the rabbit tibia model. Materials and Methods : Screw type titanium implants manufactured with a calcium metaphosphate (CMP) coating and hydroxyapatite (HA) coating were placed in the tibiae of 3 New Zealand White rabbits. The bone responses at 2 weeks after insertion were evaluated and compared by histomorphometry. Results : There was no significant difference in bone-to-implant contact between the groups (P>.05). However, some qualitative differences on histologic views were found. Conclusions : CMP-coating is suggested to be the preferred candidate for fast osseointegration over HAcoating.

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Anti-reflection Coating of Silicon Nitride Film for Solar Cell by RF Magnetron Sputtering (RF 마그네트론 스퍼터링을 이용한 태양전지용 질화 실리콘 반사방지막)

  • Choi, Kyoon;Choi, Eui-Seok;Hwang, Jin-Ha;Lee, Soo-Hong
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.585-588
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    • 2007
  • Silicon nitride films for an anti-reflection coating were deposited on silicon via RF magnetron sputtering using a $Si_3N4$ target. The best result was obtained at the sputtering condition of 340 W RF power, 5 mtorr Ar atmosphere, $100^{\circ}C$ substrate temperature. The films showed 7.9% reflectance minimum with 2.35 refractive index. 0.21 absorption coefficient at 66.6 nm thickness. The surface morphology showed a smooth and dense film with good adhesion to silicon surface.

Preparation and Properties of Waterborne Polyurethanes and Their Blend Films (수분산 폴리우레탄과 그의 블렌드물의 제조 및 물성)

  • Yoo, Byung-Ha;Kim, Eun-Young;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.38-41
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    • 2003
  • Recently, Waterhorne polyurethane(WBPU) have been used for a wide range of commercial applications due to the increasing environmental regulation to reduce low-volatile organic compounds in coating and adhesives materials [1-8]. The WBPU was used in coating industry on fiber at first, and its market is increasing these days. Especially, the Waterborne polyurethane film even is widely used in the field of breathable coating fiber or medical science [9-10]. Water vapor permeability(WVP) is the key property for application to breathable coating fiber. (omitted)

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Characterization of the Silica Coated Diatomite Based Ceramic Filter for Water Treatment (실리카 분말이 코팅된 수처리용 규조토계 세라믹 필터의 특성평가)

  • Bae, Byung-Seo;Ha, Jang-Hoon;Song, In-Hyuck;Hahn, Yoo-Dong
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.21-27
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    • 2014
  • In this study, diatomite based materials were investigated as a support filter for silica particle coating. The silica sol for coating was synthesized by a st$\ddot{o}$ber process. The diatomite support was dry-pressed at 10 MPa and sintered at $1200^{\circ}C$ for 1 hour. The coating sol was prepared as a mixture of EtOH and silica sol. The diatomite support was coated by a dip-coating process. Silica coated diatomite filter was sintered at $1000{\sim}1200^{\circ}C$ for 1 hour. The largest pore size was decreased with increasing concentration ratio of coating sol. The gas and water permeability of silica coated diatomite decreased with increasing of concentration ratio of the coating sol.